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Preparation and Pre-Clincal Evaluation of Novel Polymeric Dental Adhesives with Excellent Safty

Research Project

Project/Area Number 02557075
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 補綴理工系歯学
Research InstitutionTokyo Medical and Dental university

Principal Investigator

NAKABAYASHI Nobuo  Institute for Medical and Dental Engineering Division of Organic Materials professor, 医用器材研究所・有機材料, 教授 (30014020)

Co-Investigator(Kenkyū-buntansha) FUJIMURA. Hiroshi  Mitsui Petrorium Chemical Industry Co. Ltd. Iwakuni Polymer research Center Pres, 岩国高分子研, 所長
WATANABE Akihiko  Institute for Medical and Dental Engineering Division of Organic Materials Assis, 医用器材研究所・有機材料, 助手 (30126263)
ISHIHARA Kazuhiko  Institute for Medical and Dental Engineering Division of Organic Materials Assoc, 医用器材研究所・有機材料, 助教授 (90193341)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥5,800,000 (Direct Cost: ¥5,800,000)
Fiscal Year 1991: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1990: ¥3,700,000 (Direct Cost: ¥3,700,000)
KeywordsDental Adhesive / Polymer / Reactivity / Graft Copolymer / Hydroxyapatite / Chelate Bond / 歯科接着材 / 高分子電解質 / 反応性高分子 / pースチレンスルホン酸 / 象牙質 / エナメル質 / 歯科用レジン
Research Abstract

In order. to improved adhesion of dental resins onto teeth. polymeric adhesives were prepared and its application to the dental fields was evaluated. A water-soluble graft copolymers composed of p-styrene sulfonic acid and poly (methyl methacrylate) macromonomer (gMS) were synthesized. The teeth surface treated with gMS indicated similar polarity of poly (methyl methacrylate) even it was washed with water sufficiently. This finding means that the gMS reacted and covered on teeth surface. This is also confirmed by X-ray photoelectron spettroscopic analysis of the treated surface. The tensile bond strength of the dental resin to tooth enamel treated with the gMS aqueous solution was about 8MPa which is higher than the surface with the corresponding random copolymers of p-styrene bulfonate and mehtyl methac-rylate.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 中林 宣男: "グラフト共重合体による新しい歯科接着剤" 高分子. 40. 688 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 山本 隆司: "スルホン酸基を有する高分子を利用した歯質と歯科用レジンの接着" 高分子論文集. 47. 655-658 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 山本 隆司: "歯質反応性を有するグラフトコポリマ-の合成と歯質への接着性" 高分子論文集. 49. 119-123 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Nobuo Nakabayashi: "Novel Dental Adhesives Using Graft copolymer" Kobunshi.40. 688 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takashi Yamamoto. Kazuhiko Ishihara, Nobuo Nakabayashi: "Adhesion of Dental Resin to Tooth Substrates Using Polymers with Sulfonic Acid" Kobunshi Ronbunshu. 47(8). 655-658 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takashi Yamamoto, Junko Kajima, Kimio Kurita, Kazuhiko Ishihara, Nobuo Nakabayashi.: "Synthesis and Adhesin of Graft Copolymer with Reactive Group to Tooth Substrates" Kobunshi Ronbunshu. 49(2). 119-123 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 中林 宣男: "グラフト共重合体による新しい歯科接着剤" 高分子. 40. 688- (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 山本 隆司: "スルホン酸基を有する高分子を利用した歯質と歯科用レジンの接着" 高分子論文集. 47. 655-658 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] 山本 隆司: "歯質反応性を有するグラフトコポリマ-の合成と歯質への接着性" 高分子論文集. 49. 119-123 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 山本 隆司,石原 一彦,中林 宣男: "スルホン酸基を有する高分子を利用した歯質と歯科用レジンの接着" 高分子論文集. 47. 655-658 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 山本 隆司,賀嶋 淳子,石原 一彦,中林 宣男: "歯質反応性を有するグラフトポリマ-の合成と歯質への接着性" 高分子論文集.

    • Related Report
      1990 Annual Research Report
  • [Publications] 木下 亨: "コンポジットレジンを研削歯質に接着させる新しい歯質反応ポリマ-" 歯材器. 9. 86-101 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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