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Study and improvement of the luminescent and degradation mechanism of organic electroluminescent devices

Research Project

Project/Area Number 02452146
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 電子材料工学
Research InstitutionNagoya University

Principal Investigator

MIZUTANI Teruyoshi  Nagoya Univ.Sch.of Eng.Professor, 工学部, 教授 (70023249)

Co-Investigator(Kenkyū-buntansha) MORI Tatsuo  Nagoya Univ.Sch.of Eng.Assistant Professor, 工学部, 助手 (40230073)
SUZUOKI Yasuo  Nagoya Univ.Sch.of Eng.Associated Professor, 工学部, 助教授 (10115587)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 1992: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1991: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1990: ¥3,000,000 (Direct Cost: ¥3,000,000)
Keywordsorganic thin film / deposition rate / electroluminescent device / plasma-modification / vacuum-evaporation / work function / dye doping / tris(8-hydroxyquinoline)aluminium / プラズマ表面処理 / 仕事関数 / ESCA / 静電容量ー電圧特性 / ホ-ル注入 / 作成条件 / 真空蒸着法 / 発光しきい電圧 / アルミキノリノ-ル錯体 / ジアミン誘導体 / 電界発光
Research Abstract

Organic EL devices with a structure of ITO/TPD/Alq3/Mg were prepared by the vacuumevaporation method and their EL properties were investigated in order to improve them. The EL device emits strong green light with the polarity of the ITO electrode move through TPD,penetrate into Alq3 and recombine there with electrons which are injected from Mg electrode and arrive at the TPD/Alq3 interface region. Light is emitted through the electron-hole materials. Blue,green and red lights are obtained. In this report, we have investigated the effects of the conditions of film preparation on properties of the organic EL device. Main results obtained are as follows; (1) High deposition rate of Alq3 resulted in high EL. (2) The deposition rate of TPD did not affect the EL intensity. (3) Electron beam evaporation provided a better ITO anode than RF sputtering. (4) Mg which has a low work function resulted in high EL. (5) Plasmamodification on the ITO substrate lowers the driven voltage of EL devices. (6) Doping of DCM and Coumarine gives EL device a high efficiency. (7) Doping of squarylium dye has a new type EL device. It is important for the improvement of the organic EL devices to optimize the conditions of film preparation as well as to select materials.

Report

(4 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] Tatuo Mori: "electrical conduction of evaporated thin films for 1,1-bis-(4,4^1-diethylaminophenyl)-4,4-diphenyl-1,3-butadiene" Journal of Physics D:Applied Physics. 25. 1817-1820 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Tatuo Mori: "Estimate of hole mobilities of some organic photoconducting materials using the time-of-flight method" Journal of Physics D:Applied Physics. 26. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Tatsuo Mori,Eiichi Sugimura,Tomoaki Kichimi,Teruyoshi Mizutani: "Electrical conduction of evaporated thin films for 1,1-bis-(4,4'-diethylaminophenyl)-4,4-diphenyl-1,3-butadiene" Journal of Physics D: Applied Physics. 25. 1817-1820 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Tatsuo Mori,Eiichi Sugimura,Teruyoshi Mizutani: "Estimate of hole mobilities of some organic photoconducting materials using the time-of-flight method" Journal of Physics D:Applied Physics. 26. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Tatsuo Mori: "Electrical conduction of evaporated thin films for 1,1-bis-(4,4^1-diethylaminophenyl)-4,4-diphenyl-1,3-butadiene" Journal of Physics D:Applied Physics. 25. 1817-1820 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Tatsuo Mori: "Estimate of hole mobilities of some organic photoconducting materials using the time‐of‐flight method" Journal of Physics D:Applied Physics. 26. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Tatsuo Mori: "Effects of the preparation condition on the electrical and optical properties of an organic electroluminescent diode" Journal of Physics D:Applied Physics. 26. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Tatsuo Mori: "Estimate of hole mobilities of some organic photoconducting materials using timeーofーflight method" J.Physics D:Applied Physics.

    • Related Report
      1991 Annual Research Report
  • [Publications] Tatsuo Mori: "Electrical conduction of evaporated thin films for 1,1ーbisー(4,4'ーdiethylaminophenyl)ー4,4ーdiphenylー1,3ーbutadience" J.Physics D:Applied Physics.

    • Related Report
      1991 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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