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分子機能制御のための電子授受の設計

Research Project

Project/Area Number 02230103
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionOsaka University

Principal Investigator

村田 一郎  大阪大学, 理学部, 教授 (90028077)

Co-Investigator(Kenkyū-buntansha) 中筋 一弘  分子科学研究所, 教授 (60028230)
杉本 豊成  京都大学, 工学部, 助教授 (30093256)
小林 啓二  東京大学, 教養学部, 教授 (50012456)
小田 雅司  大阪大学, 理学部, 教授 (60004438)
伊東 〓  徳島文理大, 薬学部, 教授 (00004242)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥30,000,000 (Direct Cost: ¥30,000,000)
Fiscal Year 1990: ¥30,000,000 (Direct Cost: ¥30,000,000)
Keywordsチエピン / NADーNADHモデル / プライアデンキノン / ペンタフルベン / チエノアセン / ジセレナピレン / 含硫黄トリメチレンメタン / CTー錯体
Research Abstract

1.熱的に極めて不安定な母体チエピンを鉄カルボニル錯体として安定な黄色結晶として単離する事が出来た。この合成にはチエピンスルホン錯体を一電子還元剤であるSn12での還元が含まれており、この還元はスルホンからスルフィドへの一般的な変換方法となり得るものである(村田)。2.NADーNADHモデルとしてニコチン酸アミド部分を組み込んだ15,18ージメトキシー9ーメチルー9ーアザ[3.3]メタシクロファンー5ーカルボアミドを合成し、完全にシン型として存在する事を明らかにした。現在その還元力を検討中である(伊東)。4.チエノアセンを構造修飾した電子授受系を合成した。この中でチエノアセンを利用した新しいアクセプタ-のヨウ化銅錯体は、これ迄に例のない新しいタイプの高電導性錯体である事が明らかとなった。また剛直部分構造を持つチエノアセンは優れたホマト分子となる事が判った(小林)。3.新しいキノンとしてプライアデンー8,11ーキノンの合成に成功し、ベンゾキノンに匹敵する電子受容能をもつ事を明らかにし、そのテトラシアノキノジメタン類縁体の合成を行った。またペンタフルベンオリゴマ-の合成とその有機電導体としての展開を図った(小田)。5.CT錯体に基づく有機磁性体の構成分子として1,3ージチオ-ル[3]ラジアレンと同じC3対称をもつ含硫黄トリメチレンメタンのジカチオンを安定な塩として単離した。このジカチオンの二電子還元で生成するトリメチレンメタンのスピン状態を調べた(杉本)。6.有機分子性金属開発の一環として新しいドナ-である1,6ージセレナピレンを合成し、その各種電荷移動錯体の物性を検討した。また水素結合の特性を利用した電荷移動錯体の開発として拡張共役キンヒドロンの設計・合成を行った(中筋)。

Report

(1 results)
  • 1990 Annual Research Report

Research Products

(47 results)

All Other

All Publications (47 results)

  • [Publications] Tomoo Nakazawa: "Synthesis and Properties of 3ーSubstituted 8Hー3ーAzaheptalenー8ーones" Chem.Lett.91-92 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Kazuhiro Nakasuji: "Synthesis and Properties of 3,9ーDithiaperylene.A Third Isomer of PeriーCondensed Weitz Type Donors based on the perylene Skeleton" J.Chem.Soc.,Chem.Commun.366-367 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Hideaki Hori: "Ein monocyclisches Selenepin: Synthese und Charakerisierung von 2,7ーDiーtertーbutylー4,5ーselenepindicarbonsaurediethylester" Angew.Chem.102. 450-451 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shigeharu Wakabayashi: "Novel Products in the Reaction of 6ーCyanotricyclo[5.5.0.0^<2,5>]dodeca 3,6,9,12ーtetraene with 2,3ーDichloroー5,6ーdicyanoー1,4ーbenzoquinone" J.Chem.Soc.Perkin I. 1489-1490 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Toshikazu Kitagawa: "Amphoteric Redox Nature of pーBenzoquinones with Donor and Acceptor Substituents" Chem.Lett.897-900 (1999)

