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Unification of Solvolysis Mechanisisms

Research Project

Project/Area Number 02403010
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 有機化学一般
Research InstitutionKYUSHU UNIVERSITY (1991-1993)
Okazaki National Research Institutes (1990)

Principal Investigator

TSUNO Yuho  Kyushu University, Institute for Fundamental Research in Organic Chemmistry, Professor, 理学部, 教授 (10029845)

Co-Investigator(Kenkyū-buntansha) 藤尾 瑞枝  九州大学, 理学部, 助手 (10029887)
Project Period (FY) 1990 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥39,500,000 (Direct Cost: ¥39,500,000)
Fiscal Year 1993: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1992: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1991: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 1990: ¥27,500,000 (Direct Cost: ¥27,500,000)
KeywordsSolvolysis Mechanism / Ion-Pair Return / Ion-Pair Intermediates / O-18 Scrambling / Nucleophilic Displacement / Aryl-assisted Mechanism / Solvent Effect / Oー18スクランブリング / ソルボリシス / 反応機構 / ^<18>Oースクランブリング / 同位体化学シフト
Research Abstract

The splitting in the C-13 NMR signals, induced by isotopic oxygen substitution O-16/O-18, was utilized successfully to determine quantitatively the extent of O-18 scrambling within three oxygens in the sulfonate moiety. This method was applied to the investigation of return process in the solvolysis of various arylalkyl tosylates. The solvent dependency of (1-F) value in adamantyl solvolyses shows in good accordance with that of alpha-t-butylbenzyl one. Accordingly the ion-pair return scarcely affects the result of the solvent effect analysis of alpha-t-butyl benzyl solvolysis based on 2-adamantyl Y_<OTs>.
Despite the nucleophilically limiting nature of aryl-assisted and benzylic solvolyses, the solvent effect on these solvolyses failed to give a single linear correlation with the Winstein-Grunwald Equation, using the adamantyl Y_<OTs> but showed characteristic dispersion for various binary aqueous solvent series. Developing charge at the reaction center in the transition state of benzy … More lic k_c carbocationic process is highly delocalized through effective pi-overlapping with aryl group, and this may cause a significant loss of the highly oriented specific solvation at the reaction center in comparison with that for aliphatic localized 2-adamantyl cation. The solvent polarity scale Y_<DELTA> based on p-methoxyneophyl solvolysis combined with the Y_<OTs> has shown a wide applicability to the solvolyses of benzylic arylalkyl tosylates involving varying degree of pi-delocalization interaction with the incipient carbocation charge ; log (k/k_o) = aY_<OTs> + bY_<DELTA>. The equation can be applied to various series of aryl-assisted solvolyses in an extremely high precision, suggesting a continuous spectrum of k_c-k_<DELTA> mechanisms. Benzylic k_c solvolyses can also be treated with linear combination of Y_<OTs> and Y_<DELTA>. Application of revised equation, aY_<OTs> and bY_<DELTA> including cN_<OTs> term has also been extended to the nucleophilic solvolyses of alkyl and arylalkyl tosylates, with limited success, indicating no precise additivity for the nucleophilic solvent involvement. Less

Report

(5 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • 1991 Annual Research Report
  • 1990 Annual Research Report

Research Products

(188 results)

All Other

All Publications (188 results)

