Project/Area Number |
03554007
|
Research Category |
Grant-in-Aid for Developmental Scientific Research (B)
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Allocation Type | Single-year Grants |
Research Field |
固体物性
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Research Institution | The University of Tokyo |
Principal Investigator |
HASEGAWA Shuji The University of Tokyo, Faculty of science, Research associate, 理学部, 助手 (00228446)
|
Co-Investigator(Kenkyū-buntansha) |
INO Shozo The University of Tokyo, Faculty of Science Professor, 理学部, 教授 (70005867)
|
Project Period (FY) |
1991 – 1992
|
Project Status |
Completed (Fiscal Year 1992)
|
Budget Amount *help |
¥9,000,000 (Direct Cost: ¥9,000,000)
Fiscal Year 1992: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1991: ¥7,600,000 (Direct Cost: ¥7,600,000)
|
Keywords | X-ray spectroscopy / total reflection angle / crystal spectrometer / surface analysis / RHEED / chemical analysis / surface conductivity / semiconductor surface / EXAFS / 深さ分析 |
Research Abstract |
The aim of this project is to improve a "RHEED-TRAXS" method, our original technique for surface analysis, and to develop a "high resolution TRAXS". The achievements in this project term are as follows; 1. For the high resolution RHEED-TRAXS (reflection-high-energy electron diffraction--total-reflection-angle-X-ray spectroscopy), we developed an X-ray spectrometer which consisted of a crystal spectrometer and a position-sensitive X-ray detector. Combining it with our RHEED-MBE(molecular beam epitaxy) apparatus, we obtained high-resolution X-ray energy spectra which had intensities enough for observations of dynamical processes with short data-aquisition time. 2. Using a flat LiF(200) crystals as a spectrometer, we confirmed an energy resolution of about 13eV at GaK lines (9.2keV), which was about ten times higher than that (150eV) of the previous TRAXS method. Then, we expect to carry out EXAFS (extended X-ray absorption fine structures) with this high energy resolution. 3. With use of a Si surface, of which atomic structures and chemical compositions were well characterized with this new technique, we measured the surface conductance, and found it to be sensitively influenced by the atomic-scale structures of the surface. The changes in atomic arrangements on the surface lead to changes of surface electronic states and space-charge layer, resulting in changes in the macroscopic electrical properties such as surface conductance. This findings will be important not only from the fundamental interests, but also from their devise applications.
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