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Analysis of Electron/Ion-Transfer Reactions within Thin Films Using an in situ Electrochemical Microbalance Technique

Research Project

Project/Area Number 02805096
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionTokyo Institute of Technology

Principal Investigator

OHSAKA Takeo  Tokyo Institute of Technology, Graduate School at Nagatsuta, Associate Professor, 大学院総合理工学研究科, 助教授 (80152099)

Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1991: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1990: ¥1,000,000 (Direct Cost: ¥1,000,000)
KeywordsElectron Transfer Reaction / Quartz Crystal Oscillator / Microbalance Technique / Electrochemistry / Polymer Film / Electropolymerized Film / Polymer Complex / Ion Transfer Reaction
Research Abstract

In the present work, an in situ electrochemical quartz crystal microbalance technique (in situ EQCM technique) was developed for elucidating charge transport in electroactive thin films. This technique is based on the quartz crystal microbalance used in conjunction with electrochemistry, and can be expected as a highly useful tool capable of quantitatively measuring small mass changes (10^<-9>- 10^<-6>g cm^<-2>) of electrode surfaces which occur as a result of electrochemical process. The in situ EQCM technique was successfully applied for quantitatively clarifying the charge-transport processes of some thin films which are electroactive and well-swollen with solvent/electrolyte :
(i) Polymer complex films (poly(vinylferrocene) , osmium polymer : [Os (bpy)_2 (PVP)Cl) Cl (bpy : 2, 2'-bipyridine, PVP : poly (4-vinylpyridine) )
(ii) Hydrogen-absorbing metal films (H_2/Pd film, D_2/Pb film)
(iii) Electropolymerized films (polyaniline, polypyrrole. poly (pyrrolo-pyrrole) S)
A fruitful information about these charge-transport processes was obtained, especially demonstrating that noble technique make it possible to directly elucidate the role of electroinactive species (e. g., solvent and counter ions) in charge-transport processes.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (70 results)

All Other

All Publications (70 results)

