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Novel production process of metal alkoxide by using solvent extraction technique

Research Project

Project/Area Number 02805083
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionKANSAI UNIVERSITY

Principal Investigator

NISHIMURA Sanji  Kansai University FACULTY of ENGINEERING Professor, 工学部, 教授 (30067467)

Co-Investigator(Kenkyū-buntansha) SANO Makoto  Kansai University FACULTY of ENGINEERING Assistant, 工学部, 助手 (00170811)
Project Period (FY) 1990 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1992: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1991: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1990: ¥1,000,000 (Direct Cost: ¥1,000,000)
KeywordsMetal alkoxide / Solvent extraction / Extractant / Iron ion / Extraction process / Synthesis process / Distillation process under low pressure / Separation process / 溶媒和抽出剤 / 抽出化学種 / 亜鉛イオン / 減圧濃縮
Research Abstract

The fundamental study on the novel production process of metal alkoxide by solvent extraction technique which can selectively extract the chlorocomplex of the objected metal from aqueous chloride solution with specificextractant, removal of the coextracted water and chloride ion by distillation under low pressure and synthesis reaction with alcohol and ammonia was conducted from 1990 to 1993. The predominant objected metal was ferric iron because of its superior extractability.
It was found from the research results that the following properties were indispensable for the optimal extractant.
1) low boiling point and simple separation by distillation.
2) high basicity and high extractability in the low HCl concentration.
3) extracted species containing low water content.
4) weak bonding strength with metal alkoxide.
5) low solubility in water.
Among the various investigated extractants, TOPO(Tri-octyl-phosphine oxide) and IPE(Iso-propyl-ehter) can be effectively used as solvated extractant and … More TOA(Tri-octyl-amine) as basic extractant.
The new information was obtained with respect to the production process of metal alkoxyde. Extraction process - Reduction of water content in the organic phase is obtainable in high HCl concentration and high metal content in the organic phase. However, the latter is more effective than the former. TOPO and TOA can extract the chlorocomplex containing no water content in the extraction stage. Distillation process under low pressure - The sufficient removal of the extracted water in IPE is possible with 3 stages as a result of azeotropic effect of ethanol and can be offered to the synthesis reaction of metal alkoxyde. Synthesis process - Synthesis reaction in lower temperature is favarable. Separation process - The separation of TOPO or TOA is possible by the formation of Iron-ethoxyde-ammonium compound and the synthetic alkoxyde can be separated from the extractant having low boiling point by distillation under low pressure.
The novel production process of metal alkoxyde different from the conventional process was found to be possible by solvent extraction technique which can selectively extract the chlorocomplex of the objected metal containing no water content from the aqueous metal chloride solution involving various metallic ions with specific extractant and synthesis reaction with alcohol and ammonia in low temperature. Less

