| Project/Area Number |
03453048
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
無機・錯塩・放射化学
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| Research Institution | Nagoya University |
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Principal Investigator |
SANO Mitsuru Nagoya Univ. College of General Edu., 教養部, 助教授 (90144097)
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| Co-Investigator(Kenkyū-buntansha) |
TANAKA Masashi Nagoya Univ. Prof. College of General Educ., 教養部, 教授 (70022639)
MATSUBARA Teruo Nagoya Univ. Prof. College of General Educ., 教養部, 教授 (50023627)
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| Project Period (FY) |
1991 – 1992
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| Project Status |
Completed (Fiscal Year 1992)
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| Budget Amount *help |
¥6,900,000 (Direct Cost: ¥6,900,000)
Fiscal Year 1992: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1991: ¥5,800,000 (Direct Cost: ¥5,800,000)
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| Keywords | Molecular Hysteresis / Molecular Memory / Ruthenium Complexes / 酸化還元 / ルテニウム |
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| Research Abstract |
Thermodynamic and kinetic studies have been done on the "molecular hysteresis". We obtained all the parameters as the energy relations, the isomerization energies and rates, and the interconversion rate between the species. The energy difference is 2.1 KJ/mole and the interconversion rate is 0.12 sec^<-1> between the intermediate species. This rate is rather slow, which results in showing the "molecular hysteresis". Then, we completely made clear the mechanism of the "molecular hysteresis".
Further electrochemical study now are continued on the rutheniumpentammine-sulfoxide, where we investigate stabilities of the Ru(III)-SO and Ru(III)-OS, which can correlate with a steric hindrance of a substituted group of the sulfoxides. Then it is possible to control molecular motions by an applied voltage.
We also considered and discussed to generalize the concept of the "molecular hystereis".
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