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Study on the Methods Based upon Separation Chemistry for Intensive Improvements in Trace Analysis

Research Project

Project/Area Number 02303005
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionHiroshima University

Principal Investigator

KUMAMARU Takahiro  Hiroshima Univ., Fac. Sci., Prof., 理学部, 教授 (50033816)

Co-Investigator(Kenkyū-buntansha) KURODA Rokuro  Chiba Univ., Fac. Eng., Prof., 工学部, 教授 (50009198)
AKAIWA Hideo  Gunma Univ., Fac. Eng., Prof., 工学部, 教授 (60008414)
KAWASHIMA Takuji  Univ. Tsukuba, Dep. Chem., Prof., 化学系, 教授 (50041760)
SUZUKI Nobuo  Tohoku Univ., Fac. Sci., Prof., 理学部, 教授 (10006025)
TAGA Mitsuhiko  Hokkaido Univ., Fac. Sci., Prof., 理学部, 教授 (90000778)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥9,500,000 (Direct Cost: ¥9,500,000)
Fiscal Year 1991: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1990: ¥6,300,000 (Direct Cost: ¥6,300,000)
KeywordsCharacterization / Trace Analysis / Ion Exchange / Separation Chemistry / Solvent Extraction / Coprecipitation / Ion Flotation / On-Line Separation And Enrichment / イオン交換 / 共同沈澱
Research Abstract

Intensive developments of separation-speciation chemistry and related highly sensitive analytical techniques have been jointly investigated by thirteen analytical chemists, because of scientific significance of characterization of materials and speciation of trace elements in environmental materials. In order to achieve the goal five themes have been attacked.
1. Palladium compounds and/or albumin-enhanced GF-AAS for IIIB-IVB metals, and highly sensitive titrimetry with catalytic reaction have been developed.
2. Syntheses of metal specific resins, chelating resins, new chelating agents and their evaluation from view points of trace characterization have worked out.
3. Novel extraction system for anionic species, and new approaches on the design of extractive separation scheme based on HSAB rule or extraction behavior are established.
4. Dynamic ion-exchange separation of adjacent rare earths, enrichment of copper as the DTC complex on various membrane filters, selective preconcentration of rare earth metals by substoichiometric precipitaion of calcium oxalate and its application to neutron activation analysis, and preconcentration of anionic species by macromolecular ion flotation of anionexchange resin are also accomplished.
5. On-line preconcentration and separation methods are developed for highly sensitive and selective determination of trace elements by atomic or molecular spectrometry.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (105 results)

All Other

All Publications (105 results)

