| Project/Area Number |
03453109
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
高分子物性・高分子材料（含機械材料）
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| Research Institution | MIE UNIVERSITY |
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Principal Investigator |
KAWAGUCHI Masami Mie University, Faculty of Engineering, Professor, 工学部, 助教授 (30093123)
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| Project Period (FY) |
1991 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1993: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1992: ¥500,000 (Direct Cost: ¥500,000)
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| Keywords | inorganic particles / polymer adsorption / rheology / silica suspensions / shear stress / flow curves / storage modulus / せん断速度 / 動的粘弾性 / レオメ-タ / 無機粒子ー高分子分散系 / レオロジ- / シリカ / 吸着の動力学 / 吸着等温線 / HPMC |
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| Research Abstract |
In this study, rheological properties of silica particles dispersed in aqueous solutions of hydroxypropyl methyl cellulose (HPMC) were investigated in combination of adsorption behavior of HPMC on the silica surfaces.
1.For the suspensions of fumed silica particles dispersed in HPMC solution, rheopexy and overshooting were observed in transient shear stress, showing the existence of aggregated structure in the dispersions.
Evidence of the aggregated structures in the silica suspensions was supported by observations of a bomb at low shear rate in plots of the steady-state shear stress against shear rate (flow curves) as well as a second plateau in the frequency dependence of storage modulus. Moreover, partial desorption of HPMC from the silica particles did not reduce the bomb and the second plateau.
2.For the suspensions of colloidal silicas dispersed in HPMC solution, transient shear stress showed no time dependence. The flow curves only indicated shear thinning. The loss modulus was larger than the storage one in the entire range of frequency except for higher frequency, showing liquid-like viscoelastic behavior. The difference in the rheological behavior of the silica suspensions stemmed from the stability of the silica particles : the fumed silicas were aggregated due to their gelling character inwater, whereas the colloidal silicas were electrostatically stable.
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