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In-Situ Ion Beam Measurement of Electrodeposition Reaction

Research Project

Project/Area Number 03453075
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 無機工業化学・無機材料工学
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

ITO Yasuhiko  Kyoto University, Faculty of Technology, Professor, 工学部, 教授 (20026066)

Co-Investigator(Kenkyū-buntansha) KOUNO Masuchika  Kyoto University, Faculty of Technology, Assistant, 工学部, 教務職員
YOSHIDA Koji  Kyoto University, Faculty of Technology, Assistant, 工学部, 教務職員
MORITANI Kimikazu  Kyoto University, Faculty of Technology, Assistant, 工学部, 教務職員 (50111943)
MORIYAMA Hirotake  Kyoto University, Research Reactor Institute, Professor, 原子炉実験所, 教授 (90127150)
Project Period (FY) 1991 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 1993: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1992: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1991: ¥4,100,000 (Direct Cost: ¥4,100,000)
KeywordsIon Beam / Electro-Deposition / Ni-Co Alloy / In-Situ Measurement / Proton Beam / Radiation Spectrum / プロントビーム / 溶融塩 / イオンビ-ム / NiーCo合金 / InーSitu測定 / プロトンビ-ム / Van de Graaff型加速器
Research Abstract

The feasibility of In-Situ PIXE spectroscopy for electrodeposition reaction analysis has been demonstrated, by showing the experimental results of electrodeposition of copper, iron and nickel-cabalt alloy, as well as those of anodic dissolution of copper and iron, as examples.
This was achieved by the following three major successful results :
(1)Thin film electrode suitable for ion beam irradiation has been prepared by sputtering technique, which is composed of organic membrance, chromium oxide film and copper film.
(2)Electrolytic cell with the above thin film electrode at one side of the walls and with an electolyte circulating system has been constructed, by which In-Situ ion beam irradiation under constant electrolytic condition could be achieved through the experiment.
(3)Differential pumping system in the beam line has developed.

Report

(4 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • 1991 Annual Research Report
  • Research Products

    (7 results)

All Other

All Publications (7 results)

  • [Publications] H.Moriyama, T.Nagae, K.Moritani and Y.Ito: "A Comparison of Production of Irradiation Defects in Lithium Ceramics" Fusion Technology. 1434-1438 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Moriyama, T.Nagae, K.Moritani and Y.Ito: "A Comparison of Production Behavior of Irradiation Defects in Lithium Ceramics" Fusion Technology. 1434-1438 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Moriyama,T.Nagae,K.Moritani,Y.Ito: "A Comparison of Production Behaviour of Irradiation Defects in Lithium Ceramics" Fusion Technology. 1434-1438 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Ito,T.Shimada,and H.Kawamura: "Electrochemical Formation of Thin Carbon Film from Molten Chloride System" Proc.8th International Symposium on Molten Salts. 574-585 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Ito,T.Murata,S.Yoshizawa,and Y.Fukunaka: "An Interferometric Study on Ionic Mass Transfer Rate Associated with Natural Convection along a Silver Plane Vertical Cathode in AgNO_3-NaNO_3-KNO_3" Proc.2nd International Symposium on Electrochemical Processing of Tailored Materials. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 森谷 公一,鎌田 正裕,伊藤 靖彦: "ラジオトレ-サ-法による鉄の電気化学反応に関する研究" 電気化学および工業物理化学. 60. (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 森谷 公一,吉田 紘二,伊藤 靖彦: "NiーCoの合金電析のInーSitu測定" 電気化学および工業物理化学.

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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