  • [Publications] M.Fujio: "Substituent Effects.XVIII.The Resonance Demand in the Acetolysis of Neophyl Brosylates" Bull.Chem.Soc.Jpn.63. 1121-1128 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] A.Murata: "Substituent Effects.XIX.Solvolysis of 1-Aryl-1-(trifluoromethyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.63. 1129-1137 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] A.Murata: "Substituent Effects.XX.Highly Electron Deficient-Carbocation Solvolyses" Bull.Chem.Soc.Jpn.63. 1138-1145 (1990)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects.XXI.Solvolysis of Benzyl Tosylates" Bull.Chem.Soc.Jpn.63. 1146-1153 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Substituent Effects.22.Substituent Effect on the Solvolysis of}-t-Butylbenzyl Tosylates" Bull.Chem.Soc.Jpn.63. 856-866 (1990)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Sawada: "Substituent Effects on ^<15>N and ^<17>O NMR Chemical Shifts in 4'-Substituted trans-NNO-Azoxybenzenes" Bull.Chem.Soc.Jpn.63. 702-707 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on Solvolysis of 1,2,2-Tris(p-Methoxyphenyl)vinyl Tosylate" Tetrahedron Lett.31. 7039-7042 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Neophyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 17(2). 255-266 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis Mechanism of 1,1,3,3-Tetramethylindan-2-yl Arenensulfonates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 17(2). 267-280 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Solvent Effect on the Solvolysis of α-t-Butylbenzyl Tosylate" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 17(2). 281-298 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effect on the Solvolysis of o-Methyl- and o,o-Dimethyl-}-t-Butylbenzyl Tosylates" Tetrahedron Lett. 32. 1805-1808 (1991)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Resonance Effect in the Solvolysis of α,α-di-t-Butylbenzyl p-Nitrobenzoates" Tetrahedron Lett.32. 2929-2932 (1991)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects in the Solvolysis of Benzyl Tosylates" J.Phys.Org.Chem.3. 449-455 (1990)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Substituent Effects.Stabilities of 1-Aryl-2,2,2-Trifluoroethyl Cations" Tetrahedron Lett.31. 685-688 (1990)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Thermodynamic Stabilities of Phenonium Ions in the Gas Phase" Chem.Lett.2277-2280 (1990)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Effect of Si-Si-σ-Bonds on Stability of Adjacent Benzylic Cations" Chem.Lett.1937-1940 (1990)

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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Butyllithium-induced syn-Elimination of 2-Arylalkyl p-Toluenesulfonates" Chem.Lett.2207-2208 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effects on the Gas Phase Basicity ofα,α,α-Trifluoroacetophenone.Intrinsic Nature of Resonance Demand" Chem.Lett.2281-2284 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of 2,2-Bis(aryl)ethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 63-74 (1991)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of Monosubstituted 2,2-Diphenylethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 75-90 (1991)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Goto: "The Substituent Effect on the Acetolysis of Unsymmetrically Disubstituted 2,2-Diphenylethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 91-108 (1991)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis of 1,1,3,3-Tetramethylindan-2-yl Sulfonates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 109-120 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects on the Solvolysis of Benzyl Chlorides" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 131-142 (1991)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "The Study of ^<18>O-Scrambling on the Solvolysis of α-t-Butylbenzyl Tosylate" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 121-130 (1991)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Stereoselective Synthesis of (E)- and (Z)-2-Alkenyltrimethylsilanes from 1,2-Epoxy-1,3-bis(trimethylsilyl)propane" Bull.Chem.Soc.Jpn.64. 1122-1128 (1991)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzyl p-Toluenesulfonates.α-Silicon Effect on the Stability of Benzylic Cations in Solution" Bull.Chem.Soc.Jpn.64. 1145-1152 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects.II.Structure and Stability of 1-Phenyl-2-(trimethylsiliyl)ethyl Cation in Solution" Bull.Chem.Soc.Jpn.64. 2249-2254 (1991)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects.III.Rates and Products for Solvolysis of α-(Pentamethyldisilanyl)benzyl Halides and 1,1,2,2-Tetramethyl-1,2-disilaindan-3-yl Chlorde.Structure and Stability of α-(Pentadisilanyl)benzyl Cation in Solution" Bull.Chem.Soc.Jpn.64. 3280-3288 (1991)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Cyclization of 4-Hydroxy-4-methyl-1-pentyl p-Toluenesulfonate as a Model to Evaluate Inherent Medium Effect on S_N2 Solvolysis" Chem.Lett.2065-2068 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effect on the Solvolysis of 2,2-Dimethylindan-1-yl Chlorides" Tetrahedron Lett.33. 321-324 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Unexalted Resonance Scale of Substituent Effect in the Benzylic Solvolysis" Tetrahedron Lett.33. 345-348 (1992)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Solvent Effects on the Solvolysis of α-t-Butylbenzyl Tosylate" Tetrahedron Lett.33. 349-352 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Neophyl Tosylates" Bull.Chem.Soc.Jpn.65. 46-54 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of 1-(p-Methoxyphenyl)-2-methylpropen-1-yl Tosylate" Tetrahedron Lett.33. 1309-1312 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of α-Trimethylsilylstyrenes.Intrinsic Effect of α-Trimethylsilyl Group on the Stability of Carbenium Ions" Chem.Lett.489-492 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of Acetophenones toward Trimethylsilyl Cation" Chem.Lett.493-496 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on the Gas Phase Basicity of Pyridine N-Oxide" Chem.Lett.1081-1084 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Substituent Effect on Basicity of Phenylacelene.Intrinsic Resonance Demand of Phenylvinyl Cation" Chem.Lett.1085-1088 (1992)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Watanabe: "Pyrolytic Elimination of 1-Aryl-2-(trimethylsilyl)ethyl Acetates via Two Distinct Pathways" Chem.Lett.655-656 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "A Quantitative Scale for the Structural Effect on Reactivity toward Nucleophilic Displacement at Silicon" Chem.Lett.65. 1263-1266 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "A Novel Configuration-Controlled Stereoselectivity in Enol Silylation of Ketones.Stereochemistry of Amine-Promoted Enol Silylation of Meso and Racemic α,α'-Dichloro Ketones and of Ketonization of the Resultant Enol Silyl Ethers" Bull.Chem.Soc.Jpn.65. 971-977 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects.IV.Solvolysis of 1-(Pentamethyldisilanyl)-2-phenylcyclopropy Bromide in 2,2,2-Trifluoroethanol via β(CC)-Assisted and -Unassisted Ionization Processes" Bull.Chem.Soc.Jpn.959-964 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvent Effect on the Solvolysis of Benzonorbornen-9(anti)-yl m-Nitrobenzenesulfonate" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 223-232 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Goto: "The Substituent Effect on Solvolyses of Neophyl m-Nitrobenzenesulfonates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 233-242 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 243-256 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of p-Nitro- and 3,5-Bis(trifluoromethyl)benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 257-266 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "The ^<18>O-Scrambling in the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 267-286 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] K.Nakata: "Substituent Effect on Gas Phase Stabilities of α-t-Butyl-α-methylbenzyl cations" 18(2). 287-296 (1992)

