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Thermodynamics of BaO bearing fluxes

Research Project

Project/Area Number 03650538
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionTHE UNIVERSITY OF TOKYO

Principal Investigator

SUZUKI Kichiya  The University of Tokyo, Faculty of Engineering, Department of Metallurgy Research associate, 工学部, 助手 (00092247)

Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1992: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1991: ¥1,100,000 (Direct Cost: ¥1,100,000)
Keywordssteelmaking / thermodynamics / barium oxide / manganese oxide / activity / dephosphorization / flux / high manganese steel / 溶解度 / 状態図
Research Abstract

The purpose of present study is to investigate the thermodynamic properties of BaO- MnO fluxes.
The activity of MnO in the BaO-MnO flux was measured at 1573 and 1673K, by equilibrating the flux, a Ag-Mn alloy in a nickel crucible, and a gas mixture of CO and CO_2. The activity of BaO in the flux was calculated by using Gibbs-Duhem relationship. The influence of BaF_2 on the thermodynamics of the BaO-MnO system, including the solubility of MnO in the BaO-BaF_2 system, was also investigated at 1573K and the liquid region was established in the BaO-BaF_2-MnO ternary diagram..
Furthermore, the phosphorus and manganese partition ratios between BaO-MnO(BaF_2,CaO) melts and carbon saturated Fe-Mn melts were measured between 1573 and 1673K in a CO atmosphere. The sulfur partition ratio between BaO-MnO flux and silver was also measured at 1573K with the partial pressure of oxygen of 7.03X10^<-5>Pa. The phosphorus partition ratio increases with increasing BaO content of the flux. The manganese partition ratios were approximately constant at 0.64, 0.33 and 0.23 at 1573, 1623 and 1673K, respectively. The phosphate capacity of the BaO-MnO flux is as high as that of BaO-MnO flux and is far larger than those of CaO-bearing fluxes. The sulfide capacity of the BaO-MnO system at 1573K increases with increasing BaO content of the flux. Its value ranges from 10^<-0.4> to 10^<-0.2> and is far larger than any known flux systems.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (7 results)

All Other

All Publications (7 results)

  • [Publications] S.Shin 他: "Thermodynamic Properties of the BaO-MnO Flux System" Metall.Trans. B. 24B4月号. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y.WATANABE 他: "Thermodynamics of Phosphorus and Sulful in the Bao-MnO Flux System Between 1573 and 1673K" Metall Trans. B. 24B4月号. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S. Shim et al.: "Thermodynamic Properties of the BaO-MnO Flux System" Metall. Trans. B. vol. 24B,. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Y. Watanabe et al.: "Thermodynamics of Phosphorus and Sulfur in the BaO-MnO Flux System between 1573 and 1673K" Metall. Trans. B. vol. 24B,. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Shim 他: "Thermodynamic Properties of the BaO-MnO Flux System" Metall.Trans.B. 24B. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Watanabe 他: "Thermodynamics of Phosphorus and Sulfur in the BaO-MnO Flux System between 1573 and 1673K" Metall.Trans.B. 24B. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 渡辺 芳典: "BaOーMnO系フラックス中MnOの活量および同フラックスーFeーMnーCsatd.合金間のりん,マンガンの分配比" 材料とプロセス. 4. 15 (1991)

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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