  • [Publications] Takeo OHSAKA: "Electrode Kinetics of Thin Polymer Complex Films Composed of Poly(alkyleneviologen)and poly(p-styrenesulfonic acid)" electrochim.Acta. 35. 63-64 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "A New Amperometric Glucose Sensor Based on Bilayer Film Coating of Redox Active Clay Film and Glucose Oxidase Enzyme Film" Bull.Chem.Soc.Jpn.63. 2646-2652 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "Polymer-Complex Mediated Enzyme Electrodes for Amperometric Determination of Glucose" J.Maeromol.Sci.-Chem.A27. 1203-1215 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "Probing Absorption of Deuterim into Palladium Cathodes During D_2 Electrolysis with an in situ Electrochemical Microbalance Technique" J.J.Appl.Phys.29. 818-821 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] A.J.KELLY: "Determination of in situ Solvent Transport by Isotopic substitution in an Osmium Polymer Film Using a Quartz Crystal Microbalance" J.Electroanal.Chem.287. 185-190 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "Electrochemical Calorimetry of D_2 Electrolysis Using a Palladium Cathode" Bull.Chem.Soc.Jpn.63. 2659-2664 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 大坂 武男: "交流インピ-ダンス法によるレドックス活性ポリ(1ーピレナミン)薄膜電極における電荷移動の評価" 高分子論文集. 47. 895-901 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "Surface-Modified Electrochemical Detectro for Flow Injection Analysis -Poly(N,N-dimethylaniline)-Coated Glassy Carbon Electrodes" Denki Kagaku. 58. 1136-1142 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Nobushige YAMAMOTO: "In situ Electrochemical Quartz Crystal Microbalance Studies of Water Electrolysis at a Palladium Cathode in Acidic Aqueous Media" J.Electroanal.Chem.296. 463-471 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "Formation of a Novel Electroactive Film by Electropolymerization of 5-Amino-1-naphthol" J.Electroanal.Chem.300. 51-66 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "Preparation of Polymer-Film Electrodes by Electropolymerization of 5-Amino-1-naphthol" Synth.Met.41-43. 3089-3092 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "Electrocatalysis of Poly(2,3-Diaminonaphthalene)-Filmed Electrodes for O_2 Reduction" J.Chem.Soc.Shem.Commun.487-489 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Masaya MIZUNUMA: "Investigation of Ion and solvent Transport Accompanying Redox Reaction of Polyvinylferrocene Films Using an in situ Electrochemical Quartz Crystal Microbalance Technique" Bull.Chem.Soc.Jpn.64. 2887-2893 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Andrew J.KELLY: "電気化学マイクロバラス法による電解重合ポリピロ-ル膜におけるイオンの動的挙動のin situ解析" 分析化学(Bunseki Kagaku). 40. 835-841 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Hideharu RIFUKU: "Quartz Crystal Microbalance Study on Redox Reaction Mechanism of Polyaniline" Synth.Met.41-43. 2897-2900 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Dirohisa MIYAMOTO: "Electrochemistry of New Heteroaromatic compounds of Pyrrolopyole" J.Electrochem.Soc.138. 2003-2008 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 小山 昇: "In Situ電気化学水晶発振子マイクロバランス法" 電気化学. 59. 937-942 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "A Redox-Active Polymer Film Mediated Electrodes for Amperometric Determination of Free Cholesterol" Electrocatalysis. 3. 665-671 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeo OHSAKA: "Electrocatalysis of O_2 Reduction at Poly(o-Phenylene-diamine)-and Poly(o-Aminophenol)-Coated Glassy Carbon Electrodes" J.Chem.Soc.Chem.Commun.1072-1073 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeyoshi OKAJIMA: "Electrode Kinetics of [Ru(NH_3)_6]^<3+/2+> Complex Confined in Montmorillonie Clay Coatings on Graphie Electrodes" J.Electroanal.Chem.315. 175-189 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeyoshi OKAJIMA: "Electrical Equivalent Circuit Prameters for Montmorillonite Clay Film-Coated Quartz Crystals in Contact with Air,Moisture and Electrolyte solutions" J.Phys.Chem.(1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Takeyoshi OKAJIMA: "Complex Admittance Measurements of Montmorillonie Clay/Poly(vinyl alchol) Composite Film-coated Quartz Crystal Oscillators in Contact with Air and Electrolyte solutions" Bull.Chem.Soc.Jpn.