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Exploring Study of Novel Properties in Artificially Stacked Materials Grown by van der Waals Epitaxy

Research Project

Project/Area Number 02102002
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Research InstitutionUniversity of Tokyo

Principal Investigator

KOMA Atsushi  Univ. of Tokyo, Faculty of Science, Professor, 理学部, 教授 (00010950)

Co-Investigator(Kenkyū-buntansha) UENO Keiji  Univ. of Tokyo, Faculty of Science, Research Associate, 理学部, 助手 (40223482)
TADA Hirokazu  Univ. of Tokyo, Faculty of Science, Research Associate, 理学部, 助手 (40216974)
SAIKI Koichiro  Univ. of Tokyo, Faculty of Science, Associate Professor, 理学部, 助教授 (70143394)
AOKI Hideo  Univ. of Tokyo, Faculty of Science, Associate Professor, 理学部, 助教授 (50114351)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥220,000,000 (Direct Cost: ¥220,000,000)
Fiscal Year 1992: ¥45,000,000 (Direct Cost: ¥45,000,000)
Fiscal Year 1991: ¥60,000,000 (Direct Cost: ¥60,000,000)
Fiscal Year 1990: ¥115,000,000 (Direct Cost: ¥115,000,000)
Keywordsvan der Waals Epitaxy / Artificially Stacked Materials / STM / Organic Thin Films / Lavered Materials / Modulated Structure / Interface / ファンデルワールス・エピタキシー / 層状物集 / ファンデルワ-ルス・エピタキシ- / ヘテロ構造 / C_<60> / 有機超薄膜 / 超格子 / ファンデルワ-ルスエピタキシ- / 原子モアレ縞 / RHEED振動
Research Abstract

This project has been fulfillled to create new artificially stacked materials made of highly heterogeneous layrs and to explore novel properties they show. By extending the idea of van der Waals epitaxy developed by us we have succeeded to grow various kinds of heterostructures. The concept of dangling bond termination has made it possible to grow many layred materials on such ordinary three-dimensional materials as GaAs and Si. Good epitaxial films of fullerene and many organic molecular meterials have also been fabricated successfully. Success in heteroepitaxy between lattice-mismatched alkali halides or polar organic materials on alkali halide by using electrostatic interaction has also increased the possible combination of materials in heteroepitaxy. New properties found and investigated in the present project include moiree-type modulation in STM image, polytype and charge density state formations in ultrathin films, control of optical properties of phthalocyanien films by stacking and anomaly in surface polariton dispersion in ultrathin epitaxial films of alkali halides. Crystal growth, crystal structure, electronic properties, superconductivity dielectric properties in the artificially stacked structures have been investigated theoretically by means of Monte Carlo study, Band, calculation, Quantum Monte Carlo study of analytical method. The occurrence of superconductivity due to nonretarded attraction has been demonstrated in a class of repulsively interacting electron systems that consist of a carrier band interacting with an insulting band.

