| Project/Area Number |
03303010
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| Research Category |
Grant-in-Aid for Co-operative Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
高分子合成
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| Research Institution | Nagoya University |
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Principal Investigator |
OKAMOTO Yoshio Nagoya University. Faculty of Engineering, Professor, 工学部, 教授 (60029501)
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| Co-Investigator(Kenkyū-buntansha) |
NAKAHAMA S Tokyo Inst. of Tec., Fac. of Eng., Professor, 工学部, 教授 (90016410)
TAKEMOTO K Osaka Univ., Fac. of Eng., Professor, 工学部, 教授 (50029170)
MATSUDA M Tohoku Univ., Inst. of Chem. Rec. Sci., Professor, 非水溶液化学研究所, 教授 (90006297)
SHIMIZU T Kyoto Univ., Fac. of Eng., Professor, 工学部, 教授 (10025893)
KUNITAKE T Kyushu Univ., Fac. of Eng., Professor, 工学部, 教授 (40037734)
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| Project Period (FY) |
1991 – 1992
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| Project Status |
Completed (Fiscal Year 1992)
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| Budget Amount *help |
¥8,500,000 (Direct Cost: ¥8,500,000)
Fiscal Year 1992: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1991: ¥5,700,000 (Direct Cost: ¥5,700,000)
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| Keywords | Molecular recognition / Higher-order structure / Living polymerization / Chiral recognition / Stereo-control / Photofunctional material / Enzymatic polymerization / Polysaccharide / ポルフィリン / 光機能 / 糖 / オリゴペプチド |
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| Research Abstract |
Through this research project, interesting and meaningful results were obtained on the following subjects concerning synthesis and application of polymers capable of material recognition. (1) Ability of Photo-recognition (construction of higher-order structure, synthesis of oligonucleotides with prophyrin residue, synthesis of polysilane with difined structure); (2) Ability of Molecular Recognition (molecular recognition of polymers with nucleosides and nucleotides, synthesis of polymers with well-difined structure by living anionic polymerization and living cationic polymerization); (3) Ability of Chiral Recognition (enantioselective synthesis of cyanhidrin with dipeptide complexes, optical resolution by polysaccharide derivative, enzymatic synthesis of cellulose, synthesis of ionopher with saccharide); (4) Ability of Macromolecular Recognition (synthsis of polysaccharides, complex formation by stereoregular polymethacrylates, Synthesis of sequential polymers)
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