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Dynamics of Highly Condensed Molecular Solids by Laser-Induced Acoustic Phonon Spectroscopy

Research Project

Project/Area Number 02452036
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 固体物性
Research InstitutionGifu University

Principal Investigator

SHIMIZU Hiroyasu  Gifu University, Dept. of Electronics, Professor, 工学部, 教授 (80023258)

Co-Investigator(Kenkyū-buntansha) SASAKI Shigeo  Gifu University, Dept. of Electronics, Assistant, 工学部, 助手 (30196159)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 1992: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1991: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1990: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsAcoustic Phonon Spectroscopy / Ultrahigh-Pressure Brillouin Scattering / Hydrogen Sulfide / Crystal Growth / Elastic Constant / 6フッ化イオウ / 分子ダイナミクス / エタノ-ル / 硫化カルボニル / ダイヤモンドアンビルセル
Research Abstract

High-pressure acoustic Brillouin spectroscopy has been applied to molecular solids hydrogen sulfide (H2S) and carbon dioxide (CO2) at pressures up to 6 GPa and room temperature. The best fit of the angular dependence of Brillouin acoustic velocities between experimental values and calculations based on Every's expression for elastic waves of an arbitrary direction yielded the orientation of H2S and CO2 cubic-phase crystal grown in the diamond-anvil high-pressure cell. In situ determinations of sound velocities, as a function of pressure, could be made for any direction, the refractive index, the density, and the elastic constants.
This method provides a mean for the systematic study of elastic properties and phase transitions of condensed gases under ultrahigh pressures.

Report

(4 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] S.Sasaki: "Elastic Constants of a Cubic Crystal Girown in a High-Pressure Diamons Anvil Cell" Jpn.J.Appl.Phys.S31-1. 17-19 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu: "High-pressure Raman and Brillian Studies Elastic Properties of H2S Grown in a Diamond Cell" Mal.Cryst.& Uig.Cryst. 218. 97-102 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu: "High-Pressure Raman and Brillouin Scatterings in Hydrogen-Bonded Crystalline H_2S Grown in a Diamond Cell" Science. 257. 514-516 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 清水 宏晏: "水素結合系分子結晶の超高圧光散乱" 高圧力の科学と技術. 1. 166-176 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu: "New Development of High-Pressure Brillouin Study for Elastic Properties of Molecular Solid" Jpn.J.Appl.Phys.S32-1. 355-357 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu: "Acoustic Velocities,Refractive Index,and Elastic Constant of Liguid and Solid CO_2 up to 6 Gipa" Phys.Rev.B(Rapid Commun.). 47. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu, K.Takasaki and S.Sasaki: "Raman and Brillouin Scattering Studies of Hydrogen Sulfide at High Pressures up to 23 GPa" High-Pressure Research: Application to Earth and Planetary Sciences, edited by Y.Syono & M.H.Manghnani, Terra Scientific Publishing Co., Tokyo. 109-116 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Sasaki, S.Katoh and H.Shimizu: "Elastic Constants of a Cubic Crystal Grown in a High-Pressure Diamond Anvil Cell" Jpn.J.Appl.Phys.31(Suppl.31-1). 17-19 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu and S.Sasaki: "High-Pressure Raman and Brillouin Scatterings in Hydrogen-Bonded Crystalline H2S" Mol.Cryst. & Liq.Cryst.218. 97-102 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Sasaki and H.Shimizu: "High-Pressure Raman and Brillouin Studies of Sulfur Hexafluoride up to 10GPa" Recent Trends in High Pressure Research (Proc. XIII AIRAPT Inter. Conf. High Pressure Science and Technology), edited by A.K.Singh, Oxford & IBH Publishing Co.220-222 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu and S.Sasaki: "High-Pressure Brillouin Studies and Elastic Properties of Single-Crystal H2S Grown in a Diamond Cell" Science. 257. 514-516 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu and S.Sasaki: "New Development of High-Pressure Brillouin Study for Elastic Properties of Molecular Solid" Jpn.J.Appl.Phys.32(Suppl.32-1). 355-357 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] H.Shimizu, T.Kitagawa and S.Sasaki: "Acoustic Velocities, Refractive Index, and Elastic Constants of Liquid and Solid CO2 at High Pressures up to 6 GPa" Phys.Rev.B(Rapid Commun.).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Sasaki: "Elastic Constants of a Cubic Crystal Grown in a High-Pressure Diamond Anvil Cell" Jpn.J.Appl.Phys.S31-1. 17-19 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Shimizu: "High-Pressure Raman and Brillouin Scatterings in Hydrogen-Bonded Crystalline H_2S" Mol.Cryst.&Liq.Cryst.218. 97-102 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Shimizu: "High-Pressure Brillouin Studies and Elastic Properties of H_2S Grown in a Diamond Cell" Science. 257. 514-516 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 清水 宏晏: "水素結合系分子結晶の超高圧光散乱" 高圧力の科学と技術. 1. 166-176 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Shimizu: "New Development of High-Pressure Brillouin Study for Elastic Properties of Molecular Solid" Jpn.J.Appl.Phys.S32-1. 355-357 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Shimizu: "Acoustic Velocities,Refractive Index,and Elastic Constant of Liquid and Solid CO_2 up to 6 GPa" Phys.Rev.B. 47. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Shimizu: "Pressureーinduced Phase transition in solid hydrogen sulfide at 11 GPa" J.Chem.Phys.95. 2036-2040 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Sasaki: "HighーPressure Raman Study of Carbon Tetrafluoride up to 8GPa" J.Phys.Soc.Jpn.60. 1560-1564 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 清水 宏晏: "第13回AIRAPT高圧力国際会議に参加して" 日本高圧力学会・ニュ-ズレタ-. 2. 7-8 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Sasaki: "HighーPressure Raman Study of Sulfur Hexafluoride up to 10 GPa" J.Phys.Soc.Jpn.61. 514-518 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Shimizu: "HIGHーPRESSURE RAMAN AND BRILLOUIN SCATTERINGS IN HYDROGENーBONDED CRYSTALLINE H_2S" Mol.Cryst.& Liq.Cryst.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Sasaki: "HighーPressure Raman and Brillouin Studies of Sulfur Hexafluoride up to 10 GPa" HIGH PRESSURE RESEARCH. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Shimizu: "Highーpressure Raman Study of Liquid and Solid Ethanol at Pressures up to 17 GPa" J.Raman Spectroscopy. 21. 703-704 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Shimizu: "Highーpressure Raman Study of Liquid and Crystalline Carbonyl Sulfide" Chem.Phys.Letters. 175. 349-353 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] H.Shimizu: "Raman and Brillouin Scattering Studies of Hydrogen Sulfide at High Pressures up to 23 GPa" Highーpressure Research in Mineral Physics:Application to Earth and Planetary Sciences. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 清水 宏晏: "第2回アルキメデス・ワ-クショプ「高圧下の分子固体」" 日本物理学会誌. 45. 932-933 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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