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Study on the Production of extra-low-oxygen titanium by Calcium -halide flux method

Research Project

Project/Area Number 03453062
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

ONO Katsutoshi  Kyoto University, Department of Metallurgy, Professor, 工学部, 教授 (10026049)

Co-Investigator(Kenkyū-buntansha) OISHI Toshio  Kyoto University, Department of Metallurgy, Associate Professor, 工学部, 助教授 (80026145)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 1992: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1991: ¥5,100,000 (Direct Cost: ¥5,100,000)
KeywordsTitanium / Extra-Low-Oxygen / Fused Salt Electrolysis / Residual Resistivity Ratio / High parity Titanium / 低酸素濃度チタン / ビッカース硬さ / カルシウムーハライドフラックス / チタン / 脱酸
Research Abstract

Under co-existence of calcium and its oxide, the equiliblium oxygen content in titanium is 500 mass ppmO at 1273K^<1)2)>. The advanced methods were examined to attain the lower oxygen level from the thermodynamic viewpoints. Calcium-halide fluxes may decrease the activity of by-product CaO so efficiently that Ca-CaCl_2 and Ca-BaCl_2 fluxes were experimentally applied for the deoxidation of titanium.
Titanium wires and small pieces containing a few hundreds mass ppm were deoxidized as low as a few tens mass ppm by use of CaCl_2 flux and calcium vapor at 1273K. The oxygen sources to make worse the efficiency of the further purification of titanium were discussed and one of them was suggested to be the oxygen contamination in the flux.
Deoxidation of high purity titanium using an electrochemical technique and characterization of the obtained nearly oxygen-free titanium were carried out. High purity titanium cathode and carbon anode were immersed in molten salt (e.g. CaCl_2) at around 1223 K, and external DC voltages were applied between the electrodes. High purity titanium cathode wires containing 110 mass ppmO were deoxidized to less than 20 ppm. Trace element analysis(e.g. glow discharge mass spectrometry), micro Vickers hardness measurements, and electrical resistivity measurements were carried out to characterize the deoxidized titanium samples. The electrochemical deoxidation produced high purity titanium with a high residual resistivity ratio (rho_<298>/rho_<4.2>=155) and a low micro Vickers hardness value (64kgf/mm^2). Feasibility of deoxidation by using various molten salts such as BaCl_2 and MgCl_2 was also examined, and titanium containing about a thousand mass ppm oxygen were deoxidized to 100 - 300 ppm level by using these salts.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 岡部 徹,中村 正信,植木 達彦,大石 敏雄,小野 勝敏: "カルシウム-ハライトフラックス脱酸法による極低酸素チタンの製造方法" 日本金属学会報. 31. 315-317 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.H.Okabe,T.Oishi,K.Ono: "Preparcetion and Characterigation of extra-low-oxygen titanium" Jourmal of Asloys and Compounds. 184. 43-56 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.H.Okabe,T.Oish,K.Ono: "Deoxidation of Titanium Aluminide by Ca-Al Alloy umder Contnolled Aluminum Actinity" Metallurgital Transactions B. 23. 583-590 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 岡部 徹,鈴木 亮輔,大石 敏雄,小野 勝敏: "カルシウム-ハライドフラックス脱酸法による極低酸素チタンの製造" 鉄と鋼. 77. 93-98 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.H.Okabe,R.O.Suzuki,T.Oishi,K.Ono: "Themodynamic Properties of Dilute Titanium-Oxygen Solid Solution in Beta Phase" Materials Tramsactions,The Jopan tnstitute of Metals. 32. 485-488 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T. H. Okabe, R. O. Suzuki, T. Oishi K. Ono: "Preparation of Extra-Low Oxygen Titanium by Calcium - Halide Flux Deoxidation Method." TETSUTO-HAGANE. vol. 77. 93 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T. H. Okabe, R. O. Suzuki, T. Oishi K, Ono: "Thermodynamic Properties of Dilute Titanium - Oxygen solid solution in Beta phase" Materials Transactions. The Japan Institute of Metals. vol. 32. 485 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T. H. Okabe, M. Nakamura, T. Ueki, T. Oishi, K. Ono: "Production Method of Extra - Low Oxygen Titanium by Calcium - Halide Flux Deoxidaction" Bulletin of the Japan Institute of Metals. vol 31. 315 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T. H. Okabe, T. Oishi, K. Ono: "Preparation and characterization of extra - low - Oxygen titanium" Journal of Alloys and Compounds. vol 184. 43 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T. H. Okabe, T. Oishi, K. Ono: "Deoxidation of Titanium Aluminide by Ca - Al Alloy under Controlled Aluminum Actinity" Metallurgicul Transactions. vol 23 B. 583 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 中村正信,植木達彦,大石敏雄,岡部徹,小野勝敏: "カルシウム-ハライドフラックス脱酸法による極低酸素チタンの製造方法" 日本金属学会報. 31. 315-317 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.H.Okabe,T.Oishi,K.Ono: "Preparation and Characterization of extra low oxygen titanium" Journal of Alloys and Compounds. 184. 43-56 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 岡部 徹: "カルシウムーハライドフラックス脱酸法による極低酸素チタンの製造" 鉄と銅. 77. 93-99 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.H.OKABE: "The rmodynamic Properties of Dilcete Titaniumー6xygen Solid Solution in Beta phase" Materials Transactions,JAPAN Institute of Metals. 32. 485-488 (1991)

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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