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Crystallization and Strength of the Molten Slag on Sewage Sludge Melting Process

Research Project

Project/Area Number 02650379
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 都市工学・衛生工学
Research InstitutionNagaoka University of Technology

Principal Investigator

MOMONOI Kiyoshi  Faculty of Eng., Nagaoka Univ. of Tech. Professor, 工学部, 教授 (60003852)

Co-Investigator(Kenkyū-buntansha) TAKIZAWA Satoshi  Sewage Work Div., Public Works Research Institute Researcher, 土木研究所・下水道部, 研究員 (10206914)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1991: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1990: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywordssewage sludge / melting slag / nucleation / crystal growth / basicity / 水砕スラグ / 空冷スラグ / 結晶化スラグ / シリカ
Research Abstract

In the melting process, sewage sludge is melted in the high temperature range of 1300 to 1500 ゚C which is beyond the pouring point of sludge inorganics and a large volume reduction and stabilization of heavy metals in the slag are expected to greater than incineration process.
On the other hand, methods of converting glasses slag made from processed sewage sludge to crystalline slag has been investigated to reuse them as construction materials. Crystalyzation of slag is greatly affected by in-organic component parts in the sludge. The results are as follows.
1. Though a mixture of SiO_2, Al_2O_3, CaO and Fe_2O_3 contained in sewage sludge in-organics require a very high temperature to be melted, the melting temperature dropped about 200 ゚C with the adjustment of inorganic component ratio of Na_2O/CaO (between 0.2-0.4) by Na-added and Ca-added.
2. The maximum nucleation temperature of polymer-added sewage sludge is about 700゚C, and the maximum crystal growth temperature is about 1100゚C. The crystalline slag is made by holding the solid solution at 1100゚C during 1 hr and cooling the molten slag. Also, the crystalline slag is easily made by re-heating a glasses slag.
3. Strength of a slag is affected by SiO_2 contents in a slag. Strength of a slag increases with increasing of SiO_2 contents, but viscosity of liquids affected by SiO_2 contents causes a high melting temperature. It is suggested that the adjustment of basicity (CaO/SiO_2 ratio : about 1.0) makes the melting temperature lower.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] 桃井 清至: "下水汚泥の溶融特性と結晶化に関する研究" 環境技術. 20. 445-450 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 日本化学会編(共著): "リサイクルのための化学" 大日本図書, 196 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Kiyoshi Momonoi: "Melting Characteristic and Crystallization of sewage sludge" Journal of Environmental Conservation Engineering. 20. 445-450 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] The Chemical Society of Japan (joint author): Dainippontosho. Chemistry for Recycle, (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 桃井 清至: "下水汚泥の溶融特性と結晶化に関する研究" 環境技術. 20. 445-450 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 日本化学会編(共著): "リサイクルのための化学" 大日本図書, 196 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 桃井 清至: "下水汚泥の建設資材への利用" 化学と工業. 42. 112-116 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] 元重 浩: "下水汚泥溶融スラグの結晶化と汚泥成分の影響" 土木学会編 年次学術講演会講演概要集. 45. 1000-1001 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 桃井 清至: "下水汚泥溶融スラグの結晶化に関する研究" 日本下水道協会編 下水道研究発表会講演集. 27. 547-549 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 桃井 清至: "溶融スラグの組成性状と結晶化に関する研究" 全国都市清掃会議編 全国都市清掃研究発表会講演論文集. 12. 124-126 (1991)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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