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FUNCTION CREATION OF ELECTROPOLYMERIZED CONDUCTIVE POLYMERS AND THEIR APPLICATION TO HIGH DENSITY SECONDARY BATTERY

Research Project

Project/Area Number 03650664
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionWASEDA UNIVERSITY

Principal Investigator

OSAKA Tetsuya  WASEDA UNIV. APPLIED CHEM. PROFESSOR, 理工学部, 教授 (20097249)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Sadako  JPN.WOMEN'S UNIV., 家政学部, 教授 (30060619)
Project Period (FY) 1991 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1992: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1991: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsELECTROPOLYMERIZED POLYMER / HIGH DENSITY BATTERY / MIM DEVICE / POLYMER BATTERY / ポリマ-電池
Research Abstract

WASEDA UNIVERSITY
From these research on electropolymerized conductive polymers, we summarize the following results.
(1) For the application to lithium batteries, the cathode materials composed of polyaniline-polypyrrole multilayer and n-type PPy(polypyrrole)/Pss(polystylene sulfonate) composite were de-signed and it worked for 3V level lithium battery. Moreover, the all solid state lithium battery of Li/PEO-LiC104/PPy was tried to evaluate for high energy density battery.
(2) The switching MIM device for LCD driving was proposed to use electropolymerized non-conducting polymer, where MIM is metal(ITO)-insulator(Polymer)-metal(ITO) system. The electropolymetization conditions for making insulator polymers were studied and the polymers were formed until a certain thickness (eg. 0.2 mum) in NaOH, NaHCO or Na CO electrolyte solution. The MIM device showed symmetrical non-linear response and worked for switching device for LCD.
(3) The application of the MIM device shown in (2) term to the micro-pH sensor was studied. The insulator polymer responses to very small solution, especially OH pH sensor when added the voltage near the threshold voltage.

Report

(3 results)
  • 1992 Annual Research Report   Final Research Report Summary
  • 1991 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] T.Osaka: "Electropolymerization of Electroinactive Polypyrrole Film for a Nonlinear MIM Switching Device" Denki Kagaku. 59-12. 1019-1025 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Nakajima: "LCD Driving Characteristics of MIM Diode Using Electropolymerized Polypyrrole Thin Film as an Insulator" Denki Kagaku. 59-12. 1074-1076 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 逢坂 哲彌、門間 聰之: "ポリマー二次電池とその基礎特性評価" 電気化学. 60. 369-375 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka: "Electrochemical Aspects of Advanced Electronic Materials" Electrochimica Acta. 37. 989-995 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka,T.Fukuda,K.Ouchi,T.Momma: "Conduction Mechanism in Indium Tin Oxide/Electroinactive Polypyrrole/Indium Tin Oxide Sandwitch Structures" Thin Solid Films. 215. 200-202 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka,T.Momma,K.Nishimura: "Electroactivity Change of Eletropolymerized Polypyrrole/Polystyrenesulfonate Composite Film in Some Organic Electrolytes" Chem.Lett.1992. 1787-1790 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka: "Electropolymerization of Electroinactive Polypyrrole Film for a Nonlinear MIM Switching Device" Denki Kagaku. Vol.59-12. 1019-1025 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Nakajima, F.Matsushima, T.Fukuda, T.Osaka: "LCD Driving Characteristics of MIM Diode Using Electropolymerized Polypyrrole Thin Film as an Insulator" Denki Kagaku. Vol.59-12. 1074-1076 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka, T.Momma: "Polymer Battery and Experimental Methods for its Fundamental Properties" Denki Kagaku. Vol.60. 369-375 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka: "Electrochemical Aspects of Advanced Electronic Materials" Electrochimica Acta. Vol.37. 989-995 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka, T.Fukuda, K.Ouchi, T.Momma: "Conduction Mechanism in Indium Tin Oxide/Electroinactive Polypyrrole/Indium Tin Oxide Sandwich Structures" Thin Solid Films. Vol.215. 200-202 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] T.Osaka, T.Momma, K.Nishimura: "Electroactivity Change of Electropolymerized Polypyrrole/ Polystyrenesulfonate Composite Film in Some Organic Electrolytes" Chem, Lett.Vol.1992. 1787-1790 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1992 Final Research Report Summary
  • [Publications] 逢坂 哲彌、門間 聰之: "ポリマー二次電池とその基礎特性評価" 電気化学. 60. 369-375 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Osaka: "Electrochemical Aspects of Advanced Electronic Materials" Electrochimica Acta. 37. 989-995 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Osaka,T.Fukuda,K.Ouchi,T.Momma: "Conduction Mechanism in Indium Tin Oxide/Electroinactive Polypyrrole/Indium Tin Oxide Sandwitch Structures" Thin Solid Films. 215. 200-202 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Osaka,T.Momma,K.Nishimura: "Electroactivity Change of Eletropolymerized Polypyrrole/Polystyrenesulfonate Composite Film in Some Organic Electrolytes" Chem,Lett.1992. 1787-1790 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1991-04-01   Modified: 2016-04-21  

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