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High frequency electrical conductivity of Organic conductors

Research Project

Project/Area Number 03452046
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 固体物性
Research InstitutionToho University

Principal Investigator

KAJITA Koji  Toho University,Faculty of Science,Professor, 理学部, 教授 (50011739)

Co-Investigator(Kenkyū-buntansha) NISHIO Yutaka  Toho University,Faculty of Science,Associate Professor, 理学部, 助教授 (20172629)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥6,500,000)
Fiscal Year 1992: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1991: ¥5,200,000 (Direct Cost: ¥5,200,000)
KeywordsHigh Frequency Transport / alpha-(Bedt-TTF)_2I_3 / Metal-Non Metal Transition / 金属-非金属転移 / 有機金属 / αー(BEDTーTTF)_2I_3 / 金属ー非金属転移 / マイクロ波伝導度
Research Abstract

In the experiment, we did in 1992, we discovered that the microwave conductivity of alpha-(BEDT-TTF)_2I_3 shows an anomalous anisotropy when the system passes the phase boundary between the metallic state and the insulating state at 135K. In the electric field in the a-direction of the crystal axis, the conductivity decreases monotonically through the metal-insulator transition. While, in the field along the b-direction, the conductivity increases just above the transition and then decreases abruptly below the transition temperature.
The first experiment, we performed this year is to check if the anomalous anisotropy of the conductivity depends on the frequency in which we have measure the conductivity. We have adopted the Montgomery method by which we can measure the conductivity along the a-direction and the b-direction, simultaneously.
We found that the anomalous anisotropy of the conductivity is independent of the frequency. We also found that the phase transition at 135K is not so simple as we have expected. We have found that the anisotrpopy of the conductivity changes not only at the transition temperature(135K) but also at the temperature about 0.5K below the transition temperature.
The second experiment we have done is the survey of the metal-insulator transition under the pressures. In the investigation we did in 1992, we found that in a very high pressure, the metal-insulator transition is suppressed so that the system remains metallic down to low temperatures.
When we apply a magnetic field on such a system, we found that the metal-insulator transition appears again. We call this new phase as the "magnetic field induced insulating state".
We have done the Hall effect measurement for such systems. We found that in the magnetic field induced insulator phase, the carrier density becomes very low. The second discovery on the field induced insulator is that the carrier density at a constant temperature depends strongly on the strength of the magnetic field.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] K.Kajita,Y.Nishio,T.Takahashi,W.sachii,H.Kobayashi,A.Kobayashi,R.Kato,Y.Iye: "Anomalons Magnetoresistance in Organic Conductors and the Llimen soonality of the Electron System" Synthetic Metals. 41〜43. 2075-2078 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kajita,T.Nishida,T.Ojiro,H.Fujii,H.Kobayashi,R.Kato,Y.Iye,A.Kobayashi,Y.Sasaki: "Low Temperature Electronic State of Organic-(Super)conductors:α-,θ-and K-(BEDT-TTF)_2I_3" JJAP reries7 ¨Mechanism of Superconductivity¨. 390-394 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kajika,T.Ojiro,H.Fujii,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato: "Magneto transpcert phenomena of α-(BEDT-TTF)_2I_3 Under High Pressures" J.Phyo.Sac.Jpn.61. 23-26 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Nishima,K.Kajita,O.Kanke,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato,M.Kobayashi: "The Metel-Insulator Transition in the Organic Cnductor α-(BEDT-TTF)_2I_3-Viewed by Microwave" Synthetic Metals. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Ojiro,K.Kajita,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato,Y.Iye: "An anomalous Magnetoresistance in α-(BEDT-TTF)_2I_3 under High Pressure:A Passible New Phase" Physica B. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Ojiro,K.Kajita,Y.Nishio,H.Kobayashi,A.Kobayashi,R.kato,Y.Iye: "A New Magneto-Pressure Phase in α-(BEDT-TTF)_2I_3" Synthetic Metals. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Mishima, K.Kajita, O.Kanke, Y.Nishio, H.Kobayashi, A.Kobayashi, R.Kato and M.Kobayashi: "The Metal-Insulator Transition in the Organic Conductor alpha-(BEDT-TTF)_2I_3--viewed by Microwave" Synthetic Metals. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kajita, Y.Nishio, T.Takahashi, W.Sasaki, H.Kobayashi, A.Kobayashi, R.Kato and Y.Iye: "Anomalous Magnetoresistance in Organic Conductors and the Dimensionality of the Electron System" Synthetic Metals. 41-43. 2075-2078 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kajita, Y.Nishio, T.Ojiro, H.Fujii, H.Kobayashi, R.Kato, Y.Iye, A.Kobayashi and W.Sasaki: "Low Temperature Electronic State of Organic-(Super)Conductors: alpha-, rheta- and kappa-(BEDT-TTF)_2I_3" JJAP series 7 Mechanism of Superconductivity. 390-394 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] K.Kajita, T.Ojiro, H.Fujii, Y.Nishio, H.Kobayashi, A.Kobayashi and R.Kato: "Magnetotransport Phenomena of alpha-(BEDT-TTF)_2I_3 under High Pressures" J. Phys. Soc. Jpn.61. 23-26 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Ojiro, K.Kajita, Y.Nishio, H.Kobayashi, A.Kobayashi, R.Kato and Y.Iye: "An Anomalous Magnetoresistance in alpha-(BEDT-TTF)_2I_3 under High Pressure :A Possible New Phase" Physica B. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Ojiro, K.Kajita, Y.Nishio, H.Kobayashi, A.Kobayashi, R.Kato and Y.Iye: "A New Magneto-Pressure Phase in alpha-(BEDT-TTF)_2I_3" Synthetic Metals. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Mishima,K.Kajita,O.Kanke,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato,M.Kobayashi: "The Metal-Insulator Transition in the Organic Conducter α-(BEDT-TTF)_2I_3" Synthetic Metals.

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kajita,T.Ojiro,H.Fujii,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato: "Magnetotranspont phenomena of α-(BEDT-TTF)_2I_3 under High Pnessures" J.Phyo.Sac.Jpn.61. 23-26 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Ojino,K.Kajita,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato,Y.lye: "An anomalons Magnetoresis tance in α(BEDT-TTF)_2I_3 under High Pressure A Possible New Phase." Physica B.

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Ojino,K.Kajita,Y.Nishio,H.Kobayashi,A.Kobayashi,R.Kato,Y.lye: "A Nuo Magneto-Pressune Phase in α-(BEDT-TTF)_2I_3" Synthetic Metals.

    • Related Report
      1992 Annual Research Report
  • [Publications] 梶田 晃示: "Anomalous Magnetoresistanee in Organic Conductors and the Dimensionality of the Electron" Syn thetic Metals. 41. 2075-2078 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 西尾 豊: "Thermal and Magnetic Properties of Organic Metal (DMe_<1ーX>MeBrーDCNQI)_2Cu" Physica. B173. 300-302 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 梶田 晃示: "Magnetotransport Phenomena of αー(BEDTーTTF)_2I_3 under High Pressure" J.Phys.Sac.JPN.61. 23-26 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 梶田 晃示: "Low Temperature Electronic State of Organicー(Super)conductors:αー,0ーand Kー(BEDTーTTF)_2I_3" JJAP series7 “Mechanism of Super conductivity". 390-394 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 三島 孝博: "Microwave conductivity og αー(BEDTーTTF)_2I_3 around the MetalーNonmetal Traneitin" Salid State Commun.

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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