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Development of a practical instrument for preparing complex LB films of high quality fully automatically.

Research Project

Project/Area Number 02555167
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionUtsunomiya Scientific Research (B) (1)

Principal Investigator

KATO Teiji  Utsunomiya University Fac. of Eng. Assoc. Professor, 工学部 助教授 (60008068)

Co-Investigator(Kenkyū-buntansha) YONEDA Katsumi  Nippon Laser Elect. Co. Ltd. President, 代表取締役
若菜 辰之  システムマネージメーションK. K., プログラマー
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1991: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1990: ¥5,300,000 (Direct Cost: ¥5,300,000)
KeywordsComplex LB Films / Fully Automatic Instrument for LB Deposition / Micro-Computer Control / Peltier Element / Insoluble Monolayers / Isobaric thermal Treatment of Monolayers / High Quality LB Films / 不溶性単分子膜 / 新型Langmuir水槽 / LB膜
Research Abstract

Langmuir-Blodgett (LB) films are made by successive deposition of monolayers on the water surface onto suitable solid substrates. They are believed to be molecularly orderd ultra-thin films. Recently, however, it becomes clear that there are so many defects of molecular order in LB films. This in the reason that we can not realize practical of commercial use of LB films in spite of the potential possibilities of LB films in many fields. What we intended to develop by this grant-in-aid for scientific research is a practical instrument for preparing complex LB films of high quality fully automatically. This instrument can be controlled by two microcomputers. One microcomputer controls surface pressures of two kinds of monolayers precisely to deposit complex LB films. Another microcomputer controls the tmperature of the water surface in the Langmuir trough freely by using integrated Peltier elements and also controls the complicated movement of solid substrates during deposition of the co … More mplex LB films. This instrument could be developed successfuly and many results leading high quality monolayers and LB films have been obtained by this instrument. Refer papers on the back side of this paper, reported by us in these two years, especially two papers on the A-T isobers of monolayers which lead densification of monolayers and LB films to reduce defects in LB films. The control-program of the instrument is divided into some blocks to get good perspective of the huge control-program. Whoever wishes to use this instrument can use this by menu-system of the control program. In the second year of the project term, we have developed the Brewstar Angle Ineterference Microscopy (BAIM) which can observe insoluble monolayers on the water surface directly. This instrument have been reported first by French at the beginning of last summer. We changed the content of the project to develped this instrument because it has been very difficult to observe insoluble monolayers on the water surface directly by other experimental instruments. This microscopy will be a powerful tool for estimating quality of monolayers and LB films by combination with the newly develped freely temperature controllable Langmuir trough. Less