  • [Publications] Yayoi Miyata: "Determination of Manganese by folw injection analysis based on its catalytic effect on the oxidative coupling reaction of 3-methy1-2-benzothiazoline hydrazone with N,N-dimethylaniline" Anal.Sci.7. 97-101 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Tsutomu Katsura: "Enhancement effect of palladium and albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomec absorption spectrometry" Anal.Sci.8. 97-98 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Shigekazu Tsurubou: "Liquid-liquid extraction of cinchona alkaloids by using some metal complexes of optically pure usnic acids" Anal.Chim.Acta. 248. 501-506 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kikuo Terada: "Preconcentration of trace elements by sorption" Anal.Sci.7. 187-198 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kazuhisa Moriyasu: "Chemical analysis of thortveitite from Oro,Mineyama-cho,Naka-gun,Kyoto prefecture,Japan," Bull,Chem.Soc.Jpn.64. 2908-2911 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kin-ichi Tsunoda: "Separation of some metal thiothenoyltrifluoroacetone and their pyridine base adducts by reversed phase HPLC" Chem.Lett.1990. 1793-1796 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Shoji Motomizu: "Sensitivity enhancement in the spectrophotometric determination of silicate by a flotation-exchange-extraction method using an ion associate" Analyst〔London〕. 115. 1627-1630 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Rokuro Kuroda: "Ion-exchange chromatography of glycolatocomplexes of rare earths" Chromatographia. 32. 65 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Mitsuhiko Taga: "Determination of the complex species of copper (II) with humic acid by batch operation using cation-exchanger sulfopropyl Sephadex C-25" Anal.Sci.6. 611-612 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Nobuo Suzuki: "Synergic extraction of lanthanoid (III) with 2-thenoyltrifluoroacetone and triphenylarsine oxide in benzene" J.Radioanal.Nucl.Chem.149. 149-159 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Tomozo Koh: "A preconcentration method for spectrophotometric determination of thiocyanate by means of macromolecular ion flotation" Anal.Sci.6. 893-898 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kitao Fujiwara: "Flame spectrophotometric determination of borate based on diborane generation" Anal.Chim.Acta. 246. 413-419 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takahiro Kumamaru: "High enrichment method for the determination of ultra-teace Levels of cobalt by liquid-liquid extraction using water/oil/water emulsions as liquid surfactant membranes" Anal.Chim.Acta. 232. 389-391 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yasuaki Okamoto: "Electrodialysis pre-treatment system for ion chromatography of strongly acidic sapmples and its application to the determination of magnesium and calcium" J.Chromatogr.539. 221-224 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Terufumi Fujiwara: "Catalytic behavior of iron (III)-8-quinolinol complx in the chemiluminescence reaction of luminol with hydrogen peroxide in reverse micelles" Chem.Lett.1991. 1137-1140 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Imdadullah: "Chemiluminescence from the reaction of chloroauric acid with luminol in reverse micelles" Anal.Chem.63. 1348-1352 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yasuaki Okamoto: "Determination of cadmium by inductively coupled plasma atomic emission spectrometry after suction-flow on-line preconcentration on 8-quinolinol-loaded active carbon" Anal.Sci.7. 879-882 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Etsuro Iwamoto: "Determination of tin by electrothermal atomic absorption spectrometry with a tungsten-coated tube" J.Anal.At.Spectrom.7. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 河嶌 拓治: "ポイント分析化学演習ー基礎と計算ー" 広川書店, (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 内海 喩: "基礎教育 分析化学実験<第2版>" 東京教学社, 261 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 赤岩 英夫: "分析化学" 丸善, (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 黒田 六郎: "フロ-インジェクション分析法" 共立出版, 194 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 多賀 光彦: "教養の現代化学" 三共出版, 160 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 日本化学会編: "実験化学講座(第4版)、分析" 丸善, 509 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yayoi Miyata: "Determination of Manganese by flow injection analysis based on its catalytic effect on the oxidative coupling reaction of 3-methyl-2-benzothiazoline hydrazone with N, N-dimethylaniline" Anal. Sci.7. 97-101 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Tsutomu Katsura: "Enhancement effect of palladium and albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal. Sci.8. 97-98 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Shigekazu Tsurubou: "Liquid-liquid extraction of cinchona alkaloids by using some metal complexes of optically pure usnic acids" Anal. Chim. Acta. ij,. 501-506 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kikuo Terada: "Preconcentration of trace elements by sorption" Anal. Sci.7. 187-198 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kazuhisa Moriyasu: "Chemical analysis of thortveitite from Oro, Mineyama-cho, Naka-gun, Kyoto prefecture, Japan" Bull. Chem. Soc. Jpn.64. 2908-2911 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kin-ichi Tsunoda: "Separation of some metal thiothenoyltrifluoroacetone and their pyridine base adducts by reversed phase HPLC" Chem. Lett.1990. 1793-1796 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Shoji Motomizu: "Sensitivity enhancement in the spectrophotometric determination of silicate by a flotation-exchange-extraction method using an ion associate" Analyst[London]. 115. 1627-1630 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Rokuro Kuroda: "Ion-exchange chromatography of glycolatocomplexes of rare earths" Chromatographia. 32. 65 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Mitsuhiko Taga: "Determination of the complex species of copper (II) with humic acid by batch operation using cation-exchanger sulfopropyl Sephadex C-25" Anal. Sci.6. 611-612 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Nobuo Suzuki: "Synergic extraction of lanthanoid (III) with 2-thenoyltri-fluoroacetone and triphenylarsine oxide in benzene" J. Radioanal. Nucl. Chem.149. 149-159 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Tomozo Koh: "A preconcentration method for spectrophotometric determination of thiocyanate by means of macromolecular ion flotation" Anal. Sci.6. 893-898 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kitao Fujiwara: "Flame spectrophotometric determination of borate based on diborane generation" Anal. Chim. Acta. 246. 413-419 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takahiro Kumamaru: "High enrichment method for the determination of ultratrace Levels of cobalt by liquid-liquid extraction using water/oil/water emulsions as liquid surfactant membranes" Anal. Chim. Acta. 232. 389-391 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yasuaki Okamoto: "Electrodialysis pre-treatment system for ion chromatography of strongly acidic samples and its application to the determination of magnesium and calcium" J. Chromatogr.539. 221-224 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Terufumi Fujiwara: "Catalytic behavior of iron (III)-8-quinolinol complex in the chemiluminescence reaction of luminol with hydrogen peroxide in reverse micelles" Chem. Lett.1991. 1137-1140 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Imdadullah: "Chemiluminescence from the reaction of chloroauric acid with luminol in reverse micelles" Anal. Chem.63. 1348-1352 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yasuaki Okamoto: "Determination of cadmium by inductively coupled plasma atomic emission spectrometry after suction-flow on-line preconcentration on 8-quinolinol-loaded active carbon" Anal. Sci.7. 879-882 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Etsuro Iwamoto: "Determination of tin by electrothermal atomic absorption spectrometry with a tungsten-coated tube" J. Anal. At. Spectrom.7. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Mitsuhiko Taga: Sankyo Syuppan. "Modern Chemistry for General Arts College",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takuji Kawashima: Hirokawa Shoten. "Point exercise in Analytical Chemistry - Basic concepts and Calculations",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Rokuro Kuroda: Kyoritsu Syuppan. "Flow Injection Analysis",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Chemical Society of Japan: Maruzen. "Experimental Chemistry Series (4th Ed.), Analysis",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Satori Utsumi: Tokyo Kyogasu-sya. "Introduction to Experimental Analytical Chemistry",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Hideo Akaiwa: Maruzen. "Analytical Chemistry",