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      1993 Final Research Report Summary
  • [Publications] K.Nakata: "Solvent Effect on the Solvolysis of 2,2-Dimethylindan-1-yl-Chloride" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 297-312 (1992)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effects on the Solvolyses of threo-2-Aryl-1-methylpropyl Brosylates" Bull.Chem.Soc.Jpn.65. 3072-3079 (1992)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on the Gas Phase Basicity of α-t-Butylstyrene.Coplanarity and Resonance Demand of a Benzylic Carbocation" Chem.Lett.2435-2438 (1992)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of Styrenes toward Trimethylsilyl Cation.Structure and Stability of Me_3Si-Styrene+Complexes" Chem.Lett.2439-2442 (1992)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] F.Hayakawa: "Silicon Effects.V.β-Silicon Effect in the Solvolysis of 2-Phenylethyl Compounds" Bull.Chem.Soc.Jpn.66. 153-157 (1993)

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      1993 Final Research Report Summary
  • [Publications] S.D.Yoh: "Alkaline Hydrolysis of Substituted Benzyl Substituted Benzoates" J.Phys.Org.Chem.6. 23-28 (1993)

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      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Effect of the Twisted Nitro Group on Gas Phase Acidities of Phenol,Toluene,Aniline,and Benzoic Acid.Steric Inhibition of Intrinsic Resonance Effect" Chem.Lett.885-888 (1993)

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      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on Electron Affinity of 2,6-Dimethylnitrobenzene" Chem.Lett.889-892 (1993)

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      1993 Final Research Report Summary
  • [Publications] T.Asano: "Mechanism of Thermal Z/E Isomerization of Substituted N-Benzylideneanilines.Nature of the Activated Complex with a sp-Hybridized Nitrogen Atom" J.Org.Chem.58. 4418-4423 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "The Study of ^<18>O-Scrambling in the Menschutkin Reaction of p-Methylbenyl Tosylate with N,N-Dimethylanilines in Acetonitrile" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 19(1). 47-62 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] G.A.Ahmed: "Solvent Effects on the Solvolysis of Simple Alkyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 19(1). 63-80 (1993)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis of 1-Adamantylmethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 19(1). 81-96 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Electron Affinities of Benzaldehyde.Substituent Effects on Stabilities of Aromatic Radical Anions" Tetrahedron Lett.34. 4223-4226 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] S.Kobayashi: "Substituent Effect on Gas Phase Basicity of 1-Phenylpropyne.Thermodynamic Stability and Resonance Demand of 1-Phenylpropenyl Cations" Tetrahedron Lett.34. 5903-5906 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effect Studies of Aryl-assisted Solvolyses.I.The Acetolysis of 2,2-Bis(substitutedphenyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.66. 3015-3020 (1993)

    • Description
      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effect Studies of Aryl-assisted Solvolyses.II.The Acetolysis of 2-Phenyl-2-(substituted phenyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.66. 3021-3029 (1993)

