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High-Sensitivity Submillimeter-Wave Spectroscopy of Silicon-Containing Interstellar Molecules

Research Project

Project/Area Number 02452013
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Astronomy
Research InstitutionOkazaki National Institutes (1991)
Nagoya University (1990)

Principal Investigator

SAITO Shuji  Okazaki National Institutes, Institute for Molecular Science, Department of Molecular Structure, Professor, 分子科学研究所・分子構造研究系, 教授 (30106158)

Co-Investigator(Kenkyū-buntansha) YAMAMOTO Satoshi  Nagoya University, Department of Astrophysics, Research Associate, 理学部, 助手 (80182624)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥7,600,000 (Direct Cost: ¥7,600,000)
Fiscal Year 1991: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1990: ¥5,800,000 (Direct Cost: ¥5,800,000)
KeywordsMicrowave spectroscopy / Submillimeter-wave spectroscopy / Multiplier / Interstellar molecule / Radio telescope / Transient molecule / Free radical / Univdentified line / 含シリコン分子 / フリ-・ラジカル / サブミリ波
Research Abstract

The effective sensitivity of the microwave spectrometer was significantly improved by introducing a quadrupler for the 400 to 500 GHz region. A detailed study on the characteristics of the multiplier revealed that the quadrupler gives significant 5th component output power in the edge frequency regions specified. This enables us to carry out moderate-sensitivity spectroscopy in the frequency region between 500 and 650 GHz. We have studied several transient molecules, especially potential candidates for interstellar molecules by using the highsensitivity submillimeter-wave spectrometer combined with the multiplier.
1. Detection of new interstellar molecules : We assigned several unidentified lines, which were dbtected toward TMC-1 and IRC+10216 by Naobeyama 45 m telescope, to two new cumulene and carbone molecules, CH_2CCC and CH_2CC. The other two free radicals, SiN and HCCN, whose spectral lines we detected first in the laboratory, were also identified as new interstellar molecules by observations using IRAM and NRAO telescopes.
2. Spectroscopy of silicon-containing molecules : Three new silicon-containing transient species, C_2H_2Si, CH_2Si, and HSiO, were detected for the first time in the discharged plasma of a mixture of SiH_4, C_2H_2, and CO with laboratory submillimeter-wave spectroscopy. Their spectral lines were analyzed to give precise molecular constants, from which fundamental information for detailed molecular structures were derived.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] S.Takano: "Silicon Chemistry in the outer envelope of IRC+10216.The detailed distribution of SiC_2" The Astronomical Society of Japan. 44. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Yamamoto: "SiO in Barnard 1" The Astronomical Society of Japan. 44. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H.Mikami: "Detection of SiO Emission in the L1157 Dark Cloud" Astrophysical Journal. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Yamamoto: "The Microwave Spectrum of the CH_2N Radical in the X^2B_2 Ground Electronic State" Journal of Chemical Physics. 96. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K.Kawaguchi: "Observations of Cumulene Carbenes,H_2CCCC and H_2CCC,in TMC1" The Astronomical Society of Japan. 43. 607-619 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Takano: "Millimeter-Wave Spectra of the Aluminum Monosulfide Rakical)X^2Σ^+)" Journal of Chemical Physics. 94. 3355-3360 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Takano et al.: "Silicon Chemistry in the Outer Envelope of IRC+10216. The Detailed Distribution of SiCl_2" Publ. Astron. Soc. Japan. 44. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Yamamoto et al.: "SiO in Barnard 1" Publ. Astron. Soc. Japan. 44. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Mikami et al.: "Detection of SiO Emission in the L1157 Dark Cloud" Astrophys. J.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Yamamoto et al.: "The Microwave Spectrum of the CH_2N Radical in the X^2B_2 Ground Electronic State" J. Chem. Phys.96. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K. Kawaguchi et al.: "Observations of Cumulene Carbenes, H_2CCCC and H_2CCC, in TMC1" Publ. Astron. Soc. Japan. 43. 607-619 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Takano et al.: "Millimeter-wave Spectra of the Aluminum Monosulfide Radical (X^2SIGMA^+)" J. Chem. Phys.94. 3355-3360 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Kanada et al.: "The Microwave Spectrum of the ND_2 Radical" J. Chem. Phys.94. 3423-3428 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Mikami et al.: "The Microwave Spectrum of the Dihydronitrosyl Radical, H_2No ( ^2B_1)" J. Chem. Phys.94. 3415-3422 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Yamamoto et al.: "Rotational Spectrum of the CCS Radical Studied by Laboratory Microwave Spectroscopy and Radio-Astronomical Observations" Astrophys. J.361. 318-324 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] B. E. Turner et al.: "Interstellar Cyanomethane" Astrophys. J.355. 546-561 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] F. X. Brown et al.: "Microwave Spectroscopy of Isotopically Substituted HCCN and its Molecular Structure" J. Mol. Spectrosc.143. 203-208 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Takano: "Silicon Chemistry in the Outer Envelope of IRC+10216.The Derailed Distribution of SiC_2" Publications of the Astronomical Society of Japan. 44. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Yamamoto: "SiO in Barnard 1" Publications of the Astronomical Society of Japan. 44. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Mikami: "Detection of SiO Emission in the L1157 Dark Cloud" Astrophysical Journal. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Yamamot: "The Microwave Spectrum of the CH_2N Radical in the X^2B_1 Ground Electronic State" Journal of Chemical Physics. 96. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Kawaguchi: "Observations of Cumulene Carbenes,H_2CCCC and H_2CCC,in TMC1" Publications of the Astronomical Society of Japan. 43. 607-619 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Takano: "Millimeter-Wave Spectra of the Aluminum Monosulfide Radical(X^2Σ^+)" Joural of Chemical Physics. 94. 3355-3360 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Takano: "MillimeterーWave Spectrum of the Aluminum Monosulfide Radical (X^2Σ^+)" Journal of Chemical Physics. 94. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Kanada: "The Microwave Spectrum of the ND_2Radical" Journal of Chemical Physics. 94. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Mikami: "The Microwave Spectrum of the Dihydronitrosyl Radical,H_2NO( ^2B_1)" Journal of Chemical Physics. 94. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] S.Yamamoto: "Rotational Spectrum of the CCS Radical Studied by Laboratory Microwave Spectroscopy and RadioーAstronomical Observations" Astrophysical Journal. 361. 318-324 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] B.E.Turner: "Interstellar Cyanomethane" Astrophysical Journal. 355. 546-561 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] F.X.Brown: "Microwave Spectroscopy of Isotopically Substituted HCCN and its Molecular Structure" Journal of Molecular Spectroscopy. 143. 203-208 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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