| Project/Area Number |
03453122
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
化学工学
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| Research Institution | University of Tokyo |
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Principal Investigator |
SADAKATA Masayoshi Dept.of Chem.Eng.Univ.of Tokyo Professor, 工学部, 教授 (30011175)
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| Co-Investigator(Kenkyū-buntansha) |
NAGAMOTO Hidetoshi Dept.of Chem.Eng.Univ.of Tokyo Assistant professor, 工学部, 助教授 (40111471)
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| Project Period (FY) |
1991 – 1992
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| Project Status |
Completed (Fiscal Year 1992)
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| Budget Amount *help |
¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1992: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1991: ¥3,300,000 (Direct Cost: ¥3,300,000)
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| Keywords | Radical / Discharge / Nitrogen Atom / Plasma / Surface Discharge / マイクロ波 / エジェクター / 窒素ラジカル / 環境 / 酸化窒素 / エジェクタ- |
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| Research Abstract |
In this study, we developed the control method of generating and reducing key radicals at the specified place for the purpose of constructing a new radical reaction engineering. At first, it was examined the behavior of N radicals in the cylindrical surface discharge plasma. On the basis of these experimental results, we made the analysis of the chemical reaction engineering. It was found that the formation rate was balanced with the deactivation rate of N radicals within the residence time of 5 ms. It was also shown that the deactivation of N radicals was the main factor of decreasing formation efficiency of N radicals. From these results, it was realized that the abatement of the deactivation of N radicals on the solid surface was most important for an improvement of radical formation efficiency. Finally, we examined the deactivation rate of N radicals on the cylindrical wall in the laminar flow. As the result, we could make clear the effect of temperature, pressure and material on the deactivation rate of N radicals.
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