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      1993 Final Research Report Summary
  • [Publications] S.-D.Yoh: "Nucleophilic Substitution Reaction and Elimination Reaction of 2-Phenylethyl Arenesulfonates" Bull.Korean Chem.Soc.14. 531-533 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Importance of Resonance Stabilization in the Benzylic Solvolysis.Substituent Effects on the Solvolysis of α,α-Diisopropylbenzyl Chlorides" Tetrahedron Lett.34. 8309-8312 (1993)

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      「研究成果報告書概要(和文)」より
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      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Kinetic Effects of Thiourea Addition on Benzylic Solvolyses" Tetrahedron Lett.35. 135-138 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects. XVIII.The Resonance Demand in the Acetolysis of Neophyl Brosylates" Bull.Chem.Soc.Jpn.63. 1121-1128 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] A.Murata: "Substituent Effects. XIX.Solvolysis of 1-Aryl-1-(trifluorometyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.63. 1129-1137 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] A.Murata: "Substituent Effects. XX.Highly Electron Deficient-Carbocation Solvolyses" Bull.Chem.Soc.Jpn.63. 1138-1145 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects. XXI.Solvolysis of Benzyl Tosylates" Bull.Chem.Soc.Jpn.63. 1146-1153 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Substituent Effects. 22. Substituent Effect on the Solvolysis of alpha-t-Butylbenzyl Tosylates" Bull.Chem.Soc.Jpn.63. 856-866 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Sawada: "Substituent Effects on ^<15>N and ^<17>O NMR Chemical Shifts in 4'-Substituted trans-NNO-Azoxybenzenes" Bull.Chem.Soc.Jpn.63. 702-707 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects in the Solvolysis of Benzyl Tosylates" J.Phys.Org.Chem.3. 449-455 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Substituent Effects. Stabilities of 1-Aryl-2, 2, 2-Trifluoroethyl Cations" Tetrahedron Lett. 31. 685-688 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Thermodynamic Stabilities of Phenonium Ions in the Gas Phase" Chem.Lett.1990. 2277-2280

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Effect of Si-Si sigma-Bonds on Stability of Adjacent Benzylic Cations" Chem.Lett.1990. 1937-1940

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Butyllithium-induced syn beta-Elimination of 2-Arylalkyl p-Toluenesulfonates" Chem.Lett.1990. 2207-2208

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effects on the Gas Phase Basicity of alpha, alpha, alpha-Trifluoroacetophenone. Intrinsic Nature of Resonance Demand" Chem.Lett.1990. 2281-2284

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Goto, M.Fujio: "Solvent Effects on Solvolysis of 1, 2, 2-Tris(p-Methoxyphenyl)vinyl Tosylate" Tetrahedron Lett. 31. 7039-7042 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on Solvolysis of Neophyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 17(2). 255-266 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis Mechanism of 1, 1, 3, 3-Tetramethylindan-2-yl Arenensulfonates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 17(2). 267-280 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Solvent Effect on Solvolysis of alpha-t-Butylbenzyl Tosylate" Mem.Fac.Sci., Kyushu Univ., Ser.C. 17(2). 281-298 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effect on the Solvolysis of o-Methyl- and o, o-Dimethyl-alpha-t-Butylbenzyl Tosylates" Tetrahedron Lett. 32. 1805-1808 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Resonance Effect on the Solvolysis of alpha, alpha-di-t-Butylbenzyl p-Nitrobenzoates" Tetrahedron Lett.32. 2929-2932 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of 2, 2-Bis(aryl)ethyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 63-74 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of Monosubstituted 2, 2-Diphenylethyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 75-90 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Goto: "The Substituent Effect on the Acetolysis of Unsymm. Disubstituted 2, 2-Diphenylethyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 91-108 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis of 1, 1, 3, 3-Tetramethylindan-2-yl Sulfonates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 109-120 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effects on the Solvolysis of Benzyl Chlorides" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 131-142 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "The Study of ^<18>O-Scrambling on the Solvolysis of alpha-t-Butylbenzyl Tosylate" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(1). 121-130 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Stereoselective Synthesis of (E)-and (Z)-2-Alkenyltrimethylsilanes from 1, 2-Epoxy-1, 3-bis(trimethylsilyl)propane" Bull.Chem.Soc.Jpn.64. 1122-1128 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Rates and Mechanism for the Solvolyses of 2, 2-Dimethyl-2-sila-1-indanyl Bromide and alpha-Trialkylsilylbenzyl p-Toluenesulfonates. alpha-Silicon Effect on the Stability of Benzylic Cations in Solution" Bull.Chem.Soc.Jpn.64. 1145-1152 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects. II.Structure and Stability of 1-Phenyl-2-(trimethylsiliyl)ethyl Cation in Solution" Bull.Chem.Soc.Jpn.64. 2249-2254 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects. III.Rates and Products for Solvolysis of alpha-(Pentamethyldisilanyl)benzyl Halides and 1, 1, 2, 2-Tetramethyl-1, 2-disilaindan-3-yl Chloride. Structure and Stability of alpha-(Pentadisilanyl)benzyl Cation is Solution" Bull.Chem.Soc.Jpn.64. 3280-3288 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Cyclization of 4-Hydroxy-4-methyl-1-pentyl p-Toluenesulfonate as a Model to Evaluate Inherent" Chem.Lett.1991. 2065-2068