Report

(4 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] B.A.Parkinson,F.S.Ohuchi,K.Ueno and A.Koma: "Periodic Lattece Distortions as a Result of Lattice Mismatch Epitaxial Films of Two-Dimensional Materials" Appl.Phys.Lett.58. 472-474 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Tada,T.Kawaguchi and A.Koma: "Epitaxial Growth of Vanady-Phthalocyanine Ultrathin Films on Hidrogen-Terminated Si(111)Surfaces" Appl.Phys.Lett.61. 2021-2023 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] M.Sakurain,H.Tada,K.Saiki A.Koma,H.Funasaka and Y.Kishimoto: "Epitaxial Growth of C_<70> Films on GaSe(0001) and MoS_2(0001) Surfaces" Chem.Phys.Lett.208. 425-430 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Shimada,Y.Furukawa,E.Arakawa,K.Takeshita,T.Matsushita,H.Yamamoto and A.Koma: "Structure Determination of Ultrathin NbSe_2 Films by Grazxing Incidence X-ray Diffraction" Solid State Commun.89. 583-586 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kuroki and H.Aoki: "Superconductivity in Metal-Insulator Composite Bands : A Realization of Negative-U Pairing in Purely Repulsive Systems" Phys.Rev.B48. 7598-7617 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] N.Shima and H.Aoki: "Electronic Structure of Superhoneycomb Systems : A Peculiar Realization of Semimetal/Semiconductor Classes and Ferromagnetism" Phys.Rev.Lett.71. 4389-4392 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] B.A.Parkinson, F.S.Ohuchi, K.Ueno and A.Koma: "Periodic Lattice Distortions as a Result of Lattice Mismatch in Epitaxial Films of Two-Dimensional Materials" Appl.Phys.Lett.58. 472-474 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Tada, T.Kawaguchi and A.Koma: "Epitaxial Growth of Vanadyl-Phthalocyanine Ultrathin Films on Hydrogen-Terminated Si (111) Surfaces" Appl.Phys.Lett.61. 2021-2023 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] M.Sakurai, H.Tada, K.Saiki A.Koma, H.Funasaka and Y.Kishimoto: "Epitaxial Growth of C_<60> and C_<70> Films on GaSe (0001) and MoS_2 (0001) Surfaces" Chem.Phys.Lett.208. 425-430 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Shimada, Y.Furukawa, E.Arakawa, K.Takeshita, T.Matsushita, H.Yamamoto and A.Koma: "Structure Determination of Ultrathin NbSe2 Films by Grazxing Incidence X-ray Diffraction" Solid State Commun.89. 583-586 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kuroki and H.Aoki: "Superconductivity in Metal-Insulator Composite Bands : A Realization of Negative-U Pairing in Purely Repulsive Systems" Phys.Rev.B48. 7598-7617 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] N.Shima and H.Aoki: "Electronic Structure of Superhoneycomb Systems : A Peculiar Realization of Semimetal/Semiconductor Classes and Ferromagnetism" Phys.Rev.Lett.71. 4389-4392 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Mori,K.Saiki and A.Koms: "Atom Intensity Variation in the Scanning Tumeling Microscoge Image of Miyed Crystals of Tyansition Metel Dichslcogenidas" Jpn.J.Aqgl.Phys.31. L1370-L1372 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Koms: "Van dev Warls Eqitsxy -A New Epitsxial Growts Method for a Highly Lattiu-Mismatched System-" Thim Solid Films. 216. 72-76 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Koms: "New EQitaxial Growth Method for Modulcti,Structnres Using Van der Waels Interacrions" Surlnce Science. 267. 29-33 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Ueno,H.Abe,K.Saki,A.Koma,H.Oigawa and Y.Nanmichi: "Hefevo-ejitexy of Layered Compoind Sem:conductor Gase onto GaAs surfaces for Very Eflective Pass.vation of Nanometn Structare" Surface Science. 267. 43-46 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Tada,T.Kawaguchi and A.Komi: "Epitrxial Growth of Vanadyl-phthalocyanine Ultrathin Films on Hydrogen-Terminated Si(111)Surtacos" Aqgl.Phys.Letl.61. 2021-2023 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kuroki and H.Aoki: "Realization of Negative-U Superconductivity in a class of Purely Requlsive Systems" Phys.Rev.Letl.69. 3820-3823 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Koma,K.Ueno and K.Saiki: "Heteroepitaxial Growth by van der Waals Interaction in One-,Two-and Three-dimensional Materials" J.Crystal Growth. 111. 1029-1032 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Saiki,Y.Nakamura and A.Koma: "Heteroepitaxial Growth of KCI and LiF on a Cleaved Face of KBr" Surf.Sci.250. 27-32 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Ueno,H.Abe,K.Saiki and A.Koma: "Heteroepitaxy of Layered Semiconductor GaSe on a GaAs(111)B Surface" Jpn.j.Appl.Phys.30. L1352-L1354 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Sakurai,H.Tada,K.Saiki and A.Koma: "Van der Waals Epitaxial Growth of C60 Film on a Cleaved Face of MoS_2" Jpn.J.Appl.Phys.30. L1892-L1894 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Kuroki and H.Aoki: "Superconductivity in a Two Band Hubbard System with Inter-Band Attraction" Physica C. 185-189. 1453-1454 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Kusakabe and H.Aoki: "Low-lying Excitations in the Half-Filled and Doped Hubbard Model in One Dimension" Phys.Rev.B. 44. 7863-7869 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Shimada,H.Yamamoto,K.Saiki,and A.Koma: "RHEED Intensity Dscillation during Epitaxial Growth of Layered Materials" Jpn.J.Appl.Phys.29. L2096-L2098 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.Koma: "Heteroepitaxy between LatticeーMismatched Materials with van der Waals Interactions" Mat.Res.Soc.Symp.Proc.198. 105-110 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] F.S.Ohuchi,B.A.Parkinson,K.Ueno,and A.Koma: "van der Waals Epitaxial Growth and Characterization of MoSe_2 Thin Films on SnS_2" J.Appl.Phys.68. 2168-2175 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] B.A.Parkinson,F.S.Ohuchi,K.Ueno,and A.Koma: "Periodic Lattice Distortions as a Result of Lattice Mismatch in Epitaxial Films in TwoーDimentional Materials" Appl.Phys.Leff.58. 472-474 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Tada,K.Saiki,and A.Koma: "Preparation and Characterization of VanadylーPhthalocyanine Ultrathin Films Grown on KBr and KCl by Molecular Beam Epitaxy" Jpn.J.Appl.Phys.30. L306-L308 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Aoki and K.Kuroki: "Superconductivity in a TwoーBand Hubbard Model" Phys.Rev.B. 42. 2125-2136 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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