(1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 逢坂 哲弥: "電気化学法ー応用測定マニュアルー" 講談社サイエンティフィック, 283 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] 小山 昇: "高分子錯体ー動的相互作用と電子過程ー" 学会出版センタ-, 368 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "Macromolecular Complxes-Dynamics Interactuions and electronic Process" VCH-Publisher, 400 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Noboru OYAMA: "Molecular Design of Electrode Surfaces" John Wiley & Sons, 500 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, N. Yamamoto, O. Hatozaki, T. Ohsaka: "Probing Absorption of Deuterium into Palladium Cathodes During D_2O Electrolysis with an in situ Electrochemical Microbalance technique" J. J. Appl. Phys.29[5]. L818-L821 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] A. J. Kelly, T. Ohsaka, N. Oyama, R. J. Forster, J. G. Vos: "Determination of in situ Solvent Transport by Isotopic Substitution in an Osmium Polymer Film Using a Qaurtz Crystal Microbalance" J. Electroanal. Chem.287. 185-190 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Yamamoto , T. Ohsaka, T. Terashima, N. Oyama: "In situ Electrochemical Quartz Crystal Microbalance studies of Water Electrolysis at a Palladium Cathodes in Acidic Aqueous Media" J. Electroanal. Chem.296. 463-471 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Miyamoto, N. Oyama, T. Ohsaka, S. Tanaka, T, Miyashi: "Electrochemistry of New Heteroaromatic Compounds of Pyrrolopyrrole" J. Electrochem. Soc.138[7]. 2003-2008 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] H. Daifuku, T. Kawagoe, T. Matsunaga, N, Yamamoto, T. Ohsaka, N. Oyama: "quartz Crystal Microbalance Study on Redox Reaction Mechanism of Polyaniline" Synth. Met.41-43. 2897-2900 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] A. J. Kelly, K. Naoi, T. Ohsaka, N. Oyama: "In situ Analysis of the Kinetic Behavior of Ion Transport in Electropolymerized Polypyrrole by Electrochemical Quartz Crystal Microbalance Method" Bunseki Kagaku. 40. 835-841 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Mizunuma, T, Ohsaka, H. Miyamoto, N. Oyama: "Investigation of Ion and solvent Transport Accompanying Redox Reactions of Polyvinylferrocene Films Using an in situ Electrochemical Quartz Crystal Microbalance Technique" Bull. Chem. soc. Jpn.64[10]. 2887-2893 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Okajima, H. Sakurai, N. Oyama, K. Tokuda, T. Ohsaka: "Electrical Equivalent Circuit Parameters for Montmorillonite Clay Film-Coated Quartz Crystal Oscillators in Contact with Air, Moisture and Electrolyte solutions" J. Phys. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Okajima, H. Sakurai, N. Oyama, K. ToKuda, T. Ohsaka: "Piezoelectric Admittance Measurements for Montmorillonite Clay/Poly (vinyl alcohole) composite Film-Coated Quartz Crystal Oscillators in Contact with Air, Moisture and Electrolyte Solutions" Bull. Chem. Soc. Jpn.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] T. Ohsaka: "Analysis of Electron/Ion-Transfer Reactions of Polymeric Thin Films Using in situ Electchemical Microbalance Technique" Kobunshi. 39[12]. 862-865 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, K. Naoi, T. Ohsaka: "In situ Electrochemical Quartz Crystal Microbalance Technique" Denki Kagaku. 59[11]. 937-942 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, T. Ohsaka: "Study on Charge-Transfer Reactions Using Pulse Methods" Macromolecular Complexes. Gatsukai Shuppan Center. 243-262 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, T. Ohsaka: "Preparation of Organic Films" Electrochemical Methods-Applications. Kodansha Scientific Co.126-149 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, T. Ohsaka: "Electrochemical Pulse Analysis of Multielectron Transfer in Electroactive Macromolecular Complexes" Macromolecular Complexes-Dynamic Interactions and Electronic Processes-. VCH-Publisher. 275-313 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, T. Ohsaka: "Voltammetric Diagnosis of Charge Transport on Polymer-Coated Electrodes" Molecular Design of Electrode Surfaces. Johu Wiley & Sons.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] N. Oyama, T. Ohsaka: "Electron Transfer and Mass Transfer Kinetics in Electroactive Polymer Films" Progress in Polymer Science. Pregamon Press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Masaya MIZUNUMA: "Investigation of Ion and Solvent Transport Accompanying Redox Reaction of Polyvinylferrocene Films Using an in situ Electrochemical Quart Crystal Microbalance Technique" Bull.Chem.Soc.Jpn.64. 2887-2893 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Andrew J.KELLY: "電気化学マイクロバランス法による電解重合ポリピロ-ル膜におけるイオンの動的挙動のin situ解析" 分析化学(Bunseki Kagaku). 40. 835-841 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Hideharu DIFUKU: "Quart Crystal Microbalance Study on Redox Reaction Mechanism of polyaniline" Synth.Met.41ー43. 