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Substituent Effect on the Solvolysis of 2, 2-Dimethylindan-1-yl Chlorides" Tetrahedron Lett.33. 321-324 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Unexalted Resonance Scale of Substituent Effect in the Benzylic Solvolysis" Tetrahedron Lett.33. 345-348 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Solvent Effects on the Solvolysis of alpha-t-Butylbenzyl Tosylate" Tetrahedron Lett.33. 349-352 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Neophyl Tosylates" Bull.Chem.Soc.Jpn.65. 46-54 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of 1-(p-Methoxyphenyl)-2-methylpropen-1-yl Tosylate" Tetrahedron Lett.33. 1309-1312 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of alpha-Trimethylsilylstirenes. Intrinsic Effect of alpha-Trimethylsilyl Group on the Stability of Carbenium Ions" Chem.Lett.1992. 489-492

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of Acetophenones toward Trimethylsilyl Cation" Chem.Lett.1992. 493-496

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on the Gas Phase Basicity of Pyridine N-Oxide" Chem.Lett.1992. 1081-1084

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Substituent Effect on Basicity of Phenylacetylene. Intrinsic Resonance Demand of Phenylvinyl Cation" Chem.Lett.1992. 1085-1088

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Watanabe: "Pyrolytic Elimination of 1-Aryl-2-(trimethylsilyl)ethyl Acetates via Two Distinct Pathways" Chem.Lett.1992. 655-656

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "A Quantitative Scale for the Structural Effect on Reactivity toward Nucleophilic Displacement at Silicon" Chem.Lett.1992. 1263-1266

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "A Novel Configuration-Controlled Stereoselectivity in Enol Silylation of Ketones. Stereochemistry of Amine-Promoted Enol Silylation of Meso and Racemic alpha, alpha'-Dichloro Ketones and of Ketonization of the Resultant Enol Silyl Ethers" Bull.Chem.Soc.Jpn.65. 971-977 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Shimizu: "Silicon Effects. IV.Solvolysis of 1-(Pentamethyldisilanyl)-2-phenylcyclopropyl Bromide in 2, 2, 2-Trifluoroethanol via sigma(CC)-Assisted and -Unassisted Ionization Processes" Bull.Chem.Soc.Jpn.65. 959-964 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvent Effect on the Solvolysis of Benzonorbornen-9(anti)-yl m-Nitrobenzenesulfonate" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 223-232 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Goto: "The Substituent Effect on Solvolyses of Neophyl m-Nitrobenzenesulfonates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 233-242 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 243-256 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of p-Nitro- and 3, 5-Bis(trifluoromethyl)benzyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 257-266 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "The ^<18>O-Scrambling in the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 267-286 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Nakata: "Substituent Effect on Gas Phase Stabilities of alpha-t-Butyl-alpha-methylbenzyl Cations" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 287-296 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Nakata: "Solvent Effect on the Solvolysis of 2, 2-Dimethylindan-1-yl Chloride" Mem.Fac.Sci., Kyushu Univ., Ser.C. 18(2). 297-312 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effects on the Solvolyses of threo-2-Aryl-1-methylpropyl Brosylates" Bull.Chem.Soc.Jpn.65. 3072-3079 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on Gas Phase Basicity of alpha-t-Butylstirene. Coplanarity and Resonance Demand of a Benzylic Carbocation" Chem.Lett.1992. 2435-2438

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Gas Phase Basicities of Stirenes toward Trimethylsilyl Cation. Structure and Stability of Me_3Si-Stirene^+ Complexes" Chem.Lett.1992. 2439-2442

