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A Development of Fluorescent Detection in Laboratory EXAFS

Research Project

Project/Area Number 01850174
Research Category

Grant-in-Aid for Developmental Scientific Research (B).

Allocation TypeSingle-year Grants
Research Field 工業分析化学
Research InstitutionInstitute In Molecular Science

Principal Investigator

UDAGAWA Yasuo  Institute Molecular in Science, Associate Prof., 分子科学研究所, 助教授 (00004458)

Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1990: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1989: ¥2,300,000 (Direct Cost: ¥2,300,000)
KeywordsEXAFS / Fluorescent detection / Film / Cobalt complexes / Pirphyria / X線吸収 / 蛍光X線
Research Abstract

Fluorescent detection method was developed for Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy by the use of conventional rotating anode x-ray generator. As a result, it is now possible to obtain accurate EXAFS spectra of 1000A thick film or 5 mM/l aqueous solution.
By the use of the instrument developed with this grant, structural studies of the following materials have been performed.
1. Iron oxide thin films prepared by spin-coating method.
2. Aqueous iron and cobalt solutions.
3. Cobalt complexes in N, N-dimethylamide.
4. Iron Pirphyria in various solvents.

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (7 results)

All Other

All Publications (7 results)

  • [Publications] Kazuyuki TOHJI, Takanori MIZUSHIMA, Yasuo UDAGAWA: "Laboratory EXAFS by Flusrescenu Detection" Japanese Journal of Applied Physics. 29. 2171-2175 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kazuyuki Ozutiumi, K.Tohji Y,Udagawa, S.Ishiguro: "Structre of Cobalt (II) Ion and Triーand tetraーChlovo Cobaltate (II) Complexes in N,NーDimethylーamicle by Fluore ce it EXAFS" Bulletin of the Chemical Society of Japan.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. TOHJI, T. MIZUSHIMA, Y. UDAGAWA: "Laboratory EXAFS by Fluorescence Detection" Japanese Journal of Applied Physics. Vol. 29. 2171-2175 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Ozutsumi, K. Tohji, Y. Udagawa, S. Ishiguro: "Structure of Cobalt (II) Ion and Tri- and Tetra-Chbro Cobalt (II) Complexes in N, N-Dimethylamide by fluorescent EXAFS." Submitted to Bulletin of the Chemical Society of japan.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Kazuyuki TOHJI,Takanori Mizushima,Yasuo UDAGAWA: "Laboratory EXAFS by Fluorescence Detection" Japanese Journal of Applied Physics. 29. 2171-2175 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Kazuhiko Ozutsumi,K.Tohji,Y.Udagawa,S.Ishiguro: "Structure of Cobalt(II) lon and Triーand Tetra ChloroーCobaltate (II) Complexes in N,NーDimethylamide by Flaurescent EXAFS" Bulletin of the Chemical Society of Japan.

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Tohji,Y.Udagawa: "Fluorescence Detection of EXAFS in Lobaratory System" Jpn.J.Appl.Phys.

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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