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A Study of Technique for the Measurement of Total Reactive Nitrogen in the Troposphere

Research Project

Project/Area Number 03452062
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 気象・海洋・陸水学
Research InstitutionNagoya University

Principal Investigator

KONDO Yutaka  Nagoya Univ. Solar Terr. Env. Lab.,Professor, 太陽地球環境研究所, 教授 (20110752)

Co-Investigator(Kenkyū-buntansha) IWATA Akira  Nagoya Univ.Faculty of Engin.,Res.Assoc., 情報処理教育センター, 助手 (40023676)
KOIKE Makoto  Nagoya Univ.Solar Terr.Env.Lab.,Res.Assoc., 太陽地球環境研究所, 助手 (00225343)
IWASAKA Yasunobu  Nagoya Univ.Solar Terr.Env.Lab.,Professor, 太陽地球環境研究所, 教授 (20022709)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1992: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1991: ¥2,500,000 (Direct Cost: ¥2,500,000)
KeywordsReactive nitrogen / Gold converter / Chemiluminescence / CO / Nitric oxide / Water vapor / Ozone / Troposphere / NO_y / 窒素酸化物 / 金コンバ-タ-
Research Abstract

NO_y is measured by converting it to NO catalytically on the surface of a heated gold tube under the addition of CO. Subsequently this NO is detected with an NO detector as described above.
To determine the zero level of NO and NO_y instruments purified gas that doesn't contain NO or NO_y is directed into the reaction chamber instead of the ambient air. It was shown that purified air fulfills therequirements for stable and low zero signal better than purified oxygen and nitrogen.
One important criterion for the performance of the NO_y instrument is it's capability to convert reactive nitrogen on the heated gold tube into NO. For the interpretation of the data obtained during a balloonflight in Northern Sweden in January 92 it was crucial to know to which degree NO_y was converted into NO. Measurements in the laboratory have shown that the conversion efficiency was close to 100%.
Extensive measurements in the laboratory have been carried out to study the possible influence of condenced water in the sample air. In the free troposphere the temperatures are usually far below 0゚C. These low temperatures cause a cooling of the inlet line of the NO_y instrument. The descending aircraft encountered more humid air in the lower troposphere and boundary layer, which then whould condense on the cooled sample line. Considering this effect modifications of the NO_y instrument were made to prevent this interference in future field measurements.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] Y.Iwasaka et al.: "Chemical State of polar stratospheric aerosols," Proc NIPR Symposium. 5. 1-8 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Kondo et al.: "Reactive nitrogen,ozone,and nitrate aerosols observed in the Arctic stratosphere in January 1990," J Geophys Res. 97. 13025-13038 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Kondo et al.: "Reactive nitrogen in the lower stratosphere and troposphere," Kishou-Kennkyuu-note. 176. 111-127 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Kondo et al.: "Ground based NO_2 and O_3 measurements by visible spectrometer at Syowa base(69^0S),Antarctica," Quadren Ozone Symposium. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] M.Hayashi et al.: "Observation of ozone and aersols in the Antarctic ozone hole of 1991 under the Polar Patrol Baloon(PPB)project-preliminary result-," Quadren Ozone Symposium. (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] M.Koike et al.: "Airvraft measurements of NO and NOy at 12km over the pacific ocean," Quadren Ozone Symposium. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] M.Koike: "Depletion of Arctic ozone in the Winter 1990." J Geophys Res. 18. 791-794 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Kondo et al.: "Measurements of nitric oxide and ozone in the troposphere from mid-latitude to equator," Meteorlo.Goephys. 42. 21-29 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Iwasaka et al.: "Seasonal change and chemical state of polar stratospheric aerosols," Univ.Alaska. 720-729 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 近藤 豊: "環境工学ハンドブック(第3章3.2.2気圏の化学)" オーム社, (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Koike,M., Y,Kondo,M.Hayashi,Y.Iwasaka,P.A. Newman, M.Helten, and P.Aimedieu: "Depletion of Arctic ozone in the winter 1990" Geophys.Res.Lett.18. 791-794 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Kondo, Y.,Y.Iwasaka,A.Iwata,T.Ogawa,Y.Sumimura, and Y.Makino: "Measurements of nitric oxide and ozone in the troposphere from mid-latitude to equator." Pap. in Meteorol.Geophys. 42. 21-29 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Kondo,Y.,P.Aimedieu,M.Koike,Y.Iwasaka,P.A.Newman,U.Schmidt, and W.A. Matthews: "Reactive nitrogen,ozone, and nitrate aerosols observed in the arctic stratosphere in January 1990" J.Geophys.Res.97. 13025-13038 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Kondo,Y.,M.Koike,S.Kawakami: "Reactive nitrogen in the lower stratosphere and troposphere" Kishou-kennkyuu-note. 176. 111-127 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Kondo,Y.,W.A.Matthews,P.V.Johnston,M.Hayashi,M.Koike,Y.Iwasaka,A.Shimizu,T.Yamanouchi,and S.Aoki: "Ground based NO_2 and O_3 measurements by visible spectrometer at Syowa base (69^OS),Antarctica" Proc.Quadren.Ozone Symp.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Koike,M.,Kondo,Y.,Y.Makino,Y.Sugimura: "Airvraft measurements of NO and NO_y at 12 km over the Pacific ocean" Proc.Quadren.Ozone Symp.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Kondo,Y.,U.Schmidt,T.Sugita,P.Aimedieu,M.Koike,H.Ziereis,and Y.Iwasaka: "Total reactive nitrogen, N_2O,and ozone in the winter Arctic stratosphere" Geophys.Res.Lett.(1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Iwasaka et al.: "Chemical state of polar stratospheric aerosols," Proc NIPR Symposium. 5. 1-8 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Kondo et al.: "Reactive nitrogen,ozone,and nitrate aerosols observed in the Arctic stratosphere in January 1990," J Geophys Res. 97. 13025-13038 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Kondo et al.: "Reactive nitrogen in the lower stratosphere and troposphere," Kishou-Kennkyuu-note. 176. 111-127 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Kondo et al.: "Ground based NO_2 and O_3 measurements by visible spectrometer at Syowa base(69^oS),Antarctica," Quadren Ozone Symposium. (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Hayashi et al.: "Observation of ozone and aersols in the Antarctic ozone hole of 1991 under the Polar Patrol Baloon(PPB) project -preliminary result-," Quadren Ozone Symposium. (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.koike et al.: "Airvraft measurements of NO and NOy at 12km over the Pacific ocean," Quadren Ozone Symposium. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Koike: "Depletion of Arctic ozone in the winter 1990," J Geophys Res. 18. 791-794 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Kondo et al.: "Measurements of nitric oxide and ozone in the troposphere from mid-latitude to equator," Meteorol Geophys. 42. 21-29 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Iwasaka et al.: "Seasonal change and chemical state of polar stratospheric aerosols," Univ,Alaska. 720-729 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] 近藤 豊: "環境工学ハンドブック(第3章3.2.2気圏の化学)" オーム社, (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Kondo,Y.: "Measurements of nitric oxide and ozone in the troposphere from midーlatitude to equator" Pap.in Meteorol.Geophys.42. 21-89 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Kondo,Y.: "Reactive nitrogen,ozone,and nitrate aerosols observed in the Arctic stratosphere in January 1990" J.Geophys.Res. (1992)

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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