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] F.Hayakawa: "Silicon Effects. V.beta-Silicon Effect in the Solvolysis of 2-Phenylethyl Compounds" Bull.Chem.Soc.Jpn.66. 153-157 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.D.Yoh: "Alkaline Hydrolysis of Substituted Benzyl Substituted Benzoates" J.Phys.Org.Chem.6. 23-28 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Effect of the Twisted Nitro Group on Gas Phase Acidities of Phenol, Toluene, Aniline, and Benzoic Acid. Steric Inhibition of Intrinsic Resonance Effect" Chem.Lett.1993. 885-888

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Substituent Effect on Electron Affinity of 2, 6-Dimethylnitrobenzene" Chem.Lett.1993. 889-892

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Mishima: "Electron Affinities of Benzaldehyde. Substituent Effects on Stabilityes of Aromatic Radical Anions" Tetrahedron Lett.34. 4223 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Asano: "Mechanism of Thermal Z/E Isomerization of Substituted N-Benzylideneanilines. Nature of the Activated Complex with a sp-Hybridized Nitrogen Atom" J.Org.Chem.58. 4418 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Tsuji: "Study of ^<18>O-Scrambling in the Menschutkin Reaction of p-Methylbenyl Tosylate with N, N-Dimethylanilines in Acetonitrile" Mem.Fac.Sci., Kyushu Univ., Ser.C. 19(1). 47-62 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] G.A.Ahmed: "Solvent Effects on the Solvolysis of Simple Alkyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 19(1). 63-80 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Solvolysis of 1-Adamantylmethyl Tosylates" Mem.Fac.Sci., Kyushu Univ., Ser.C. 19(1). 81-96 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Kobayashi: "Substituent Effect on Gas Phase Basicity of 1-Phenylpropyne. Thermodynamic Stability and Resonance Demand of 1-Phenylpropenyl Cations" Tetrahedron Lett.34. 5903-5906 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effect Studies of Arylassisted Solvolyses. I.The Acetolysis of 2, 2-Bis(substituted phenyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.66. 3015-3020 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Substituent Effect Studies of Arylassisted Solvolyses. II.The Acetolysis of 2-Phenyl-2-(substituted phenyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.66. 3021-3029 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.-D.Yoh: "Nucleophilic Substitution Reaction and Elimination Reaction of 2-Phenylethyl Arenesulfonates" Bull.Korean Chem.Soc.14. 531-533 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fujio: "The Importance of Resonance Stabilization in the Benzylic Solvolysis. Substituent Effects on the Solvolysis of alpha, alpha-Disopropylbenzyl Chlorides" Tetrahedron Lett.34. 8309-8312 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Yatsugi: "Kinetic Effects of Thiourea Addition on Benzylic Solvolyses" Tetrahedron Lett.35. 135-138 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] F.Hayakawa: "Silicon Effects.V.beta-Silicon Effect in the Solvolysis of 2-PhenylethylCompounds" Bull.Chem.Soc.Jpn.66. 153-157 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.D.Yoh: "Alkaline Hydrolysis of Substituted Benzyl Substituted Benzoates" J.Phys.Org.Chem.6. 23-28 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Mishima: "Effect of the Twisted Nitro Group on Gas Phase Acidities of Phenol,Toluene,Aniline,and Benzoic Acid.Steric Inhibition of Intrinsic Resonance Effect" Chem.Lett.885-888 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Mishima: "Substituent Effect on Electron Affinity of 2,6-Dimethylnitrobenzene" Chem.Lett.889-892 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Mishima: "Electron Affinities of Benzaldehyde.Substituent Effects on Stabilities of Aromatic Radical Anions" Tetrahedron Lett.34. 4223-4226 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Asano: "Mechanism of Thermal Z/E Isomerzation of Substituted N-Benzylideneanilines.Nature of the Activated Complex with a sp-Hybridized Nitrogen Atom" J.Org.Chem.58. 4418-4423 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Tsuji: "The Study of 18O-Scrambling theMenschutkin Reaction of p-Methylbenyl Tosylate with N,N-Dimethylanilines in Acetonitrile" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 19(1). 47-62 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] G.A.Ahmed: "Solvent Effects on the Solvolysis of Simple Alkyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C22GD08:19(1). 