    • Related Report
      1990 Annual Research Report
  • [Publications] William E.Acree,Jr,: "Polycyclic Aromatic Hydrocarbons and Polycyclic Aromatic Sulfur Heterocycles: Examination of Molecular StructureーFluorescense Probe Character Correlations" Appl.Spectrosc.44. 951-957 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Satoshi Inagaki: "Conformational Adaptation: A New Aspect of Substituent Effects" Bull.Chem.Soc.Jpn.63. 2099-2100 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Atsushi Kawamoto: "Crystal and Electronic Structures of Radical Salts of 2,7ーBisー(methylthio)ー1,6ーdithiapyrene (MTDTPY) and 2,7ーBis(methylseleno)ーー1,6ーdithiapyrene (MSDTPY)" Bull.Chem.Soc.Jpn.63. 2137-2145 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Atsushi Kawamoto: "Electronic Structures of 2,7ーBis(methylthio)ー1,6ーdithiapyrene (MTDTPY) ChargeーTransfer Complexes" Bull.Chem.Soc.Jpn.63. 2146-2149 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Yuriko Aoki: "Molecular Orbital Study on the Electron Donating and Accepting Abilities of NonーAlternant Polycyclic Conjugated Hydrocarbons" Tetrahedron. 46. 6659-6672 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Keitaro Nishino: "Synthesis and Thermal Stability of 2ーMethylー1ーbenzothiepine" Chem.Express. 5. 853-856 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shigeru Sasaki: "Synthesis of a Highly Amphoteric 8,16ーDiisopropylーsーindaceno [1,2,3ーcd;5,6,7ーc'd']diphenalene: Switching Between Diatropism and Paratropism Accompanied by its Oxidation levels" Angew.Chem.103. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Nakasato,H.Hioki,S.Ito: "Synー[2.2]metacyclophaneー5,13ーdicarbaldhydes.Synthesis,spectra and thermal stability." Tetrahedron letters.

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Ito,C.Hashimoto and H.Hioki: "15,18ーDimethoxyー9ーmethylー9ーaza[3.3]metacyclophane,a NAD model." Tetrahedron Letters.

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "Synthesis of synーSubstituted Triptycenes viaーHeteroatomーdirected Metallation" J.Chem.Soc.,Chemical Communications. 339-340 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "6ーDimethylaminoー6ーlithofulvene,a Novel 6ーFulvenyl Anion of Potential Synthetic Utility" Tetrahedron Letters,. 31. 545-548 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Masahiko Iyoda: "NickelーCatalyzed cyclodimerization of Hexapentaenes: 4 Radialenes and 5 Radialenones with Cumulated Double Bonds" Angew.Chem.Int.Ed.Engl.29. 1062-1064 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "Generation,Characterization,and Reactions of Fulvene Dianions" Chemistry Letters. 1683-1686 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Masahiko Iyoda: "Thermal and Nickelーcatalyzed Dimerization of Hexapentaene.Synthesis of Two 4 Radialenes with Planar,Stable Cyclobutadieneーlike Geometry" Chemistry Letters. 2149-2152 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Shigeru Murata: "Reaction of Bicyclo 6.3.0 undecaー2,4,6,8,11ーpentaenー10ーylidene in OxygenーDoped Matrices: Characterization of the First Carbonyl Oxide with a ーDonating Ring System" J.Org.Chem.55. 4502-4504 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Masaji Oda: "Novel Thermal Decarbonylative Dimerization of 1,2,3,4,5,6ーHexahydrobenzo 1,2;4,5 dicyclobuteneー3,6ーdione" Tetrahedron Letters. 31. 7341-7342 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Keiji Okada: "A Simple and Convenient Photodecarboxylation Method of Intact Carboxylic Acids in the Presence of Aza Aromatic Compounds" J.Photobiol.A.

    • Related Report
      1990 Annual Research Report
  • [Publications] Takashi Kumagai: "Preparative Derivatization of endoーDicyclopentadiene via Metallation" Bull.Chem.Soc.Jpn.

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "8,11ーDihydropleiadeneー8,11ーdione.A New Pleiadenequinone having Considerable Electron Affinity"

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "Synthesis of 2ーCyclopentadienylideneー2Hーthiapyran by Novel Reductive Rearrangement of a 6ーThienylfulvene"

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeshi Kawase: "A New Synthesis of 1,4,5,8ーAnthradiquinones"

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Saito: "Tetramerized Structure of (DMET)_2ReO_4 and Its Apparent Metallic Behavior in Resistivity." Bull.Chem.Soc.Jpn.63. 1865-1870 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Murata: "Physical Properties and Crystal Structures of DMET Superconductors and Conductors." “The Physics and Chemistry of Organic Superconductors" ed.by G.Saito and S.Kagoshima,SpringerーVerlag,Berlin. 230-233 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Murata: "Superconductivity and Spin Density Waves in (DMET)_2Au(CN)_2" “The Physics and Chemistry of Organic Superconductors" ed.by G.Saito and S.Kagoshima,SpringerーVerlag,Berlin. 234-237 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Saito: "Phase Transition of the Organic Metal (DMET)_2Au(CN)_2" “The Physics and Chemistry of Organic Superconductors" ed.by G.Saito and S.Kagoshima,SpringerーVerlag,Berlin. 238-241 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Kanoda: "Antiferromagnetic Transitions in (DMET)_2X and (DMPT) and (DMPT)_2X." “The Physics and Chemistry of Organic Superconductors" ed.by G.Saito and S.Kagoshima,SpringerーVerlag,Berlin. 242-245 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] I.Ikemoto: "Organic Superconductors,(DMET)_2X." Mol.Cryst.Liq.Cryst.181. 185-195 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Ishikawa: "Structure of the Organic Superconductor (DMET)_2AuCl_2." Acta Cryst.C46. 1652-1655 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Ishikawa: "Crystal Structure of the Organic Metal (DMET)_2BF_4." Bull.Chem.Soc.Jpn.64. 212-215 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Harada: "Characterization of Organic UltraーThin Films by Penning Ionization Electron Spectroscopy During Layerーbyーlayer Preparation." Surf.Sci.

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Kobayashi: "Linearly Condensed Polythiophenes; Characteristic Molecular Aggregation." J.Am.Chem.Soc.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Mazaki: "A New Host Series for HostーGuest Inclusion Complexes." J.Chem.Soc.,Chem.Commun.

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Mazaki: "Thermal and Photochemical formation of Quinonoid Derivatives of Linearly Condensed Polythiophenes." Tetrahedron Lett.

    • Related Report
      1990 Annual Research Report
  • [Publications] Z.Yoshida,T.Sugimoto,and Y.Misaki: "Electronーdonating Radialenes.Potential Donors for (Super)Conductors and Ferromagnets" Materials Research Society Symposium Proceedings. 173. 3-14 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Sugimoto,K.Ikeda,and J.Yamauchi: "Tris(ethylenedithio)ー and Tris(1,2ーbenzodithio)ーsubstituted Trimethylenemethanes" Chemistry Letters. 29-32 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Sugimoto,A.Kawachi,K.Ikeda,and J.Yamauchi: "Synthesis of Tetrakis(1,2ーbenzodithio)tetramethyleneethane Dication Salt and Its Twoーelectron Reduction" Chemistry Letters. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Kitagawa: "Amphoteric Pedox Nature of pーBenzoquinones with Donorー and AcceptorーSubstituents" Chem.Lett.897-900 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Nakasuji: "Synthesis and Properties of 3,9ーDithiaperylene: A Third Isomer of PeriーCondensed WeitzーType Donors Based on the Perylene Skeleton" J.Chem.Soc.,Chem.Commun.366-367 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Inagaki: "Conformational Adaptation: A New Aspect of Substituent Effects" Bull.Chem.Soc.Jpn.63. 2099-2100 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.Kawamoto: "Crystal Structure and Electronic Structure of Radical Salts of 2,7ーBis(methylthio)ー1,6ーdithiapyrene (MTDTPY) and 2,7ーBis(methylseleno)ー1,6ーdithiapyrene (MSDTPY)" Bull.Chem.Soc.Jpn.63. 2137-2145 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.Kawamoto: "Electronoic Structure of 2,7ーBis(methylthio)ー1,6ーdithiapyrene (MTDTPY) Charge Transfer Complexes" Bull.Chem.Soc.Jpn.63. 2146-2149 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] W.E.Acree: "Polycyclic Aromatic Hydrocarbons and Polycyclic Aromatic Sulfur Heterocycles: Examination of Molecular StructureーFluorescence Probe Character Correlations" Appl.Spectrosc.44. 951-957 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-03-31   Modified: 2016-04-21  

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