• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

分子設計の基礎と展開

Research Project

Project/Area Number 03214104
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionOsaka University

Principal Investigator

村田 一郎  大阪大学, 理学部, 教授 (90028077)

Co-Investigator(Kenkyū-buntansha) 竹内 賢一  京都大学, 工学部, 教授 (50026358)
新海 征治  九州大学, 工学部, 教授 (20038045)
大木 道則  岡山理科大学, 理学部, 教授 (40011407)
今村 詮  広島大学, 理学部, 教授 (70076991)
安藤 亘  筑波大学, 化学系, 教授 (30008429)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥8,700,000 (Direct Cost: ¥8,700,000)
Fiscal Year 1991: ¥8,700,000 (Direct Cost: ¥8,700,000)
Keywords分子設計理論 / 分子の動的性質 / 分子認識場 / 不安定分子種 / 電子授受 / ヘテロ原子
Research Abstract

1.平成3年6月21日(金)、22日(土)の二日間、仙台市商工会議所ホ-ルにおいて平成3年度第一回公開シンポジウムを行った。こゝでは計画研究班員会員の他、評価班から桜井、吉田、三角、長倉の四教授、一般より66名の出席を得て、13名の班員の研究発表が行われた。発表会終了後、長倉教授より全体に亘っての講評を頂いた。
2.上記シンポジウム初日の昼食時に総括班会議を開き、評価班の吉田、三角教授の出席を得て主として予算、今年度の活動方針並びに最終年度の成果報告および本領域の成果取り纏めについて協議した。また、A04班岩村秀班長の特別推進研究採択内定に伴い、同班の班長候補者として京大・工・竹内賢一教授を内定した。また二日目昼食時に各班会議を行ない各種亊務連絡の他、第二回シンポジウム発表者を決定した。
3.各研究班では次のように研究連絡会議を開き、研究進行状況および問題点について討論を行った。A01(北大・理)、A02(東大・理)、A03(東京ガ-デンパレス)、A04(名大・理)、A05(富山高志会館)、A06(作並)。これらの会議には理論班から1〜2名の参加を得て理論の立場からの助言を得たことは実験班員にとって有益であった。
4.平成4年1月20日(月)、21日(火)の二日間、新大阪シティプラザにおいて本年度第二回公開シンポジウムを行ない、計画班11名の研究発表があり、それぞれ極めて活発な討論があった。本シンポジウム中にも総括班会議、および班会議が開かれ、最終年度の成果取り纏め、事務連絡を行った。
5.ニュ-スレタ-No.3の発行を行った。
6.総括班で購入し阪大・理に設置されている質量分析計では、竹内(東大・教養)管原(東大・教養)、大木(岡山理大)等の班員の試料測定を行ない、有効に利用された。

Report

(1 results)
  • 1991 Annual Research Report

Research Products

(60 results)

All Other

All Publications (60 results)

