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Preparation and Application of Quantum Size Ultrafine Silver Iodide Particles

Research Project

Project/Area Number 03650624
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 無機工業化学・無機材料工学
Research InstitutionKyoto Institute of Technology (KIT)

Principal Investigator

TANAKA Toshio  KIT, Dept. of Chem. & Mater. Professor Technol., 工芸学部, 教授 (50026770)

Co-Investigator(Kenkyū-buntansha) IWASAKI Masashi  KIT, Dept. of Chem. & Mater. research Technol. associate, 工芸学部, 助手 (80135631)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1992: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1991: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsSilver Iodide / Preparation of Ultrafine Particles / Quantum Size Effect / Multichannel Spectrometry / Transmission Electron Microscopy / Crystal Growth Restrainer / Holographic Recording Material
Research Abstract

1. Absorption spectra of quantum size silver iodide particles in aqueous media, varying with early-stage particle growth, could be recorded using our multichannel spectrophotometer equipped with an old one-step, two-solution mixing device.
2. With a new two-step, three-solution mixing device, stable ultrafine silver halide particles could be prepared, whose diameter was 20-30 nm for silver iodobromide and about 10 nm for pure silver iodide as determined by transmission electron microscopy.
3. Influences on particle size of varying halide composition, addition of poly(vinyl alcohol) as growth restrainer, different mixing devices and mixing modes, etc. were studied, to find conditions for preparing particles with more appropriate size distributions.
4. Suspensions of ultrafine silver halide particles thus prepared were then chemically sensitized with sulfur and gold compounds, spectrally sensitized with cyanine dyes, and their photographic properties assessed.
5. As an application to ultrahigh-density recording, holographic test plates could be prepared capable of recording more than 5000 per mm red laser beam interference fringes.
6. Spectral sensitization, coating weight, etc. were further optimized to give holographic plates of higher sensitivity and maximum density.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] 田中 俊夫: "ハロゲン化銀微粒子" 日本写真学会誌. 54. 570-579 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Masashi IWASAKI: "Preparation of New Ultrafine-Grain Emulsion for Holography" Journal of Photographic Science. 41. (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 岩崎 仁: "研究室で作成するホログラフィ用超微粒子乳剤" HODIC Circular. 5-11 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Toshio Tanaka: "Fine Particles of Silver Halides (in Japanese)" Nippon Shashin Gakkaishi (J. Soc. Photogr. Sci. Technol. Jpn.). 54. 570-579 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Masashi Iwasaki: "Preparation of New Ultrafine-Grain Emulsion for Holography" Journal of Photographic Science. 41. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] Masashi Iwasaki: "Laboratory-Made Ultrafine-Grain Emulsion for Holography(in Japanese)" HODIC Circular. 1993(1). 5-11 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 田中 俊夫: "ハロゲン化銀微粒子" 日本写真学会誌. 54. 570-579 (1991)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masashi Iwasaki: "Preparation of New Ultrafine-Grain Emulsion for Holography" Journal of Photographic Science. 41. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 岩崎 仁: "研究室で作成するホログラフィ用超微粒子乳剤" HODIC Circular. 5-11 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masashi Iwasaki: "Preparation of New UltrafineーGrain Emulsion for Holography" Journal of Photographic Science. 40. (1992)

    • Related Report
      1991 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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