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Study of the effect of turbulent mixing on chemical reaction in liquid

Research Project

Project/Area Number 02402026
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field Fluid engineering
Research InstitutionNagoya University

Principal Investigator

NAKAMURA Ikuo  Nagoya Univ.,Mech.Eng.,Professor, 工学部, 教授 (00023127)

Co-Investigator(Kenkyū-buntansha) YAMASHITA Shintaro  Gifu Univ.,Mech.Eng.,Professor, 工学部, 教授 (20023236)
TSUNODA Hiroyuki  Nagoya Univ.,Mech.Eng.,Research Associate, 工学部, 助手 (10207433)
KUSHIDA Takehiro  Nagoya Univ.,Mech.Eng.,Research Associate, 工学部, 助手 (90109281)
SAKAI Yasuhiko  Nagoya Univ.,Mech.Eng.,Associate Professor, 工学部, 助教授 (20162274)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥32,100,000 (Direct Cost: ¥32,100,000)
Fiscal Year 1992: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1991: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 1990: ¥27,300,000 (Direct Cost: ¥27,300,000)
KeywordsChemical Reaction / Turbulent Mixing / Coaxial Jets / Concentration / Multicomponent / Laser Velocimeter / Stochastic Model / Random Fourier Mode / レ-ザ流速計 / ランダムフ-リエモ-ド法
Research Abstract

In order to clarify the effect of turbulent mixing on the chemical reaction occurring in liquid, the researches were performed both experimentally and computationally. Chemical reaction, simple but suited to optical measurement and selected is the type; A + B * R,B + R * S (the azo coupling of 1-naphthol (A) with diazotised sulfanilic acid (B) in dilute, aqueous, alkaline buffered solution). The optical fiber probe with the core diameter of 10 mum has been anew developed to measure the instantaneous concentrations of chemical products (R and S) at a spatial point. The improved concentration measuring system of multiple species was also fitted up. As the fundamental research,the turbulent jet of species B into species A was investigated. At first, the mean velocity and velocity fluctuation rms profiles were measured using the fiber type of LDV system purchased. Next, various statistical properties of the concentration fields of chemical products R and S (the mean value, fluctuation rms … More value, correlation between R and S, pdf, etc.) were investigated in detail.
As the research on the mixing process in the turbulent pipe flow, the diffusion field of single species from the continuous point source on the wall was measured. The turbulence in the pipe (Inner diameter D=100 mm, the length of the test section 2000 mm, Reynolds number Re=U<@D2m@>D2D/nu (] SY.simeq.[) 20000, U<@D2m@>D2: maximum mean velocity) was not fully developed but the radial profile of the mean velocity is almost self-similar in the downstream direction. By examining the contours of the iso-mean concentration and iso-concentration fluctuation rms values, the spread of the plume was also clarified.
With regards to the numerical simulation, the diffusion of fluid particle around a circular cylinder was investigated by the combined model of random Fourier modes and random flight. The molecular mixing models of the passive scalar in turbulent flow were also examined by the PDF method. To compare these numerical results with experiments, the disturbance effect of a sphere on the plume developed in grid-turbulence was investigated experimentally. From the fractal analysis, it is elucidated that the flow distortion due to the sphere is not effective to the change of the fractal dimension. The mixing process of two species in the case of coaxial jet was also examined. Less

