About the abnormal Valence of the Transition Metal in The CT complex
| Project/Area Number |
02640338
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
物理化学一般
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| Research Institution | Nagoya University |
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Principal Investigator |
TANAKA Masashi Nagoya University, College of Genral Education, Professor, 教養部, 教授 (70022639)
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| Project Period (FY) |
1990 – 1991
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| Project Status |
Completed (Fiscal Year 1991)
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| Budget Amount *help |
¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1991: ¥100,000 (Direct Cost: ¥100,000)
Fiscal Year 1990: ¥1,400,000 (Direct Cost: ¥1,400,000)
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| Keywords | BEDT-TTF / conductivity / phase transition / ESR / 混合原子価 / 反射スペクトル / 電気伝導局 / BEDT・TTF |
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| Research Abstract |
Bis (ethylenedithio) tetrathiafulvalene (BEDT-TTF) forms many charge transfer complexes. The crystal of (BEDT-TTF)_4 [Ni(CN)_4] belongs to the triclinic pl with the lattice constants of a=10.994 (2), b=16.443 (2), c=9.703 (1), alpha=97.85 (1), beta=115.15 (1), gamma=95.94 (1)ﾟ. In the crystal, there exists the face to face overlap of the BEDT-TTF molecules along the [201] direction. The intermolecular interaction by the short S ・・・ S contact is also observed along the [201] direction.
The room temperature conductivity was about 20S/cm. The crystal was metellic between 230 and 300K and became semi-conductive with an energy gap of 100K below 160K, although the temperature dependence of the conductivity was not obtween 160 and 230K. This kind of resistance behavior may be explained by the phase transition of the crystal between 160 and 230K.
The ESR spectrum at 4K consists of the strong band at g=2.013 and the weak band at g=2.056.
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Report
(3 results)
Research Products
(9 results)
