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Superplasticity and Oxidation Propertiesof Solid Solution Strengthened (beta+gamma')-Two Phase Intermetallic Alloys Having Nano- Structures

Research Project

Project/Area Number 03650585
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 金属材料(含表面処理・腐食防食)
Research InstitutionTHE Nishi-Tokyo University

Principal Investigator

OCHIAI Shouichi  The Nishi-Tokyo University, Department of Science and Engineering, Associate Professor, 理工学部, 助教授 (70169324)

Co-Investigator(Kenkyū-buntansha) KUGITA Tsuyoshi  The Nishi-Tokyo University, Department of Science and Engineering, Assistant, 理工学部, 助手 (80225127)
KOJIMA Yo  Nagaoka University of Technology, Department of Engineering, Professor, 工学部, 教授 (60016368)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1992: ¥500,000 (Direct Cost: ¥500,000)
KeywordsNiAl / Ni_3Al / two-phase / intermetallics / superplasticity / oxidation resistance / nano structure / solid solution hardening / 2相アルミナイド / ラメラ構造 / マルテンサイト / Ms点
Research Abstract

The present work was carried out to clarify the influence of the element addition on the microstructures, mechanical properties and oxidation resistance in the (beta+gamma')-two phase intermetallic alloys with the composition of Ni-33.9mo1%Al-0.1mo%B. On the basis of the ternary phase diagrams, Fe and Co were selected as the candidates for additives for the base alloy. It is recognized that these elements substitute for Ni site of beta or gamma' phase and have the relatively large solubility limit than other elements. Alloys with 2 and 4 mo1% of Fe and Co were prepared using arc-melting method and then subjected to homogenizing heat treatment followed by heat refining treatment. Subsequently, observation of microstructures, compressive and tensile tests at high temperatures were attempted for these specimens. Also, the oxidation tests were conducted at 137** in air. For both Fe and Co added alloys stresses showed the maximum and then decreased gradually, namely high temperature yieldin … More g phenomena were observed. The maximum stresses tend to decrease with the contents of additives. The steady state deformation stress, however, increased with Fe addition, suggesting solid solution hardening. On the other hand, it was found that Co addition has little contribution to solid solution hardening. Apparent activation energies for high temperature deformation were estimated at 224 KJ/mol for base alloy, 251 KJ/mol for 2Fe, 262 KJ/mol for 4Fe alloys and also 236 KJ/mol for 2 and 4 Co alloys. Since these values are considerably less then those for bulk diffusion, it is inferred that grain boundary sliding controlles the high temperature deformation. The strain rate sensitivity exponent, m value, is assessed at 0.4 for the base alloy. While for Fe added alloys m value was about 0.28, Co added alloys showed above 0.35. Fe added alloys fractured by brittle manner with lower elongation than base alloy, when they were tested at 1073K and strain rate of 8.3 chi 10^<-5> s^<-1>. But the Co added alloys exhibited larger elongation compared with the base alloy, indicating that Co addition promotes the superplasticity of the two phase alloy. Whereas Fe addition decreases the oxidation resistance, Co addition seldom change that properties. Less

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] 落合 鐘一: "ボロンを添加した(β+γ′)2相ニッケルアルミナイドの超塑性" 日本金属学会誌. 57. 214-219 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 落合 鐘一: "(NiAl+Ni_3Al)2相合金の組織および機械的性質におよぼすFeおよびCo添加の影響" 日本金属学会誌.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Ochiai, Y.Doi, I.Yamada and Y.Kojima: "Superplasticity in Boron-Doped (beta+gamma')Two-phase Nickel-Aluminide" Jpn.Inst.Met. 57. 214 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] S.Ochiai, Y.Doi, I.Yamada and Y.Kojima: "Effect of Fe and Co Addition On The Microstructures and Mechanical Properties of (NiAl+Ni_3Al) Alloys" J. Jpn.Inst.Met.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 落合 鐘一: "ボロンを添加した(β+γ')2相ニッケルアルミナイドの超塑性" 日本金属学会誌. 57. 214-219 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 落合 鍾一,小島 陽他: "Bを添加した(NiAl+Ni_3Al)2相合金の超塑性" 日本金属学会誌.

    • Related Report
      1991 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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