Report

(4 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] Yasuhiko SAKAI: "Diffusion of fluid particles by the combined model of random fourier modes and random flight" JSME International Journal.Ser.II. 35. 497-506 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 劉 身健: "プルーム拡散場のマルチフラクタル性およびそれに対する球による変形の影響" 日本機械学会論文集(B編). 58. 1707-1714 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 酒井 康彦: "球による流れ場の変形の軸対称プルーム拡散場の構造に対する影響" 日本機械学会論文集(B編). 58. 1731-1738 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 酒井 康彦: "2粒子対確率過程モデルによる変動スカラー場の数値シミュレーション" 日本機械学会論文集(B編). 58. 3087-3093 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Hiroyuki TSUNODA: "The Effect of a Circular Cylinder on the Diffusion of Matter by a Plume" Journal of Fluid Mechanics. 246. 419-442 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 酒井 康彦: "液中化学反応に及ぼす乱流混合の影響に関する研究" 日本機械学会東海支部第42期総会講演会講演論文集. 933-1. 116-118 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SAKAI, Shengjian LIU, Hiroyuki TSUNODA & Ikuo NAKAMURA: "On the statistics of a Point-Source Plume around a Sphere" Trans.Japan Soc.Mech.Eng. Vol.58,No.541,B. 51-58 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SAKAI,Shengjian LIU,Hiroyuki TSUNODA & Ikuo NAKAMURA: "Distortion Effects of Flow due to a Sphere on the Structure of Axisymmetric Diffusing Plume" Trans.Japan Soc.Mech.Eng. Vol.58,No.550,B. 1731-1738 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Shengjian LIU,Yasuhiko SAKAI,Hiroyuki TSUNODA & Ikuo NAKAMURA: "Multifractal Feature of Diffusing Plume and Effect of Distortion of Flow due to a Sphere on It" Trans.Japan Soc.Mech.Eng. Vol.58,No.550,B. 1707-1714 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SAKAI,Hiroyuki TSUNODA,Takeshi SUZUKI & Ikuo NAKAMURA: "Numerical Simulation of the Scalar Fluctuation Field by the Two-Particle Stochastic Process Model" Trans.Japan Soc.Mech.Eng. Vol.58,No.554,B. 3087-3093 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Hiroyuki TSUNODA,Stephen B.POPE & Ikuo NAKAMURA: "On Molecular Mixing Model for PDF Equation of a Passive Scalar in Turbulent Flow" Proc.of the Chugoku-Shikoku Branch Conf.of Japan Soc.Mech.Eng. No.295-2. 70-72 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SASAKI,Julian C.R.HUNT & Jimmy C.H.FUNG: "Diffusion of Fluid Particles by the Combined Model of Random Fourier Modes and Random Flight" JSME Int.Journal,Series II. Vol.35,No.4. 497-506 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Hiroyuki TSUNODA,Yasuhiko SAKAI,Ikuo NAKAMURA & Shengjian LIU: "The Effect of a Circular Cylinder on the Diffusion of Matter by a Plume" Journal of Fluid Mech. Vol.246. 419-442 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SAKAI,Hiroyuki TSUNODA,Masafumi YAMADA & Ikuo NAKAMURA: "A Fundamental study on the Influence of Turbulent Mixing on Chemical Reaction in Liquid" Proc.of the Tokai Branch Conf.of Japan Soc.Mech.Eng. No.993-1. 116-118 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Yasuhiko SAKAI: "Diffusion of fluid particles by the combined model of random fourier modes and random flight" JSME Inteonational Journal.Ser.II. 35. 497-506 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 劉 身健: "プルーム拡散場のマルチフラクタル性およびそれに対する球による変形の影響" 日本機械学会論文集(B編). 58. 53-60 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 酒井 康彦: "2粒子対確率過程モデルによる変動スカラ場の数値シミュレーション" 日本機械学会論文集(B編). 58. 141-147 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 酒井 康彦: "ランダムフ-リエモ-ドとランダムフライトモデルの複合モデルによる流体粒子の拡散に関する研究" 日本機械学会論文集B編. 57. 1673-1980 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 中村 育雄: "流れの変形が点源拡散に及ぼす影響について(変動速度、濃度場の考察と実験)" 流体熱工学研究. 25. 19-28 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] 劉 身健: "球前方のプル-ム拡散場の特性について" 日本機械学会論文集B編. 57. 2976-2983 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 酒井 康彦: "球周辺のプル-ム拡散場の統計的特性について" 日本機械学会論文集B編. 58. 51-58 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 酒井 康彦: "球による流れ場の変形の軸対称プル-ム拡散場の構造に対する影響" 日本機械学会論文集B編.

    • Related Report
      1991 Annual Research Report
  • [Publications] 中村 育雄: "円管内流における物質の乱流拡散に関する実験的研究" 日本機械学会論文集B編.

    • Related Report
      1991 Annual Research Report
  • [Publications] 角田 博之: "2粒子相関モデルによる連続点源乱流拡散の数値シミュレ-ション" 第22回乱流シンポジウム講演論文集(日本流体力学会誌9巻別冊). 9巻別冊. 87-92 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 山下 新太郎: "二次元チャンネル流の空間線形安定計算による流れ特性と混合過程" 第22回乱流シンポジウム講演論文集(日本流体力学会誌9巻別冊). 9巻別冊. 209-213 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 酒井 康彦: "ランダムフ-リエモ-ドとランダムフライトの複合モデルによる流体粒子の拡散に関する研究" 日本機械学会論文集(B編). 57. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Yasuhiko SAKAI: "Development of an optical fiber type of fluctuation concentration measuring system of multiple species by the light absorption spectrometric method" Experiments in Fluids.

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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