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The preparation of high-Tc superconducting films by liquid phase epitaxy and their surface analyses

Research Project

Project/Area Number 03650016
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionTottori University

Principal Investigator

TOKUTAKA Heizo  Tottori University, Faculty of Engineering, Professor, 工学部, 教授 (70032266)

Co-Investigator(Kenkyū-buntansha) NISHIMORI Katsumi  Tottori University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (40032271)
KISHIDA Satoru  Tottori University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30112105)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1992: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1991: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsSuperconducting Oxide / Liquid Phase Epitaxy / Crystal Growth / Bi-Sr-Ca-Cu-O / Electronic Device / Surface Composition / Surface Structure / X-ray Photoelectron spectroscopy / BiーSrーCaーCuーO薄膜 / 液相エピタキシ-法 / X線光電子分光
Research Abstract

We prepared the Bi-Sr-Ca-Cu-O (BSCCO) superconducting films by liquid phase epitaxy (LPE).
(1) The systems of BSCCO film growth, which are called a tippinng method and a tipping method were designed and manufactured.
(2) The BSCCO- and (BSCCO + KCl)- based phase diagrams were obtained by using the film growth systems.
(3) The 7K-phase BSCCO films were deposited on the MgO(100) substrates by a dipping method of LPE.
(4) From the results of X-ray photoelectron spectroscopy(XPS), we found that the LPE film did not contain K and Cl, which were the elements of the KCl flux. This may indicate that the preparation of the BSCCO single crystal films is possible.
(5) We compared the XPS results of the LPE film with those of the 80K-phase BSCCO film deposited by rf magnetron sputtering and post-anneled, which had a good superconductivity, surface morphology and crystallization. The results indicated that the LPE film contained more Cu and Ca than the sputtered film.
(6) The 7K-phase BSCCO films were obtained by a tipping method. The film was 7K single-phase and had a good surface morphology. Therefore, the BSCCO film is probable a single crystal film.
We will carry out the BSCCO superconducting film by a tipping method of LPE and obtain BSCCO single crystal film.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] 小山 正一他: "大気中および真空中劈開した80K相Bi系超伝導単結晶のSEM・SAMによる表面分析" 真空. 35. 187-189 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.KISHIDA et al.: "Crystal Growth of the High Quality 80K-Phase Bi-Sr-Ca-Cu-O Bulk Single Crystals" Advances in Superconductivity IV. 477-480 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Koyama et al.: "Surface Analysis of Air- and Vacuum-Cleaved 80K-Phase Bi-Sr-Ca-Cu-O Single Crystal by SEM and SAM" J. Vacuum Soc. Japan. 35-3. 187-189 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Kishida et al.: "Crystal Growth of the High Quality 80K-Phase Bi-Sr-Ca-Cu-O Bulk Single Crystals" Advances in Superconductivity. IV. 477-480 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 小山 正一他: "大気中および真空中劈開した80K相Bi系超伝導単結晶のSEM.SAMによる表面分析" 真空. 35. 187-189 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Kishida et al.: "Crystal Growth of the High Quality 80K-Phase Bi-Sr-Ca-Cu-O Bulk Single Crystals" Advaces in Superconductivity IV. 477-480 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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