  • [Publications] S.Sasaki,K.-U.Klabunde,I.Murata,J.Toyoda,and K.Nakasuji: "Synthesis of a Highly Amphoteric 8,16-Diisopropyl-s-indaceno[1,2,3-cd;5,6,7,-c'd']diphenalene:Switching Between Diatropism and Para-tropism Accompanied by Its Oxidation Levels" Angew. Chem.,Int.Ed.Engl.30. 172-173 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Nakasuji,K.Sugiura,T.Kitagawa,J.Toyoda,H.Okamoto,I Murata.etal: "Exploration of New Cooperative Proton-Electron Transfer (PET) System First Example of Extended Conjugated Quinhydrones,1,5-Dihalo-2,6-naphthoquinones" J.Am.Chem.Soc.113. 1862-1864 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Nishino,M.Takagi,T.Kawata,I.Murata,J.Inanaga,K.Nakasuji: "Thiepine-iron Tricarbonyl:Stabilization of Thermally Labile Parent Thiepine by Transition Metal Complexation" J.Am.Chem.Soc.113. 5059-5060 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Sugihara,J.Saito,I.Murata: "2-Triphenylmethyldicyclohept[cd,g]indene:A Novel Cata-Peri Condensed Nonalternant Hydrocarbon" Angew.Chem.Int.Ed.Engl.30. 1174-1176 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] J.Toyoda,K.Nakasuji,T.Kotani,I.Murata,A.Kawamoto,J.Tanaka: "The Crystal Structure and Physical Properties of the 3:2 Charge Transfer Complex of Bis(ethylenedithio)dithiapyrene (ETDTPY) and Dibenzobarrelenotetracyanoquinodimethane" Chem.Lett.1237-1240 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Sugihara,T.Yagi,I.Murata,A.Imamura: "1-Phenylthieno[3,4-d]borepine:A New 10 pi Electron System Isoelectronic with Azulene" J.Am.Chem.Soc.114. 1479-1481 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Sakakibara,Y.Kabe,T.Shimizu,W.Ando: "Molecular Interactions of Polysilane and Unsaturated Nitrogen Compounds.Photochemical Addition of Disilene versus Silylene to Azobenzene" J.Chem.Soc.,Chem.Commun.43-44 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Shimizu,K.Shimizu,W.Ando: "Synthesis,Structure,and Stabilities of trans-1,2-Diphenyl-4,4,5,5,6,6-hexamethyl-4,5,6-trisilacycloheptene" J.Am.Chem.Soc.113. 354-355 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Akasaka,A.Sakurai,W,Ando: "Cooxidation Reaction in the Singlet Oxygenation of Cyclic and Benzylic Sulfudes:S-Hydroperoxysulfonium Ylide Intermediate as a New Epoxidizing Species" J.Am.Chem.Soc.113. 2696-2701 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] W.Ando,T.Yamamoto,H.Saso,Y.Kabe: "Stable η^4-Silatrimethylenemethane Transition-metal Complexes by the Reaction of Alkylidenesilirane with Metal Carbonyl" J.Am.Chem.Soc.113. 2791-2793 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] W.Ando,N.Tokitoh,Y.Kabe: "Synthesis and Reaction of Novel Sulfur containing Heterocyclic Systems" Phosphorus,sulfur,and Silicon. 58. 179-205 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] W.Ando,M.Kako,T.Akasaka: "Direct observation of an Azetidinium Imide Intermediate in[π^2+σ^2]Addition of 1,2,4-Triazoline-3,5-dione to Disirane" J.Am,Chem.Soc.113. 6286-6288 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] W.Ando,T.Ohtaki,T.Suzuki,T.Kabe: "The First Stable Enethiolizable Thioaldehyde via a Zirconocene η^2-Thioacyl Complex" J.Am,Chem.Soc.113. 7782-7784 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] W.Ando,H.Yoshida,K.Kurishima,M.Sugiyama: "Intramolecular Reaction of 1,5-Disila-1,4-Pentadiene:Formation of 2,4,5-Trisilabicyclo[1.1.1]pentane and 2,3,5-Trisilabicyclo[2.1.0]pentane" J.Am,Chem.Soc.113. 7790-7792 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Akasaka,K.Sato,M.Kako,W.Ando: "Formation of 1,2,3,6-Dioxadisilin in Photo-induced Electron Transfer Oxygenation of 1,2-Disiletene" Tetrahedron Lett.32. 6605-6608 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Shin-ichiro Hayashi: "Ab initio calculation of linear and nonlinear polariza-bilities in the side-chain direction on the conjugated polymers" Chem.Phys.Lett.,. 179. 405-409 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Kazuhiro Shimofuji: "Unimolecular Thermal Decomposition of Ethyl Vinyl Ether and the Consecutive Thermal Reaction of the Intermediary Product Acetaldehyde:Shock Wave Experiment and ab Initio Calculation" J.Phys.Chem.,. 95. 155-165 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Yuriko Aoki: "Self-consistent-field perturbational approach to aperiodic polymers" J.Molec.Struct.(Theochem). 235. 95-105 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Akira Imamura: "A theoretical synthesis of polymers by using uniform localization of molecular orbitals Proposal of an elongation method" J.Chem.Phys.,. 95. 5419-5431 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Yoshikazu Sugahara: "1-Phenylthieno(3,4-d)borepine:A New 10π Electron System Isoelectronic with Azulene" J.Amer.Chem.Soc.,.