63-80 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Yatsugi: "Solvolysis of 1-Adamantylmetyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 19(1). 81-96 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Kobayashi: "Substituent Effect on Gas PhaseBasicity of 1-Phenylpropyne.Thermodynamic Stability and Resonance Demand of 1-Phenylpropenyl Cations" Tetrahedron Lett.34. 5903-5906 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Fujio: "The Substituent Effect Studies of Aryl-assisted Solvolyses.I.The Acetolysis of 2,2-Bis(substituted phenyl)ethy Tosylates" Bull.Chem.Soc.Jpn.66. 3015-3020 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Fujio: "The Substituent Effect Studies of Aryl-assisted Solvolyses.II.The Acetolysis of 2-Phenyl-2-(substituted phenyl)ethyl Tosylates" Bull.Chem.Soc.Jpn.66. 3021-3029 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.-D.Yoh: "Nucleophilic Substitution Reaction and Elimimnation Reaction of 2-Phenylethyl Arensulfonates" Bull.Korean Chem.Soc.14. 531-533 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Fujio: "The Importance of Resonance Stabilization in the Benzylic Solvolysis.Substituent Effects on the Solvolysis of alpha,alpha-Diisopropylbenzyl Chlorides" Tetrahedron Lett.34. 8309-8312 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Yatsugi: "Kinetic Effects of Thiourea Addition on Benzylic Solvolyses" Tetrahedron Lett.34. 135-138 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Shimizu: "Silicon Effects.IV.b-Silicon Effect of Various Silyl Groups in Solvolysis for alpha-Alkylbenzyl and alpha-Silylbenzy Systems" Bull.Chem.Soc.Jpn.67. 500-504 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Mishima: "Substituent Effect on the Gas Phaee Basicity of Pyridine N-Oxide" Chem.Lett.1081-1084 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Mishima: "Gas Phase substituent Effect on Basicity of Phenylacetylene. Intrinsic Resonance Demand of Phenylvinyl Cation" Chem.Lett.1085-1088 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Yatsugi: "Solvent Effect on the Solvolysis of Benzonorbornen-9(anti)-yl m-Nitrobenzenesulfonate" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 257-266 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Goto: "The Substituent Effect on Solvolyses of Neophyl m-Nitrobenzenesulfonates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 233-242 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 243-256 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Fujio: "Solvent Effects on the Solvolysis of p-Nitro and 3,5-Bis(trifluoromethyl)benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 257-266 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Tsuji: "The 18 O-Scramlbing in the Solvolysis of Benzyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 267-286 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Natata: "Substituent Effect on Gas Phase Stabilities of α-t-Butyl-α-methylbenzyl cations" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 287-296 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Natata: "Solvent Effect on the Solvolyses of 2,2-Dimethylindan-1-yl Chloride" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(2). 297-312 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Fujio: "The Substituent Effect on the Solvolysis of threo-2-Aryl-1-methylpropyl Brosylates" Bull.Chem.Soc.Jan.65. 3072-3079 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Mishima: "Substituent Effect on the Gas Phase Basicity of α-Butylstyrene. Coplanarity and Resonance Demand of a Benzylic Carbocation" Chem.Lett.2435-2438 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Mishima: "Gas Phase Basicities of Styrenes toward Trimethylsilyl Cation. Structure and Stability of Me_3Si-Styrene Complexes" Chem.Lett.2439-2442 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.D.Yoh: "Alkaline Hydrolysis of Substituted Benzyl Substituted Benzoates" J.Phys.Org.Chem.6. 23-28 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Fujio: "Substituent Effects on the Solvolysis of Benzyl Chlorides" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 131-142 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of 2,2ーBis(aryl)ethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 63-74 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Maeda: "The Substituent Effect on the Acetolysis of Monosubstituted 2,2ーDiphenylethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 75-90 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Goto: "The Substituent Effect on the Acetolysis of Unsymmetrically Disubstituted 2,2ーDiphenylethyl Tosylates" Mem.Fac.Sci.,Kyushu Univ.,Ser.C. 18(1). 91-108 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] N.Shimizu: "Silicon Effects.III.Rates and Products for Solvolysis of αー(Pentamethyldisilanyl)benzyl Halides and 1,1,2,2ーTetramethylー1,2ーdislilaindanー3ーyl Chloride.Structure and Stability of αー(Pentadisilanyl)benzyl Cation in Solution" Bull.Chem.Soc.Jpn.64. 3280-3288 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Fujio: "Substituent Effect on the Solvolysis of 2,2ーDimethylindanーlーyl Chlorides" Tetrahedron Lett.33. 321-324 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Fujio: "The Unexalted Resonance Scale of Substituent Effect in the Benzylic Solvolysis" Tetrahedron Lett.33. 345-348 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Tsuji: "Solvent Effects on the Solvolysis of tーButylbenzyl Tosylate" Tetrahedron Lett.33. 349-352 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Fujio: "Solvent Effect on the Solvolysis of Neophyl Tosylates" Bull.Chem.Soc.Jpn.65. 46-54 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Fujio: "Solvent Effect on the Solvolysis of 1ー(pーMethoxyphenyl)ー2,2ーdimethylpropenー1ーyl Tosylate" Tetrahedron Lett.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Mishima: "Gas Phase Basicities of αーTrimethylsilylstyrenes.Intrinsic Effect of αーTrimethylsilyl Group on the Stability of Carbenium Ions" Chem.Lett.489-492 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Mishima: "Gas Phase Basicities of Acetop掃enones toward trimethylsilyl Cation" Chem.Lett.493-496 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Fujio,M.Goto,S.Susuki,M.Mishima,and Y.Tsuno,: "Substituent Effects in the Solvolysis of Benzyl Tosylates." J.Phys.Org.Chem.3. 449-455 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Mishima,H.Inoue,M.Fujio,and Y.Tsuno,: "Gas Phase Substituent Effects.Stabilities of 1ーArylー2,2,2ーtrifluoroethyl Cations." Tetrahedron Lett.31. 685-688 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Sawada,Y.Takai,T.Tanaka,T.Hanafusa,M.Okubo,and Y.Tsuno: "Substituent Effects on ^<15>N and ^<17>O NMR Chemical Shifts in 4'ーSubstituted transーNNOーAzoxybenzenes." Bull.Chem.Soc.Jpn.,. 63. 702-707 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Fujio,M.Goto,M.Mishima,and Y.Tsuno: "Substituent Effects.XVIII.The Resonance Demand in the Acetolysis of Neophyl Brosylates." Bull.Chem.Soc.Jpn.,. 63. 1121-1128 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.Murata,M.Goto,R.Fujiyama,M.Mishima,M.Fujio,and Y.Tsuno: "Substituent Effects.XIX.Solvolysis of 1ーArylー1ー(trifluoromethyl)ethyl Tosylates." Bull.Chem.Soc.Jpn.,. 63. 1129-1137 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.Murata,S.Sakaguchi,R.Fujiyama,M.Mishima,M.Fujio,and Y.Tsuno: "Substituent Effects.XX.Highly ElectronーDeficient Carbocation Solvolyses." Bull.Chem.Soc.Jpn.,. 63. 1138-1145 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Fujio,M.Goto,T.Susuki,I.Akasaka,M.Mishima,and Y.Tsuno: "Substituent Effects.XXI.Solvolysis of Benzyl Tosylates." Bull.Chem.Soc.Jpn.,. 63. 1146-1153 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Tsuji,M.Fujio,and Y.Tsuno,: "Substituent Effects.22.The Solvolysis of αーtーButylbenzyl Tosylates." Bull.Chem.Soc.Jpn.,. 63. 856-866 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Fujio,M.Goto,K.Funatsu,T.Yoshino,and Y.Tsuno: "Solvent Effects on the Solvolysis of Neophyl Tosylates." Mem.Fac.Sci.,Kyushu Univ.,Ser.C,. 17(2). 255-266 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Yatsugi,Y.Kikuta,Y.Tsuji,M.Fujio,and Y.Tsuno,: "Solvolysis Mechanism of 1,1,3,3ーTetramethylindanー2ーyl Arenesufonates." Mem.Fac.Sci.,Kyushu Univ.,Ser.C,. 17(2). 267-280 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Tsuji,M.Fujio,and Y.Tsuno,: "Solvent Effect on the Solvolysis of αーtーButylbenzyl Tosylate." Mem.Fac.Sci.,Kyushu Univ.,Ser.C,. 17(2). 281-298 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Masaaki Mishima,Yuho Tsuno,and Mizue Fujio: "Thermodynamic Stabilities of Phenonium Ions in the Gas Phase." Chem.Lett.,. 2277-2280 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Masaaki Mishima,Yuho Tsuno,and Mizue Fujio: "Substituent Effect on the Gas Phase Basicity of α,α,αーTrifluoroacetopheone.Intrinsic Nature of Resonance Demand." Chem.Lett.,. 2281-2284 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-03-31   Modified: 2016-04-21  

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