| Project/Area Number |
03650774
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
化学工学
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| Research Institution | HIROSHIMA UNIVERSITY |
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Principal Investigator |
OKUYAMA Kikuo Hiroshima University,Faculty of Engineering, Professor, 工学部, 教授 (00101197)
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| Project Period (FY) |
1991 – 1992
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| Project Status |
Completed (Fiscal Year 1992)
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| Budget Amount *help |
¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1992: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1991: ¥1,300,000 (Direct Cost: ¥1,300,000)
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| Keywords | Conductor High-Tc Super / Thin Film / Fine Particles / CVD / System Bi-Ca-Sr-Cu-O / Cluster / クラスタ- |
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| Research Abstract |
The formation of superconductive Bi-Ca-Sr-Cu-O thin film and fine particles was carried out using beta-diketonate complexes of Ca, Cu and Sr and organometallic compound of Bi as starting materials in MOCVD method. The vaporized starting materials were introduced into the reaction chamber using Ar gas as a carrier gas. O_2 gas acting as an oxidizing agent was introduced to the reaction chamber at the same time through a different path. The thin films formed and the particles deposited on the reactor wall were observed using an electron microscope under various supplied concentrations of vapor, reaction temperatures and operating pressure inside the reactor. It has been found that the generation of fine particles is enhanced at higher concentration of vapor, higher reaction temperature and higher pressure, but the formation of thin films is more enhanced under lower pressure. The observed trends agreed qualitatively with the simulation results obtained by numerically solving the aerosol dynamic equation where the particle formation was evaluated by a simplified reaction and coagulation model.
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