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Development of Crystal Structure Analysis due to Convergent-Beam Electron Diffraction

Research Project

Project/Area Number 02402055
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 結晶学
Research InstitutionTohoku University

Principal Investigator

TANAKA Michiyoshi  Tohoku University Research Institute for Scientific Measurements, 科学計測研究所, 教授 (90004291)

Co-Investigator(Kenkyū-buntansha) TERAUCHI Masami  Tohoku University Research Institute for Scientific Measurements, 科学計測研究所, 助手 (30192652)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥29,600,000 (Direct Cost: ¥29,600,000)
Fiscal Year 1991: ¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1990: ¥23,400,000 (Direct Cost: ¥23,400,000)
KeywordsConvergent-Beam Electron Diffraction / Crystal Structure Analysis / Point Space Groups / Imaging Plates / Signal Processing
Research Abstract

This imaging plate (IP) has the following advantages for the detection of the election beam : (1) High sensitivity to small electron dose, (2) wide dynamic range, (3) linearity of sensitivity, (4) high precision digital images and (5) dry system. We have applied the IP to the convergent-beam electron diffraction (CBED) and obtained the following results.
(a) It has been shown that the IP is effective to detect the symmetry of CBED patterns. As an example, very weak 200 and equivalent reflections of GaAs were recorded by the IP at the 001 incidence. These reflections all very important for the symmetry study of the material, and had not been recorded clearly by conventional photo films due to the back ground noise. The IP recording and successive image processing of the reflections enable us to reveal the symmetry formed by the 200 and equivalent reflections.
(b) The symmetry of CBED patterns has been quantitatively examined for the first time. The symmetry of CBED pattern has been judged … More by human eyes but has not ever been studied quantitatively. Two reflections which are connected by a symmetry operation were compared. Intensity of one reflection is subtracted from that of the other and the value of R=ROO<SIGMA(I_1-I_2)^2/SIGMAI_1^2> is calculated. It was revealed that a CBED pattern of <111> Si, which is a typical example of good symmetry, showed a value of R<similar or equal>10 %. Human eyes recognize the breakdown of symmetry when CBED patterns which have a value of R beyond 20 %.
(c) The displacement vector of a stacking fault can be determined by analyzing the intensity profiles of reflections appearing in CBED patterns. The IP is quite useful to record the intensities of profiles accurately. The displacement vectors of stacking faults in Si and TiO_2 could be reliably determined by applying IP.
(d) One of the final goal of CBED is the crystal structure analysis, which requires precise intensity measurements. The IP is indispensable to develop the crystal structure analysis using CBED. Firstly, we tried to solve the crystal structure of the low temperature phase of SrTiO_3, or the rotation angle of the oxygen octahedron and the Debye-Waller factor. The computer analysis program using a nonlinear least-square method (SALS) was developed. Using the intensity data recorded by IP and the analysis program, the rotation angle of the oxygen octahedron was determined to be 1.12 <plus-minus> 0.04゚. The value shows a good agreement with that obtained by the electron-spin resonance method. Secondary, the crystal structure of the intermediate phase of the hexagonal BaTiO_3, which had been remained unsolved, was determined under the guide of the result of the soft-mode analysis. These results strongly promise the success of the crystal structure analysis of a small specimen area using CBED. Less

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] M.Tanaka: "Characterization of icosahedral quasicrystals by convergent-beam electron diffraction" Sci.Rep.of RITU.A36. 159-170 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Tanaka,M.Terauchi and T.kaneyama: "Identification of lattice defects by convergent-beam electron diffraction" J.Electron Microscopy. 40. 211-220 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Saito,M.Tanaka: "Space group determination of decagonal quasicrystals of an AL_<70>Ni_<15>Fe_<15> alloy using convergent-beam electron diffraction" Jpn.J.Appl.Phys.31. L109-L112 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 寺内 正己,田中 通義: "収束電子回折法による4次元空間群の決定" 日本結晶学会誌. 34. 11-18 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Tanaka,K.Tsuda,M.Terauchi: "Electron diffraction and electron microscope study of decagonal quasicrystals of Al-Ni-Fe alloys" J.Non-Crystalline Solids.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K.Tsuda and M.tanaka: "Crystal structure analysis of the low temperature phase of SrTiO_3 by convergent-beam electron diffraction" Acta.Cryst.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 田中 通義(三宅 静雄編): "実験物理学講座21「電子回折・電子分光」" 共立出版, 560 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 田中 通義(日本電子顕微鏡学会関東支部編): "先端材料評価のための電子顕微鏡技法" 朝倉書店, 382 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Tanaka: "Characterization of icosahedral quasicrystals by convergent-beam electron diffraction" Sci. Rep. of RITU.A36. 159-170 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Tanaka, M. Terauchi and T. Kaneyama: "Identification of lattice defects by convergent-beam electron diffraction" J. Electron Microscopy. 40. 211-220 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Saito, M. Tanaka: "Space group determination of decagonal quasicrystals of an Al_<70>Ni_<50>Fe_<15> alloy using convergent-beam electron diffraction" Jpn. J. Appl. Phys.31. L109-L112 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Tanaka, K. Tsuda, M. Terauchi: "Electron diffraction and electron microscope study of decagonal quasicrystals of Al-Ni-Fe alloys" J. Non-Crystalline Solids.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K. Tsuda and M. Tanaka: "Crystal structure analysis of the low temperature phase of SrTiO_3 by convergent-beam electron diffraction" Acta. Cryst.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Tanaka: "Characterization of icosahedral quasicrystals by convergentーbeam electron diffraction" Sci. Rep. of RITU.A36. 159-170 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Tanaka,M.Terauchi and T.Kaneyama: "Identification of Lattice defects by convergentーbeam electron diffraction" J. Electron Microscopy. 40. 211-220 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Saito,M.Tanaka…: "Space group determination of decagonal quasicrystals of an Al_<70>Ni_<15> alloy using convergentーbeam electron diffraction" Jpn. J. Appl. Phys.31. L109-L112 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 寺内 正己,田中 通義: "収束電子回折法による4次元空間群の決定" 日本結晶学会誌. 34. 11-18 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Tanaka,K.Tsuda,M.Terauchi…: "Electron diffraction and electron microscope study of decagonal quasicrystals of AlーNiーFe alloys" J. NonーCrystalline Solids.

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Tsuda and M.Tanaka: "Crystal Structure analysis of the low temperature phase of SrTiO_3 by convergentーbeam electron diffraction" Acta. Cryst.

    • Related Report
      1991 Annual Research Report
  • [Publications] 田中 通義(三宅 静雄 編): "実験物理学講座21「電子回折・電子分光」" 共立出版, 560 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 田中 通義(日本電子顕微鏡学会関東支部 編): "先端材料評価のための電子顕微鏡技法" 朝倉書店, 382 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Tsuda and M.Tanaka: "The use of imaging plates for cervergevtーbeam electron diffraction" J.of Electron Microscopy. 40. (1991)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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