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] T.Kato: "The Time of Observation of Measurements of π-A Isotherms II.A Possibility That So-Called Solid Films may Correspond to the First-Order Phase Transition reasions." langmuir. Vol.7. 2208-2212 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 加藤 貞二: "自在に温度制御できるLangmuir水槽の開発と、ミリスチン酸単分子膜のAーT等圧線測定" 日本化学会誌. 1991. 1027-1029 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T.Kato: "Direct Evidence of the Enthalpy Release Being Accompanied by the First-Order Phase transitions of Monolayers by Compression." Chemical Physics Letters. Vol.184. 455-460 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T.Kato: "The Time of Observation of π-A Isotherms III.Studies on the Morphology of Arachidic Acid Monolayers,Observed by TEM of Replica Samples of One-Layer LB Films." Thin Solid Films. Vol.207. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K.iriyama: "Electron Microscopic Visualization of J-Aggregate in Monolayer of Spyropyran." Membrane. Vol.16. 387-392 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 加藤 貞二: "キャナル法による不溶性単分子膜の表面粘性の精密測定" 日本化学誌. 1991. 1594-1597 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato: "Estimation of the Dynamic Properties of Monolayers at the Air/Water Interface." Surface Science. 11 (4). 221-228 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato: "What is the Charactristic Time of measurement of pi-A Isotherms? Necessity of the Constant Strain Rate-Compression of Monolayers for pi-A Measurements" Langmuir. 6 (4). 870-872 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato and T. Naruse.: "Visualization of Boundary Line of Overturned Molecules in LB Films during Deposition." Nippon Kagakukaishi. 1990 (10). 1117-1120 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato and K. Ohshima: "Defect-Free LB Films by the Isobaric Thermal Treatment of BArium Arachidate Monolayers." Jpn. J. Appl. Phys.29 (11). L2102-2104 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato, K. Seki and R. Kaneko: "Insoluble Monolayers of Irisresorcinol at the Air/Water Interface." Colloid & Polymer Sci.268 (10). 934-937 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K. Iriyama, T. Araki and T. Kato.: "Electron Microscopic Visualization of Numerous Two-Dimensional Crystal-Like Domains in a Monolayer on an Aqueous Solution." Membrane. 16 (1). 43-47 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato and H. Akiyama: "Development of a Freely Temperature Contollable Langmuir Trough and A-T Isobars of Myristic Acid Monolayers." Nippon Kagakukaishi. 1991 (7). 1027-1029 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato, Y. Hirobe and M. Kato.: "The Time of Observation of Measurements of pi-A Isotherms II. A Possibility that So-Called Solid Films of Monolayers of Lond-Chain Acids may not Correspond to the Two-Dimensional Solids." Langmuir. 7 (10). 2208-22122 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato H. Akiyama, and T. Tanaka.: "Direct Evidence of the Enthalpy Release Being Accompanied by the First-Order Phase transitions of Monolayers at the Air/Water Interface." Chem. Phys Lett.184 (5). 455-460 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato: "Studies on the Dynamic Properties of the Insoluble Monolayers. Recent Progress." News Letter of the Division of Colloid and Interface Chemistry, CSJ.16 (9). 15-20 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato, K. Iriyama and T. Araki.: "The Time of Observation of pi-A Isotherms III. Studies on the Morphology of Arachidic Acid Monolayers, Observed by TEM of Replica Samples of One-Layer LB Films." Thin Solid Films.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] K. Iriyama, T. Araki and T. kato.: "Electron Microscopic Visualization of J-Aggregate in Monolayers of Spyropiran." Membrane. 16 (6). 387-392 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato and M. Arai.: "Precise Measurement of Surface Viscosity of Monolayers by Cannal Method and the Kinetic Energy Correction." Nippon Kagakukaishi. 1991 (12). 1594-1597 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Kato and H. Akiyama.: "A-T Isobars of Monolayers of Long-Chain Acids and the First-Order Phase transitions." Nippon Kagakukaishi. 1992 (3). 261-266 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 加藤 貞二: "LB膜作成装置とLB膜の構造" 油化学. Vol.39. 141-147 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "The Time of Observation of Measurements of π-A Isotherms II. A Possibility That So-Called Solid Films may Correspond to the First-Order Phase Transition reasions." Langmuir. Vol.7. 2208-2212 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 加藤 貞二: "自在に温度制御できるLangmuir水槽の開発と、ミリスチン酸単分子膜のA-T等圧線測定" 日本化学会誌. 1991. 1027-1029 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "Direct Evidence of the Enthalpy Release Being Accompanied by the First-Order Phase transitions of Monolayers by Compression." Chemical Physics Letters. Vol.184. 455-460 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "The Time of Observation of π-A Isotherms II. Studies on the Morphology of Arachidic Acid Monolayers, Observed by TEM of Replica Samples of One-Layer LB Films." Thin Solid Films. Vol.207. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 加藤 貞二: "長鎖脂肪酸単分子膜のA-T等圧線測定と一次相転移" 日本化学会誌. 1992. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 福田 清成: "超薄分子膜の科学" 講談社サイエンティフィク, 260 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "What is the Characteristic Time of Measurement of πーA Isotherms?" Langmuir. 6. 870-872 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 加藤 貞二、成瀬 俊道: "LB膜累積中の分子反転境界の可視化と累積中の分子脱離の可視化" 日本化学会誌. 1990. 1117-1120 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Kato and K.Ohshima: "DefectーFree LB Fims by the Isobaric Thermal Treatment of Monolayers." Jpn.J.Appl.Phys.29. L2102-L2104 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Kato,K.Seki and R.Kaneko: "Insoluble Monolayers of Irisresorcinol at the Air/Water Interface." Colloid &Polymer Sci.,. 268. 934-937 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] K.Iriyama,T.Araki and T.Kato: "Electron Microscopic Visualization of Numerous TwoーDimensional CrystalーLike Domains in a Monolayer on an Aqueous Solution." Membrane. 16. 43-47 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Kato,Y.Hirobe and M.Kato: "The"Time of Observation"of Measurements of πーA Isotherms.II" Langmuir. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 加藤 貞二,秋山 秀行: "自在に温度制御できるLangmuir水槽の開発とミリスチン酸単分子膜のAーT等圧線測定" 日本化学会誌. (1991)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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