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Fundamental Theory of Phosphoric Acid Fuel Cell Engineering

Research Project

Project/Area Number 03650223
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 電力工学
Research InstitutionIbaraki University

Principal Investigator

TSUTSUMI Yasuyuki  Ibaraki Univ., Faculty of Engineering, Prof., 工学部, 教授 (90217349)

Co-Investigator(Kenkyū-buntansha) ONO Kun  Ibaraki Univ., Faculty of Engineering, Lecturer, 工学部, 講師 (80007731)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1992: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1991: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsPhosphoric acid / Fuel cell / Theory / Analysis / リン酸形燃料電池 / 特性解析 / 電圧ー電流特性 / ガス濃度分布 / 温度分布 / 負荷変動
Research Abstract

Purpose of this research is to develop and expand theories for calculating voltage-current distributions, temperature distributions and gas concentration distributions in fuel cells from properties of materials, configurations of cells or a stack, and fuel cells operating conditions. The theory is applicable to optimizing design of the stack, improving operating methods, or preventing corrosive circumstances.
1. In 1991, fundamental performances of the cell elements at various gas conditions such as air/hydrogen, hydrogen/hydrogen, nitrogen/hydrogen, air/ nitrogen, nitrogen/nitrogen, and air/air as gas combination of cathode/anode were measured, which were indispensable to analyzing cell performances at various circumstances such as start-stop, load change, hot-standby, or cold halt.
2. In 1992, transient performance distributions in a large practical scale cell at fast load following conditions were measured. As the delay time of the fuel supply increased, fuel lack area appeared in the cell and local corrosive circulating current were detected as predicted by theories.
An allowable limit theory for load following operation was developed and certified by the experiments.
3. From the late 1991, steam transport mechanism in a cell was investigated.
Expanded precise theory of performance analysis for phosphoric acid fuel cells including steam transport mechanism was developed.
4. Two applied research of performance analysis were carried out for this grant-in-aid period. One was research for detecting method of local short circuit in cells, and the other was research on abnormal phenomena after long term operation.
These results were reported as 6 full papers of the Tras.I.I.E. of Japan.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] 堤、山口、幹、難波: "リン酸燃料電池の各種ガス雰囲気下におけるセル電圧-電流密度特性と炭酸ガス発生現象" 電気学会論文誌B. 111-B. 1013-1022 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、幹、山口、難波: "リン酸形燃料電池におけるセル内局部短絡の検出方法" 電気学会論文誌B. 111-B. 1249-1256 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、山口、難波: "長期運転した燃料電池のリン酸補給前後の諸特性" 電気学会論文誌B. 112-B. 115-121 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、児玉、小野、山口: "リン酸形燃料電池用空気極の発電試験における水分の移動と蓄積" 電気学会論文誌B. 112-B. 641-649 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、山口、難波: "リン酸形燃料電池の負荷応答性" 電気学会論文誌B. 112-B. 1146-1154 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、山口: "リン酸形燃料電池生成水の空気排気系と燃料排気系への分配" 電気学会論文誌B.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, M.Yamaguchi, A.Miki, Y.Nanba: "Cell voltage-current density characteristics and CO_2 evolution phenomena of phosphoric acid fuel cells at various supplied gas conditions" Trans.IEE of Japan,. Vol.111-B,No.9. 1013-1022 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, A.Miki, M.Yamaguchi, Y.Nanba: "Method for detecting local short circuit cells of phosphoric acid fuel cells" Trans.IEE of Japan,. Vol.111-B,No.11. 1250-1256 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, M.Yamaguchi, Y.Nanba: "Characteristics of phosphoric acid fuel cells before and after acid replenishment during endurance testing" Trans.IEE of Japan,. Vol.112-B,No.1. 115-121 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, H.Kodama, K.Ono, M.Yamaguchi: "Water transport and accumulation during air electrode testing for phosphoric acid fuel cells" Trans.IEE of Japan,. Vol.112-B,No.7. 641-649 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, M.Yamaguchi, Y.Nanba: "Load following characteristics of phosphoric acid fuel cells" Trans.IEE of Japan,. Vol.112-B,No.12. 1146-1154 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.Tsutsumi, M.Yamaguchi: "Steam share between exhausted air and exhausted fuel from phosphoric acid fuel cells" Trans.IEE of Japan,.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 堤、山口、難波: "リン酸形燃料電池の負荷応答性" 電気学会論文誌B. 112-B. 1146-1154 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 堤,山口,幹,難波: "リン酸形燃料電池の各種ガス雰囲気下におけるセル電圧ー電流密度特性と炭酸ガス発生現象" 電気学会論文誌B. 111ーB. 1013-1022 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 堤,山口,幹,難波: "リン酸形燃料電池におけるセル内局部短絡の検出方法" 電気学会論文誌B. 111ーB. 1250-1256 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] 堤,山口,難波: "長期運転したリン酸形燃料電池のリン酸補給前後の諸特性" 電気学会論文誌B. 112ーB. 115-121 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] 堤,児玉,小野,山口: "リン酸形燃料電池用空気極の発電試験における水分の移動と畜積" 電気学会論文誌B. 112ーB. (1992)

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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