    • Related Report
      1991 Annual Research Report
  • [Publications] Yuriko Aoki: "A Simple Treatment to Design NBMO Denerate Systems in Altermant and Non-Altermant Hydrocarbons" Theoret.Chim .Acta.

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XVII.Dissociation of the N-B Bond in the Coor-Dinated form of 2-[2-Dimethylaminomethyl)phenyl]-4,4-diphenyl-1,3,2-dioxaborolane and Related Compounds" Bull.Chem,Soc.Jpn.63. 1168-1173 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XVIII.Factors Affecting the Rates of Dissociation of N-B Bond in the Coordinated Form of 9[2-(Dialkylaminomethlyl)-phenyl]-9-borabicyclo[3.3.1]nonanes" Bull.Chem,Soc.Jpn.64. 1554-1562 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determinaion of Rates of Dissociation.XIX.Sulfur Inversion in 9-[2-(Ethylthiomethyl)-phenyl]-9-borabicyclo[3.3.1]nonane Proceeds via Dissociative Mechanism" Bull.Chem,Soc.Jpn.64. 1563-1569 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Toyota: "Structure of Boron-Amine Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Stucture and Barrier to Dissociation of the N-B Bonds" Bull.Chem,Soc.Jpn.

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Toyota: "Dynamic NMR as a Nondestructive Method for the Determination of Rates of Dissociation.XX.Secondary Isotope Effect on Kinetic Basicity of Amine Ligands in a Boronate-Amine Complex and an Ammonum Salt"

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Coordination Compounds."

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of Amine Ligands in Some Intramolecular Coordination compounds"

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Oki: "Effects of Molecular Size of Solvent on Dissociation of the N-H Bond in Ammonium Salts"

