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Sulphide Capacity of CaO-Al_2O_3-MgO Slag

Research Project

Project/Area Number 02453054
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionTohoku University

Principal Investigator

BAN-YA Shiro  Professor in Dept. of Metall., Fac. of Engr., Tohoku Univ., 工学部, 教授 (90005223)

Co-Investigator(Kenkyū-buntansha) HINO Mitsutaka  Associate Professor in Dept. of metall., Fac. of Engr., tohoku Univ., 工学部, 助教授 (10091729)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1991: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1990: ¥5,400,000 (Direct Cost: ¥5,400,000)
KeywordsSecondary refining / CaO-Al_2O_3 slag / Desulphurization / Sulphide Capacity / Steelmaking / Physical chemistry / CaO-Al_2O_3-MgO slag / Sulphur distribution ratio
Research Abstract

Many kinds of secondary steelmaking process have been developed recently to product highly purified steel, where CaO-Al_2O_3 system has been utilized as industrial flux. Therefore, the sulphide capacities of CaO-Al_2O_3, CaO-Al_2O_3-MgO, where MgO is dissolved from refractories, and CaO-Al_2O_3-SiO_2 slags, where SiO_2 is brought via steelmaking. process, were studied to estimate the sulphur distribution ratio between secondary steelmaking slag and liquid slag.
The slag samples were equilibrated with Ar-CO-CO_2-SO_2 gas mixtures at 1823 to 1923 K. After reaching equilibrium, the samples were quenched and crushed to determine the contents of constituents and sulphur by chemical analysis.
The present result of sulphide capacity in CaO-Al_20_3 slag agreed well with the previous works. From the obtained results, it was confirmed that substitution of CaO to MgO or SiO_2 at a given N_<Al_2O_2> decreased the sulphide capacities. The evaluated values of sulphur distribution ratio for both slags was higher than 1000 at 1873 K on the condition of CaO-saturation if the dissolved aluminium content in steel was assumed to be 0.01%.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 萬谷 志郎: "CaOーAl_2O_3ーMgO及びCaOーAl_2O_3ーSiO_2系スラグのサルファイド・キャパシティ" 日本学術振興会19委ー11305、反応ー759. 1-1-1-13 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 萬谷 志郎: "CaOーAl_2O_3ーMgO及びCaOーAl_2O_3ーSiO_2系スラグのサルファイド・キャパシティ" 材料とプロセス. 5. 8-8 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Mitsutaka HINO: "Sulphide Capacities of CaO-Al_2O_3-Mgo and CaO-Al_2O_3-SiO_2 Slags" Proc.of Molten Slags & Fluxes '92. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Mitsutaka HINO: "Sulphide Capacities of CaO-Al_2O_3-Mgo and CaO-Al_2O_3-SiO_2 Slags" ISIJ International. 33. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Ban-ya, M. Hino and S. Kitagawa: "Sulphide Capacities of CaO-Al_2O_3-MgO and CaO-Al_2O_3-SiO_<> Slags" Jpn. Soc. Prom. Sci., 19th-Sub., Tech. Paper. No. 11305. 1-1-1-13 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Ban-Ya, M. Hino and S. Kitagawa: "Sulphide Capacities of CaO-Al_2O_3-MgO and CaO-Al_2O_3-SiO_<> Slags" CAMP-ISIJ. 5. 8 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Hino, S. Kitagawa and S. Ban-ya: "Sulphide Capacities of CaO-Al_2O_3-MgO and CaO-Al_2O_3-SiO_2 Slags" Proc. of Molten Slags & Fluxes '92. (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Hino, S. Kitagawa and S. Ban-ya: "Sulphide Capacities of CaO-Al_2O_3-MgO and CaO-Al_2O_3-SiO_2 Slags" ISIJ International. 33. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 萬谷 志郎: "CaOーAl_2O_3ーMgO及びCaOーAl_2O_3ーSiO_2系スラグのサルファイド・キャパシティ" 日本学術振興会19委ー11305、反応ー759. 1-1/1-13 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 萬谷 志郎: "CaOーAl_2O_3ーMgO及びCaOーAl_2O_3ーSiO_2系スラグのサルファイド・キャパシティ" 材料とプロセス. 5. 8-8 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Mitsutaka HINO: "Sulphide Capacities of CaOーAl_2O_3ーMgO and CaOーAl_2O_3ーSiO_2 Slags" Proc.of Molten Slags & Fluxes '92. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Mitsutaka HINO: "Sulphide Capacities of CaOーAl_2O_3ーMgO and CaOーAl_2O_3ーSiO_2 Slags" ISIJ International. 33. (1993)

    • Related Report
      1991 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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