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Yayoi Miyata: "Determination of Manganese by flow indection analysis based on its catalytic effect on the oxidative coupling reaction of 3ーmethylー2ーbenzothiazoline hydrazone with N,Nーdimethylaniline" Anal.Sci.7. 97-101 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Tsutomu Katsura: "Enhancement effect of palladium and albumin on the sensitivities of group IIIBーVIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.8. 97-98 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Shigekazu Tsurobou: "Liquieーliquid extraction of cinchona alkaloids by using some metal complexes of optically pure usnic acids" Anal.Chim.Acta. 248. 501-506 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Kikuo Terada: "Preconcentration of trace elements by sorption" Anal.Sci.7. 187-198 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Kazuhisa Moriyasu: "Chemical analysis of thortveitite from Oro,Mineyamaーcho,Nakaーgun,Kyoto prefecture,Japan," Bull.Chem.Soc.Jpn.64. 2908-2911 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Yasoo Itoh: "Synergist induced potentiometric responese of liquid membranes containing chelating agents" Anal.Sci.7. 947-950 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Shoji Motomizu: "Porous membrane permiation of halogens and its application to the determination of halide ions and residual chlorine by flow injection analysis" Anal.Chim.Acta.

    • Related Report
      1991 Annual Research Report
  • [Publications] Rokuro Kuroda: "Ionーexchange chromatography of glycolatocomplexes of rare earths" Chromatographia. 32. 65 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Mitsuhiko Taga: "Evaluation of copper(II)ーbinding of humic acids in peat using sulphopropylーsephadex Cー25 cation exchanger" Anal.Chim.Acta. 244. 281-288 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Nobuo Suzuki: "Synergic extraction of lanthanoid(III) with 2ーthenoyltrifluoroacetone and triphenylarsine oxide in benzene" J.Radioanal.Nucl.Chem.149. 149-159 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Tomozo Koh: "Spectrophotometric determination of sulfide at the 10^<ー6>mol 1^<ー1> level by Solvent extraction of Silver(I)with methylene blue" Anal.Sci.

    • Related Report
      1991 Annual Research Report
  • [Publications] Kitao Fujiwara: "Flame spectrophotometric determination of borate based on diborane generation" Anal.Chim.Acta. 246. 413-419 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Yasuaki Okamoto: "Electrodialysis preーtreatment system for ion chromatography of strongly acidic samples and its application to the determination of magnesium and calcium" J.Chromatogr.539. 221-224 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Terufumi Fujiwara: "Catalytic behavior of iron(III)ー8ーquinolinol complex in the chemiluminescence reaction of luminol with hydrogen peroxide in reverse micelles" Chem.Lett.1991. 1137-1140 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Imdadullah: "Chemiluminescence from the reaction of chlorauric acid with luminol in reverse micelles" Anal.Chem.63. 1348-1352 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Yasuaki Okamoto: "Detrmination of cadmium by inductively coupled plasma atomic emission spectrometry after suctionーflow onーline preconcentration on 8ーquinolinolーloaded active carbon" Anal.Sci.7. 879-882 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Etsuro Iwamoto: "Determination of tin by electrothermal atomic absorption spectrometry with a tungstenーcoated tube" J.Anal.At.Spectrom.7. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takahiro Kumamaru: "Measurements of isotope ratios of antimony and lead by hybride generation inductively coupled plasma mass spectrometry" Analyst[London].

    • Related Report
      1991 Annual Research Report
  • [Publications] 河嶌 拓治: "ポイント分析化学演習ー基礎と計算ー" 広川書店, (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 内海 喩: "基礎教育 分析化学実験〈第2版〉" 東京教学社, 261 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 赤岩 英夫: "分析化学" 丸善, (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 多賀 光彦: "教養の現代化学" 三共出版, 160 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 日本化学会編: "実験化学講座(第4版)、分析" 丸善, 509 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 日本化学会編: "標準化学用語辞典" 丸善, (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kumamaru: "High Enrichment Method for the Determination of UltraーTrace Levels of Cobalt by LiquidーLiquid Extraction Using Water/Oil/Water Emulsions as Liquid Surfactant Membranes" Anal.Chim.Acta. 232. 389-391 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Okamoto: "Graphite Furnace Atomic Absorption Spectrometric Determination of UltraーTrace Levels of Cobalt after Solvent Extraction with W/O/W Emulsions as Liquid Surfactant Membranes" Anal.Sci.6. 401-405 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Okamoto: "Determination of Vanadium and Titanium in Steel by InductivelyーCoupled Plasma Atomic Emission Spectrometry with Modified Use of Tungsten Boat Furnace Atomizer for Atomic Absorption Spectrometry" Anal.Chim.Acta. 239. 139-143 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Okamoto: "Electrodialysis Pretreatment of Strongly Acidic Samples for the IonーChromatographic Determination of Magnesium and Calcium" J.Chromatogr.

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Kanke: "Determination of Arsenic by Graphite Furnace Atomic Absorption Spectrometry Combined with LiquidーLiquid Extraction of Arsenomolybdic Acid" Anal.Chim.Acta.

    • Related Report
      1990 Annual Research Report
  • [Publications] E.Iwamoto: "GraphiteーFurnace AtomicーAbsorption Spectrometry with GraphiteーCloth Ribbon and its Applicability to Determination of Arsenic in Biological Materials" Talanta.

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Fujiwara: "Catalytic Behavior of Iron(III)ー8ーquinolinol Complex in the Chemiluminescence Reaction of Luminol with Hydrogen Peroxide in Reverse Micelles" Chem.Lett.

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Tanaka: "Adsorption Accumulation Voltammetry of Copper(II) Using Complex Formation Reaction with Salicylideneaminoー2ーthiophenol" Fresenius'J.Anal.Chem.338. 898-901 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Kan: "Fluorophotometric Determination of Phosphate after Collection on Membrane as the Ion Pair of Molybdophosphate with Rhodamine 6G" Anal.Sci.7. 87-91 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] F.Jitoh: "Substoichiometric Speciation for Inorganic Arsenic and Methylated Arsenic and Its Application to Samples of Marine Organisms" Anal.Chim.Acta. 228. 85-91 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Iwata: "Coprecipitation Equilibrium of Lanthanoid(III) Ions with Calcium Oxalate" Anal.Sci.6. 753-756 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Ozutsumi: "Structure of Iron(III)ーTiron Complexes in Aqueous Solution" Anal.Sci.6. 573-577 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Miyata: "Determination of Manganese by Flow Injection Analysis Based on Its Catalytic Effect on the Oxidative Coupling Reaction of 3ーMethylー2ーBenzothiazolinone Hydrazone with N,NーDimethylaniline" Anal.Sci.7. 97-101 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Kawamoto: "Chelate Extraction Constant Based on HSAB Rule" Chem.Lett.1451-1454 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Tsunoda: "Separation of Some Metal Thiothenoyltrifluoroacetonates and Their Pyridine Base Adducts" Chem.Lett.1793-1796 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] R.Kuroda: "Determination of Trace Concentrations of Indium in Silicate Rocks by Graphite Furnace Atomic Absorption Spectrometry" Analyst(London). 115. 1535-1537 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Katsura: "Sensitivity Enhancement by OrganoーPalladium Complexes for Graphite Furnace Atomic Absorption Spectrometry of Alkyltin Compounds in Organic Solvent" Anal.Sci.6. 909-910 (1990)