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Shinkai: "Ion Template Effects on the Conformation of Water-Soluble Calixarenes." J.Org.Chem.56. 295-300 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Matsuda: "New Water-Soluble Calixarenes Bearing Chiral Substituents." J.Org.Chem.56. 301-306 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Shinkai: "New Syntheses and Physical Properties of p-Alkylcalix[n]arenes." Bull.Chem.Soc.Jpn.64. 381-386 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Iwamoto: "Syntheses of New Isomers form p-t-Butyl-calix[4]arene:Strategies for Regioselective Alkylation on the Lower Rim." Chem.Lett.473-476 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Yamada: " ^1H and ^<13>C Nuclear Magnetic Resonance Relaxation-time Studies of Ionophoric Calixarene Esters." J.Chem.Soc.Perkin Trans.2. 793-797 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Arimura: "Formation of Molecular Complexes with Calixarenes as Detected by Induced ciruclar Dichroism." Bull.Chem.Soc.Jpn.64. 1896-1900 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Iwamoto: "How is the 1,2-Alternate Conformer Formed in Tetra-O-alkylation of p-Tert-Butyl-calix[4]arene?" J.Chem.Soc.,Perkin Trans.1. 1611-1613 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Iwamoto: "Syntheses of All Possible Conformational Isomers of O-Alkyl-p-t-Butylcalix[4]arenes." Tetrahedron. 47. 4325-4342 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Tsukagoshi: "Specific Complexation with Mono-and Disaccharides That Can be Detected by Circular Dichroism." J.Org,Chem.56. 4089-4091 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Nagasaki: "Synthesis and Solvent Extraction Studies of Novel Calixarene-based Uranophiles Bearing Hydroxamate Groups." J.Chem.Soc.,Perkin Trans.2. 1063-1066 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Nagasaki: "A New Calix[6]arene-based Uranophile with Phosphonate Groups as Ligands." Bull.Chem.Soc.Jpn.56. 2575-2577 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Iwamoto: "Conformations and Structures of Tetra-O-alkyl-p-tert-butylcalix-[4]arenes.How is the Conformation of Calix[4]arene Immobilized?" J.Org.Chem.56. 4955-4962 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Shinkai: "Molecular Recognition of Mono-and Di-saccharides by Phenylboronic Acids in Solvent Extraction and as a Monolayer." J.Chem.Soc.,Chem.Commun.1039-1041 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Nagasaki: "Kinetic Studies of Calixarene-based Cyclic and Non-cyclic 'Super-uranophiles'." J.Chem.Soc.,Perkin Trans.2. 1325-1327 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Arimura: "Calixarene-based Molecular Capsule." Tetrahedron Lett.32. 1715-1718 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Shinkai: "Chiral Calix[4]arene." J.Chem.Soc.,Perkin Trans.1. 2429-2434 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Shimizu: "Chromogenic Calix[4]arene." Chem.Lett.2147-2150 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Shinkai: "pK_a Determination of Water-Soluble Calix[4]arenes." J.Chem.Soc.,Perkin Trans.2. 1883-1886 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Aonuma,K.Komatsu,N.Maekawa,and K.Takeuchi: "Enhanced Polarization of Heptafulvene and Tropone by Annelation with Three Bicylclo[2.2.2]octene Frameworks" Chem.Lett.767-770 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Komatsu,H.Kamo,R.Tsuji,H.Masuda,and K.Takeuchi: "4-Homoadamantyne:Generation,Chemical Trapping and Structure of Its Pt(O) Complex" J.Chem.Soc.,Chem.Commun.71-72 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Komatsu,S.Aonuma,Y.Jinbu,R.Tsuji,C,Hirosawa,and K.Takeuchi: "Generation and Oligomerization of Bicyclo[2.2.2]octyne and Properties of Tris(bicyclo[2.2.2]octeno)benzene Obtained from the Linear Trimer" J.Org.Chem.56. 195-203 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Ikai,K.Takeuchi,T.Kinoshita,K.Haga,K.Komatsu,and K.Okamoto: "Stereomutation of 7-Tropylionorbornane,2-Tropyliobicyclo[2.2.2-]-octane,and 2-Tropylioadamantane:Evidence for the Intermediacy of Heptafulvenes" J.Org.Chem.56. 1052-1058 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Komatsu,H.Akamatsu,S.Aonuma,Y.Jinbu,N.Maekawa,and K.Takeuchi: "Formation,Properties,and Reactions of the 1,2:3,4:5,6-Tris(bicyclo[2.2.2]octeno)tropylium Ion" Tetrahedron. 47. 6951-6966 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Tsuji,K.Komatsu,Y.Inoue,and K.Takeuchi: "1-Naphtyltropylium Ions Having Condensed Aromatic Rings at the 8-P-sition:Dependence of the Intramolecular Charge-Transfer Interaction upon Geometry of the Donor" J.Org.Chem.57. 636-641 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Small Difference in Cation Stability in Contyolling the Formation of Hydrocarbon Salt or Covalent Hydrocarbon" Chem.Lett.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Miyabo,T.Kitagawa,And K.Takeuchi: "Significance of Steric Effect in the Heterolysis of Carbon-Carbon σ Bond in Ionically Dissociative Hydrocarbons" Chem.Lett.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kitagawa,K.Takeuchi,K.Komatsu,and T.Kinoshita: "Syntheses and Properties of Hydrocarbon Salts and Ionically Dissociative Hydrocarbons" J.Synth.Org.Chem.Jpn.

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kinoshita,H.Kimura,I.Nakajima,K.Takeuchi,and K.Okamoto: "Synthesis and Properties of 1,2,4-Tris(7H-dibenzo[c,g]-fluorenylidenemetyl)cyclopentadienide Ion"

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Komatsu,T.Nishinaga,N.Maekawa,Y.Kagayama,and K.Takeuchi: "Syntheses and Redox Behavior of the p-Phenylenebis-and Acetylenebis[tris(bicyclo[2.2.2]octeno)tropylium]Dications"

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Precise Control of Covalent and Ionic Bond Formation in Carbocation-Carbanion Combination Reaction"

    • Related Report
      1991 Annual Research Report
  • [Publications] A.Miyabo,T.Kitagawa,and K.Takeuchi: "Heterolysis of Carbon-Carbon σ Bond in Hydrocarbons:Significance of Steric Effect"

    • Related Report
      1991 Annual Research Report

URL: 

Published: 1991-03-31   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi