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Light-Induced Self Organization Phenomena in Polymer Alloys and Its Application to Design Novel Polymer Materials.

Research Project

Project/Area Number 02805112
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 高分子物性・高分子材料(含機械材料)
Research InstitutionKyoto Institute of Technology

Principal Investigator

TRANーCONG Qui  Kyoto Institute of Technology, Assistant Professor, 繊維学部, 助手 (50188827)

Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1991: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1990: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsPolymer Alloy / Polystyrene / Poly (vinyl methyl ether) / Polybutadiene / Photo-Cross-Link / Photodimerization / Reaction-Diffusion / Rayleigh-Benard Instability / アントラセン / 二量化反応 / ポリマ-アロイ / 光架橋 / 熱力学的不安定性 / 反応ー拡散機構 / 自己組織化
Research Abstract

The Purposes of this work are :
1) Investigation of the self organization process in binary Polymer blends irradiated with UV light.
2) Elucidation of the possibility for taking advantage of this mechanism to design novel polyner materials with the ordered structures in micrometer range.
At first, Polystyrene/poly(2-chlorostyrene)(PS/P2CS)and polystyrene/poly(vinyl methyl ether)(PS/PVME)blends were irradiated during the time evolution of the spinodal decomposition Process. The photo-cross-link reactions between PS chains are induced via the photodimerization of anthracene moieties which are covalently attached to PS chains. The effects of irradiation intensity, irradiation time, annealing temperature and T-jump depths on the resulting morphology were examined by using phase-contrast optical microscope, light scattering and small-angle X-ray scattering.
The following results were obtained :
- The concentration fluctuations developing during the spinodal decomposition process were efficiently … More frozen upon irradiation with either XeF excimer laser or ffg lamp. These results indicate that by taking advantage of photo-cross-link reactions, multiphase polymer materials with various ordered structures in the mum range can be designed.
- Further analysis of the ordered structures resulting from irradiation shows that the reaction between PS does not only freeze the concentration fluctuations but also modify these structures. 'For PS/P2CS submitted to a shallow T-jump, the light scattering profile exhibits multiple scattering peaks, revealing the unusual effects of irradiation.
- To separate the contribution of the spinodal structures to the effects of. photo-cross-link, irradiation experiments were performed in the one-phase region of Polystyrene/polybutadiene(PS/PB). It was found that photo-cross-link reactions between PB chains result in the large modulated structures with internal domains
- A reaction-diffusion model taking into account of the nonlinear reactions between polymer chains in a binary polymer mixture was proposed in ordered to explain these morphology. Alternatively, there is another possibility for the origin of the ordered structures revealed by irradiation with laser, That is the convection caused by the extra heat originated from the radiationless process of'excited anthracenes. Actually, the morphology obtained by irradiating PSA/P2CS blends with XeF excimer laser shows the typical dissipative structures of the Rayleigh-Benard type.
The competition between reaction-diffusion Turing instability and Rayleigh-Benard instability for polymer alloys irradiated with light is currently investigated by computer simulation. Less

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] Q.TRAN-CONG et al: "Structure/Property Relationship in Binary Polymer Blends Photo-Crosslinked During the Spinodal Decomposition Process" Polym.Mat.Sci.Eng.62. 706-711 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRAN-CONG et al: "Ordered Structures Resulting from Photo-Croslink of Binary Polmer Blends Undergoing Phase Separation" in "Dynamics and Patterns in Complex Fluids",A.Onuki and K.Kawasaki Eds.,Spininger-Verlag,New York.59-60 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRAN-CONG et al: "Structure of Polymer Blends Photo-Crosslinked During te Spinodal Decomposition Process" Macromolecules. 24. 1505-1510 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRANSーCONG: "光架橋によるポリマ-ブレンドのモルヘロジ-制御" 機能材料. 12(5). (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRAN-CONG et al.: "Controlling Morphology of Polystyrene/Poly(vinyl methyl ether)Blends Undergoing Spinodal Decomposition Process by Photo-Crosslink" Polym.Sci.Eng.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRAN-CONG et al.: "Phase Behanvior and Morphology of Polystyrene/Polybutadiene Oligomer Blends Photo-Crosslinked in the One-Phase Region." J.Polym.Sci.Polym.Phys.Ed.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. Tran-Cong et al.: "Sturucture/Property Relationship in binary Polymer Blends Photo-Crosslinked During the Spinodal Decomposition Process" Polym. Mat. Sci. Eng.62. 706-711 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. Tran-Cong et al.: "Ordered Structures Resulting from Photo-Crosslink of Binary Polymer Blends Undergoing Phase Separation" "Dynamics and Patterns in Complex Fluids". Springer Verlag, New York.59-60 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. TRAN-CONG et al.: "Structure of Polymer Blends Photo-Crosslinked During the Spinodal Decomposition Process" Macromolecules. 24. 1505-1510 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. TRAN-CONG: "Controlling Morphology of Polymer Blends by Photo-Crosslink (in Japanese)" 12(5). (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. TRAN-CONG et al.: "Controlling Morphology of Polystyrene/Poly (vinyl methyl ether) Blends Undergoing Spinodal Decomposition Process by Photo-Crosslink" Polym. Sci. Eng.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q. TRAN-CONG et al.: "Phase Behavior and Morphology of Polystyrene/Polybutadiene Oligomer Blends Photo-Crosslinked in the One-Phase Region." J. Polym. Sci. Polym. Phys. Ed.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Q.TRANーCONG et al.: "Structure of Polymer Blends PhotoーCrosslinked During the Spinodal Decomposition Process" Macromolecules. 24. 1505-1510 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Q.TRANーCONG et al.: "Controlling Morphology of Polystyrene/Poly(vinyl methyl ether) Undergoing Spinodal Decomposition Process by PhotoーCrossーlinks." Polym.Sci.Eng.

    • Related Report
      1991 Annual Research Report
  • [Publications] Q.TRANーCONG et al.: "Phase Behavior and Morphology of Polybutadiene/Polystyrene Blends PhotoーCrosslinked in the Miscible Region" J.Polym.Sci.Polym.Phys.Ed.

    • Related Report
      1991 Annual Research Report
  • [Publications] Q.TRANーCONG: "光架橋によるポリマ-ブレンドのモルホロジ-制御" 機能材料. 12(5). (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] QUI TRANーCONG et al.: "“Immobilization of Transient Structures in Polystyrene/Poly(2ーchlorostyrene)Blends Undergoing Phase Separation by Using PhotoーCrossーLinking"" MACROMOLECULES. 22. 2720-2723 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] QUI TRANーCONG et al.: "“Structure/Property Relationship in Binary Polymer Blends PhotoーCrossーLinked During the Spinodal Decomposition Process"" POLYM.MAT.SCI.ENG.(ACS). 62. 706-711 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] QUI TRANーCONG et al.: "“Stucture of Polymer Blends PhotoーCrossーLinked During the Spinodal Decomposition Process"" MACROMOLECULES. 24. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] QUI TRANーCONG et al.: "“Ordered Structures Resulting from PhotoーCrossーLinks of Binary Polymer Blends Undergoing Phase Separation"" in“DYNAMICS AND PATTERNS IN COMPLEX FLUIDS" A.Onuki and K.Kawasaki Eds.,SpringerーVerlag,New YorkーBerlinーHeidelberg. 59-60 (1990)

    • Related Report
      1990 Annual Research Report

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Published: 1990-04-01   Modified: 2021-04-07  

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