| Project/Area Number |
03453032
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機化学一般
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| Research Institution | Gakushuin University |
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Principal Investigator |
MOCHIDA Kunio Gakushuin University Chemistry Department Professor, 理学部, 教授 (20118772)
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| Co-Investigator(Kenkyū-buntansha) |
岡野 光俊 学習院大学, 理学部, 助手 (30194377)
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| Project Period (FY) |
1991 – 1992
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| Project Status |
Completed (Fiscal Year 1992)
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| Budget Amount *help |
¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 1992: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1991: ¥3,800,000 (Direct Cost: ¥3,800,000)
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| Keywords | Polygermane / Charge-transfer / HOMO / LUMO / Ion radical / Pulse radiolysis / Transient absorption / 電極反応 / 分子軌道法 / 光反応 |
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| Research Abstract |
1. Charge-transfer spectra of permethylated polygermanes-tetra-cyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or chemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.
2. In the pulse radiolytic method two types of polyatomic molecules are used. For the generation of polygermyl anion radicals, tetrahydrofuran (THF) is preferred. The type of molecules used for generation of polygermyl radical cations comprises alkyl halides such as CH_2Cl_2 and CHCl_3.
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