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"Formational mechanisms and materials properties of iron sulfides"

Research Project

Project/Area Number 02045003
Research Category

Grant-in-Aid for international Scientific Research

Allocation TypeSingle-year Grants
SectionUniversity-to-University Cooperative Research
Research InstitutionTohoku University

Principal Investigator

OHMOTO Hiroshi TSUKAMOTO Katsuo (1991-1992)  Faculty of Science, Tohoku University. Prof. Faculty of Science, Tohoku University., 理学部, 助手 (60125614)

大本 洋 (1990, 1992)  東北大学, 理学部, 教授 (60194304)

Co-Investigator(Kenkyū-buntansha) U. Graham  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
S. Poulson  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
L.M. Kump  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助教授
K.OSSEO-ASARE  College of Earth and Mineral Sciences, Pennsylvania State University., 地球及び鉱物科学, 教授
NARAOKA Hiroshi  Faculty of Science, Tohoku University., 理学部, 助手 (20198386)
KITAKAZE Arashi  Faculty of Science, Tohoku University., 理学部, 助手 (90035064)
HAYASHI Ken-ichiro  Faculty of Science, Tohoku University., 理学部, 助教授 (40124614)
SHIMADA Masahiko  Faculty of Engineering, Tohoku University., 工学部, 教授 (80029701)
HIRAI Toshio  Institute of Material Sciences, Tohoku University., 金属材料研究所, 教授 (50005865)
SIMON R.Poulson  College of Earth and Mineral Sciences, Pennsylvania State University.
URSULA M.Graham  College of Earth and Mineral Sciences, Pennsylvania State University.
LEE M.Kump  College of Earth and Mineral Sciences, Pennsylvania State University.
GRAHAM U.  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
POULSON S.  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
KUMP L.M.  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助教授
OSSEOーASARE アサレ  ペンシルヴァニア州立大学, 地球及び鉱物科学, 教授
GRAHAM U  ペンシルヴァニア州立大学, 地球及び鉱物科学, 助手
OSSEO Asare  ペンシルヴァニア州立大学, 地球及び鉱物科学, 教授
塚本 勝男  東北大学, 理学部, 助手 (60125614)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1992: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1991: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1990: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsIron Sulfides / Pyrrhotite / Hydrothermal Solution / Semiconductivity / Lattice Constant / Anisotropy / Trace Elements / 微量元素 / 熱電率 / 微量成分 / モルフォロジ- / 鉄硫化鉱物 / 鉱物特性 / イオウ同位体 / 海底熱水鉱床 / 金鉱床
Research Abstract

Iron sulfides, especially pyrite and pyrrhotite, are the most abundant sulfide minerals in the Earth. They are formed from magmas in igneous rocks, from hydrothermal solutions in a variety of mineral deposits, and by bacterial activity in oceans, sedimentary rocks, coals and petroleum. The iron sulfide minerals are known to exhibit considerable variations in physical properties (morphology and habits, density), crystal structure (lattice constants), optical properties,(reflectivity,anisotropy), electrochemical properties (semiconductivity, photoelectrical and thermoelectrical potentials),surface reactivity in the air and in aqueous solutions, sorption potentials for gold and other trace elements, and in chemical properties (Fe/S ratios, trace element contents). The principal objective of this cooperative research project was,therefore, to identify the relationships among the various properties of pyrite, and the relationships between the properties and the formational mechanisms of pyr … More ite. This objective was approached through systematic investigations on the properties of both synthetic and natural iron sulfide crystals formed under a variety of conditions. We were able to accomplish the objective.
The results of our research are expected to provide an important basis for the better use of pyrite in various industries, For example, in the electronic industry, some pyrite crystals may be developed as semiconductors, high energy batteries, and solar energy cells. In the mineral processing, petroleum, and coal industries, understanding the relationships between the properties and the formational environments of pyrite crystals will help developments of better methods for preferential removal of pyrite from other metal-bearing minerals, oils and coals. In environmental agancies, information on the behaviors of pyrite in aqueous solutions will be useful in controlling the weathering of pyrite at abandoned mine sites, which has been the main cause for acid drainages. In the mining industry, some properties of pyrite may be used for exploration of new mineral deposits, especially gold deposits. Less

