TIME-RESOLVED SPECTROSCOPY ON ULTRAFAST NONRADIATIVE RELAXATION OF TRANSITION METAL IONS IN SOLIDS
| Project/Area Number |
02640247
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
固体物性
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| Research Institution | TOHOKU UNIVERSITY |
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Principal Investigator |
SUZUKI Yoshiro TOHOKU UNIVERSITY, FACULTY OF ENGINEERING, RESEARCH ASSOCIATE, 工学部, 助手 (80133932)
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| Project Period (FY) |
1990 – 1991
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| Project Status |
Completed (Fiscal Year 1991)
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| Budget Amount *help |
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1991: ¥200,000 (Direct Cost: ¥200,000)
Fiscal Year 1990: ¥1,500,000 (Direct Cost: ¥1,500,000)
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| Keywords | Time-resolved Spectroscopy / Pump & Prove Method / Streak Camera / Nonradiative Transition / Ce^<3+>lons / YAG Crystals / フェムト秒分光 / 遷移金属イオン / エネルギ-緩和 / 励起刻態吸収 / ストリ-クカメラ / 励起状態吸収 / 時間分解吸収スペクトル |
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| Research Abstract |
Trivalent cerium impurities (Ce^<3+>) in YAG crystals were selected as a model system to investigate the de-excitation mechanism of d electrons in solids. The 4f electrons at the ground state were pumped to the second-lowest 5d state (5d_b) by UV laser pulses. Then, observed were the growths of the yellow-green (YG) emission from the lowest 5d state (5d_a) by a streak camera, as well as the growths of the excited state absorption (ESA) from the 5d_a to higher excited states by a pump & prove method.
Each measurement gave consistent results. The growth times (tau) at temperatures below 80K were as long as 50ps. The tau decreased above 80K to be less than 5ps at 300K. The constant tau below 80K was interpreted from a tunneling process from 5d_b to 5d_a, while the decreasing tau above 80K was from a thermally-activated process. It follows that the nonradiative transition (NRT) between 5d states occurs not dynamically, but statically after completing a thermal equilibrium in the initial 5d state.
The above results predict the existence of UV emission from the metastable 5d_b state to the 4f ground state. The UV emission was successfully detected at 350 to 400nm. Agreement of the decay time of the UV emission with the tau of the ESA and YG emission supports the static mechanism of the NRT for 5d electrons.
To apply the time-resolved spectroscopy to a variety of d electron systems, extension of the pumping wavelengths and improvement of the pumping methods were required. As the former examination, F^+_ centers were shown to be available for an IR pulse source, while, as the latter, a method of time-delayed double excitation was demonstrated by making use of two pulse lasers.
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Report
(3 results)
Research Products
(15 results)