Report

(4 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • 1990 Annual Research Report
  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] Sanji,NISHIMURA and Makoto,SANO: "Crystaelization stripping of Silver from Metal loaded Versatic Acid 10 by CO_2 gas" Proceedings of International Symposium on Processing of Rare Metals,Kokura. 153-156 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji,NISHIMURA and Makoto,SANO: "Studies on the stripping Ti(IV)loaded in D2EHPA" Proceedings of Symposium on solvent extraction,December,1991,Osaka. 351-354 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji,NISHIMURA: "Production of ferric hydroxide and oxide powders by using hydrolytic stripping" Proceedings of Symposium on solvent extraction,December,1991,Osaka. 75-80 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji,NISHIMURA and Makoto,SANO: "New production method of metallic oxide and metal powders-application of solvent extraction technique" Solvent Extraction 1990 Process Metallurgy 7A. part. 1163-1168 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji,NISHIMURA and Makoto,SANO: "Extraction of metal ions from mixed aqueous-organic media with liquid-liquid extraction and ion exchange resin" Solvent Extraction 1990 Process Metallurgy 7A. part. 1169-1174 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji,NISHIMURA and Yoichi,MARU: "On the stripping and crystallization of cobalt in the VA10-kerosene solution into water under high pressure CO_2" Metallurgical Revirw of MMIJ. 8. 99-114 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and M.Sano: "Crystallization stripping of Silver from the Metal loaded Versatic Acid 10 by CO_2gas" Proceedings of International Symposium on Processing of Rare Metals, Kokura. 153-156 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and M.Sano: "Studies on the stripping of Ti(IV) loaded in D2EHPA" Proceedings of symposium on solvent extraction, December, 1991, Osaka. 351-354 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and M.Sano: "Production of ferric hydroxide and oxide powders by using hydrolytic stripping" Proceedings of symposium on solvent extraction, December, 1991, Osaka. 75-80 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and M.Sano: "New production method of metallic powders-application of solvent extraction technique" Solvent Extraction 1990, Process Metallurgy 7A. Part B. 1163-1168 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and M.Sano: "Extraction of metal ions from mixed aqueous-organic media with liquid-liquid extraction and ion exchange resin" Solvent Extraction 1990, Process Metallurgy 7A. Part B. 1169-1174 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Nishimura and Y.Maru: "On the stripping and crystallization of cobalt in the VA10-kerosene solution into water under high pressure CO_2" Metallurgical Review of MMIJ. Vol.8. 99-114 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Sanji Nishimura and Makoto Sano: "Studies on the stnipping of Ti(IV) loaded in D2EHPA" Proceedings of symposium on solvent extraction,December,1991.Osada. 351-354 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Sanji Nishimura and Makoto Sano: "Production of ferric hydroxide and oxide powders by using hydrolytic stripping" Proceedings of symposium on solvent extraction.December,1991,Osaka. 75-80 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Sanji Nishimura and Makoto Sano: "New production method of metallic oxide and metal pawders-application of solvent extraction technique" Solvent Extraction 1990 Process Metallungy 7A. Part B. 1163-1168 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Sanji Nishimura and Makoto Sano: "Extraction of metalions from mixed aqueous-organic media with liquid-liquid extraction and ion exchavgeresin" Solvent Extraction 1990 Process Metallurgy 7A. Part B. 1169-1174 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Yoichi Masu and Sanji Nishimura: "On the stripping and crystallization of cobalt in the VA10-Kerosene solution into water under high pressure CO_2" Metallurgical Review of MMIJ. 8. 99-114 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Sanji Nishimura and Makoto Sano: "Production of fine powders by solvent extraction-Hydrolytic stripping of Fe(III)" Technology Reports of Kansai University. 34. 79-89 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Makoto,Sano,Sanji,Nishimura: "Solvent Extraction of Molybdenum and Tungsten" Proceedings of International Symposium on Processing of Rere Metals,Kokura. 121-124 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] Sanji,Nishimura,Makoto,Sano: "Crystallization stripping Silver from the Metal loaded Versatic Acid 10 by Co_2 gas" Proceedings of International Symposium on Processing of Rere Metals,Kokura. 153-156 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西村 山治: "溶媒抽出技術ー産業廃棄物への適用" 金属. 1月号. 30-36 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西村 山治,丸 洋一: "Naを含む水溶液とVersatic Acid10との間のNaの分配と相平衡" 日本金属学会誌. 第55巻. 654-659 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西村 山治,丸 洋一: "炭酸ガス加圧下におけるVA10ーケロシン溶液中コバルトの水相への剥離晶析について" 資源と素材. 第107巻. 647-654 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西村 山治: "溶媒抽出法を応用した金属酸化物粉および金属粉の製造" ケミカルエンジニアリング. 第36巻. 31-36 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西村 山治: "溶媒抽出法を応用した金属酸化物粉および金属粉の製造" 化学工学会第23回秋季大会研究発表講演要旨集. 第5分冊SE107. 10-12 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 西村 山治: "溶媒抽出法による産業廃棄物から有価物の回収" 資源・素材'90ー資源リサイクリングー. U. 13-16 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Makoto Sano,Junji Shibata and Sanji Nishimura: "New production method of metallic oxide and metal powdersーApplication of solvent extraction teohnique" Proceedings of the International Solvent Extraction Lonference '90. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Junji Shibata,Makoto Sano and Sanji Nishimura: "Extraction of metal ions from mixed a quoousーorganic rnedia with liquidーliquid extraction and in exchange resin" Proceedinp of the International Solvent Extraction Conference '90. (1991)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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