Report

(3 results)
  • 1992 Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] S.R.Poulson and H.OHMOTO: "″An evaluation of the solubility of sulfide sulfur in silicatc mclts from cxpcrimental data and natural samples″" Chem.Geol. 85. 57-75 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.S Kim,Y.T.Kho,H.W.Pickering,and K.Osseo-Asare: "″Mass transfer effects on the anodic behavior of porous Fe and Co sintered electrodes in aqueous ammonical solution″" J.Electrochem.Soc.138. 1599-1607 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.MISHRA and K.Osseo-Asare: "″Electroreduction of Fe^<3+>,O_2,and Fe(CN)_6^<3->at the n-pyrite(FeS_2)surface″" J.Electrochem.Soc.139. 3116-3120 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Osseo-Asare: "″Semiconductor electrochemistry and hydrometallurgecal dissolution processes″" Hydrometallurgy. 29. 61-90 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.OHMOTO,K.HAYASHI,and Y.KAJISA: "″Experimental study of the solubilities of pyrite in NaCl-bearing aqueous solutions at250゚-350℃″" Geochim.Cosmochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] ONUMA,K.,TSUKAMOTO,K.,and NAKADATE,S.: "Application of real time phase shift interferometer to the measurement of concentration field" J.Crystal Growth.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.OHMOTO,C.J.Kaiser,and K.A.Geer: "Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemental deposits in StableIsotopes and Flued Processes in Mineralization,Herbert,H.M.and Ho,S.E.eds." The Univ.of Wetern Australia Publication, (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] TSUKAMOTO,K.: "In-situ observations of erystal growth processes,in VII European symqosium on materials and Nuid sciences in microgravity,Kaldeich,B.H.ed." (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.R Poulson and H. Ohmoto: "An evaluation of the solubility of sulfide sulfur in silicate malts from experimental data and natural samples" Chem. Geol.85. 57-75 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.S.Kim, Y.T.Kho,H.W.Pickering, and K.Osseo-Asare: "Mass transfer effects on the anodic behavior of porous Fe and Cosintered electrodes in aqueous ammonical solution" J.Electrochem.Soc.138. 1599-1607 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K. Mishra and K. Osseo-Asare: "Electroreduction of Fe^<3+>, O_2, and Fe(CN)_6^<3-> at the n-pyrite (FeS_2) surface" J. Electrochem. Soc.139. 3116-3120 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K. Osseo-Asare: "Semiconductor electrochemistry and hydrometallurgical dissolution processes" Hydrometallurgy. 29. 61-90 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H. Ohmoto, Hayashi, and Y. Kajisa: "Experimental study of the solubilities of pyrite in CaCl-bearing aqueous solutions at 250゚-350゚C" Geochim. Cosmochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Ohmoto, C.J.Kaiser, and K.A.Geer: The Univ.of Western Australia Publication. Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted basemental deposits in Stable Isotopes and Fluid Processes in Mineralization, Herbert, H.M.and Ho, S.E.eds., 23,70-120 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K. Tsukamoto: In-situ observations of crystal growth processes, in VII European symposium on materials and fluid sciences in microgravity, Kaldeich, B.H. ed., 561-563 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 塚本 勝男,小沼 一雄: "Dissolution kinetics of KーAlum crystals as judged from the mesurements of surface undersaturations." J.Crystal Growth. 110. 724-732 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 大本 洋,塚本 勝男,林 謙一郎: "Solubility and reaction kinetics of solutionーsolid reactions determined by in situ observations." Nature. 351. 634-636 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 林 謙一郎,大本 洋: "Solubility of gold in NaClーand H_2Sーbearing aqueous solutions at 250ー350 C." Geochimica et Cosmochimica Acta. 55. 2111-2126 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Osseo-Asare: "Semiconductor electrochemistry and hydrometallurgical dissolution processes." Hydrometallurgy. 29. 1-29 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Osseo-Asare K.K.Mishra: "Fermi level pinning at pyrite (FeS_2)/electrolyte junctions." J.Electrochemical Society. 139. 749-752 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Poulson H.Ohmoto: "Local-scale and regional scale geochemical behavior of sulfur in granitoids during the intrusion of the South Mountain batholith,Nova Scotia,Canada." Geochimica et Cosmochimica Acta. 55. 3809-3830 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Poulson,S.R.,大本 洋: "An evaluation of the solubility of sulfideーsulfur in silicate melts from experimental data and natural samples" Chemical Geology. 85. 57-75 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 春名 誠・上野 宏共,大本 洋: "Development of skarnーtype ores at the Tengumori copper deposit of the Kamaishi Mine,Iwate Prefecture,Northeastern Japan" Mining Geology. 40. 223-244 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 林謙 一郎・苣木 浅彦, 北風 嵐: "Solubility of sphalerite in aqueous sulfide solutions at temperatures between 25° and 24°C" Geochim.Cosmochim.Acta. 54. 715-725 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 小沼 一雄・塚本 勝男,砂川 一郎: "Growth kinetics of KーAlum crystals in relation to the surface supersaturations" J.Crystal Growth. 24. 123-132 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.S.Kim,Y.T.Kho,H.W.Pickering,K.OsseoーAsare: "Mass transfer effects on the anodic behavior of porous Fe and Co sintered electrodes in aqueous ammoniacal solution" J.Electrochem.Soc.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.T.Kho,K.OsseoーAsare,H.W.Pickering: "Anodic behavior of iron in ammoniacal ammonium carbonate solution.I.Steadyーstate polarization and cyclic voltammetry" J.Electrochem.Soc.

    • Related Report
      1990 Annual Research Report
  • [Publications] 大本 洋,C.T.Kaiser,K.A.Geer: "Systematics of sulfur isotopes in recent marine sediments and ancient sedimentーhosted basemetal deposits.In "Stable Isotopes and Fluid Processes in Mineralization"" The Univ.of Western Australia Publication, 70-120 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.OsseoーAsare,F.J.Arriagada: "Synthesis of nanosize particles in reverse micromeulsions.In "Ceramic Power Science III"" American Ceramic Society, 3-16 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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