2897-2900 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Hirohisa MIYAMOTO: "Electrochemistry of New Heteroaromatic Compounds of Pyrrolopyrrole" J.Electrochem.Soc.138. 2003-2008 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 小山 昇: "In Situ電気化学水晶発振子マイクロバランス法" 電気化学. 59. 937-942 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeo OHSAKA: "Formation of a Novel Electroactive Film by Electropolymerization of 5ーAminoー1ーnaphthol" J.Electroanal.Chem.300. 51-56 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeo OHSAKA: "Preparation of PolymerーFilm Electrodes by Electropolymerization of 5ーAminoー1ーnaphthol" Synth.Met.41ー43. 3089-3092 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeo OHSAKA: "Electrocatalysis of Poly(2,3ーDiaminonaphthalene)Filmed Electrodes for O_2 Reduction" J.Chem.Soc.Chem.Commun.487-489 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Noboru OYAMA: "A RedoxーActive Polymer Film Medated Electrode for Amperometric Determination of Free Cholesterol" Electrocatalysis. 3. 665-671 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeo OHSAKA: "Electrocatalysis of O_2 Reduction at Poly(oーphenyleneーdiamine)ーand Poly(oーAminophenol)ーCoated Glassy Carbon Electrodes" J.Chem.Soc.Chem.Commun.1072-1073 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeyoshi OKAJIMA: "Electrical Equivalent Circuit Parameters for Montmorillonite Clay FilmーCoated Quartz Crystals in Contact with Air,Moisture and Electrolyte Solutions" J.Phys.Chem.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeyoshi OKAJIMA: "Electrode Kinetics of [Ru(NH_3)_6]^<3+/2+> Complex Confined in Montmorillonite Clay Coatings on Graphite Electrodes" J.Electroanal.Chem.315. 175-189 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Noboru OYAMA: "Macromolecular ComplexesーDynamic Interactions and Electronic Process" VCHーPublisher, 400 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 小田 昇: "高分子錯体ー動的相互作用と電子過程ー" 学会出版センタ-, 368 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Noboru OYAMA: "Molecular Design of Electrode Surfaces" John Wiley & Sons, 500 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Takeo OHSAKA: "Electrode Kinetics of Thin Polymer Complex Films Composed of Poly(alkyleneviologen)and Poly(pーstyreneーsulfonic acid)" Electrochim.Acta. 35. 63-64 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeo OHSAKA: "A New Amperometric Glucose Sensor Based on Bilayer Film Coating of Redox Active Clay Film and Glucose Oxidase Enzyme Film" Bull.Chem.Soc.Jpn.63. 2646-2652 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Noboru OYAMA: "PolymerーComplex Mediated Enzyme Electrodes for Amperometric Deterination of Glucose" J.Macromol.Sci.ーChem.A27. 1203-1215 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Noboru OYAMA: "Probing Absorption of Deuterium into Palladium Cathodes During D_2O Electrolysis with an in situ Electrochemical Microbalance Technique" J.J.Appl.Phys.29. 818-821 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] A.J.Kelly: "Determination of in situ Solvent Transport by Isotopic Substitution in an Osmium Polymer Film Using a Quartz Crystal Microbalance" J.Electroanal.Chem.287. 185-190 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Noboru OYAMA: "Electrochemical Calorimetry of D_2O Electrolysis Using a Palladium Cathode" Bull.Chem.Soc.Jpn.63. 2659-2664 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 大坂 武男: "交流インピ-ダンス法によるレドックス活性ポリ(1ーピレナミン)薄膜電極における電荷移動の評価" 高分子論文集. 47. 895-901 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeo OHSAKA: "SurfaceーModified Electrochemical Detector for Flow Injection AnalysisーPoly(N,Nーdimethylaniline)ーCoated Glassy Carbon Electrodes" Denki Kagaku. 58. 1136-1142 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Nobushige YAMAMOTO: "In situ Electrochemical Quartz Crystal Microbalance Studies of Water Electrolysis at a Palladium Cathode in Acidic Aqueous Media" J.Electroanal Chem.296. 463-471 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeo OHSAKA: "Formation of a Novel Electroactive Film by Electropolymerization of 5ーAminoー1ーnaphthol" J.Electroanal Chem.300. 51-66 (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeo OHSAKA: "Preparation of PolymerーFilm Electrodes by Electropolymerization of 5ーAminoー1ーnaphthol" Synth.Met.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Takeo OHSAKA: "Electrocatalysis of Poly(2,3ーDiaminonaphthalene)ーFilmed Electrodes for O_2 Reduction" J.Chem.Soc.Chem.Commun.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] 逢坂 哲弥: "電気化学法ー応用測定マニュアルー" 講談社サイエンティフィック, 283 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2016-04-21  

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