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  • [Publications] T.Katsura: "Sensitivity Enhancement by OrganoーPalladium Complexes for Graphite Furnace Atomic Absorption Spectrometry of Alkyltin Compounds in Organic Solvent and Its Application to the Determination of Total Tin Fluted from Ship Paints" Anal.Chim.Acta.

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  • [Publications] T.Koh: "Spectrophotometric Determination of Trace Amounts of Sulphide and Hydrogen Sulphide by Formation of Thiocyanate" Analyst(London). 115. 1133-1137 (1990)

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      1990 Annual Research Report
  • [Publications] T.Koh: "A Preconcentration Method for Spectrophotometric Determination of Thiocyanate by Means of Macromolecular Ion Flotation" Anal.Sci.6. 893-898 (1990)

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  • [Publications] A.Hase: "Preconcentration of Trace Metals with DithiocarbamateーChitin" Anal.Sci.6. 747-751 (1990)

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  • [Publications] I.Suzuki: "Vacuum Sublimation Behavior of Nickel(II),Palladium(II),and Platinum(II) Chelates with Dimethylglyoxime" Bull.Chem.Soc.Jpn.63. 3686-3688 (1990)

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  • [Publications] S.Umetani: "Adduct Formation Properties of Monoーand Bidentate Phosphine Oxide Compounds in the LiquideーLiquid Extraction of Some Divalent Metals with 1ーPheny1ー3ーMethy1ー4ーBenzoy1ー5ーPyrazolone" Anal.Chim.Acta.232. 293-299 (1990)

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  • [Publications] H.Mukai: "Steric Effect of OrthoーSubstituents of 1ーPheny1ー3ーMethy1ー4ーAroy1ー5ーPyrazolones on the Synergic Extraction of Lutetium with Trioctylphosphine" Anal.Chim.Acta.239. 277-282 (1990)

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  • [Publications] 守安 一久: "ヒドロキシイミノジ酢酸キレ-ト樹脂の合成と希土類金属イオンの捕集・分離特性" 分析化学. 39. 475-480 (1990)

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  • [Publications] 山本 善大: "II,III族およびスズー8ーキノリンチオレ-トの蛍光特性とその分析化学への適用" 日本化学会誌. 26-29 (1990)

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  • [Publications] H.Kubota: "LiquidーLiquid Extraction Behavior of Inorganic and Organic Anions with ColorーChangeable Neutral Extractants" Anal.Sci.6. 737-745 (1990)

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  • [Publications] S.Motomizu: "Spectrophotometric Determination of Calcium with Dicyclohexanoー24ーCrownー8 and Propyl Orange by Solvent Extraction/Flow Injection Method" Anal.Sci.6. 215-220 (1990)

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  • [Publications] K.Fujiwara: "Coprecipitation of Trace Metals by DNA and RNA Molecules" Anal.Chem.62. 504-508 (1990)

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  • [Publications] K.Fujiwara: "Flame Photometric Detection of Borate Coupled with Diborane Generation Technique" Anal.Chim.Acta.

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  • [Publications] 多賀 光彦: "教養の現代化学" 三共出版, (1991)

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  • [Publications] 黒田 六郎: "フロ-インジェクション分析法" 共立出版, 182 (1990)

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  • [Publications] 南 茂夫: "分光技術ハンドブック" 朝倉書店, 14 (1990)

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      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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