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二酸化炭素の活性化と化学的固定・変換

Research Project

Project/Area Number 04241106
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionOsaka University

Principal Investigator

村井 真二  大阪大学, 工学部, 教授 (00029050)

Co-Investigator(Kenkyū-buntansha) 堀 善夫  千葉大学, 工学部, 教授 (20114324)
坂田 忠良  東京工業大学, 大学院・総合理工学研究科, 教授 (40013510)
井上 祥雄  東北大学, 工学部, 教授 (50005518)
井上 祥平  東京理科大学, 工学部, 教授 (20010762)
池田 章一郎  名古屋工業大学, 工学部, 助教授 (90024364)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥82,900,000 (Direct Cost: ¥82,900,000)
Fiscal Year 1994: ¥36,700,000 (Direct Cost: ¥36,700,000)
Fiscal Year 1993: ¥23,500,000 (Direct Cost: ¥23,500,000)
Fiscal Year 1992: ¥22,700,000 (Direct Cost: ¥22,700,000)
Keywords二酸化炭素 / 金属錯体 / 電極 / 一酸化炭素 / 還元
Research Abstract

本研究は、二酸化炭素の活性化と化学的固定・変換の新しい方法の開発を課題するもので2年間の成果を発展させつつある。金属錯体を反応場として用いた研究ではアルミニウムポルフィリン錯体を触媒として、二酸化炭素から有用物質の合成に成功し(井上祥平)、また、パラジウム金属錯体を用いる、二酸化炭素からの有用物質合成(井上祥雄)にも成功した。酸化亜鉛-酸化銅系燒結体電極が二酸化炭素のエタノールへの電解還元に有効なこと(池田)、ニッケル電極を用いた高圧二酸化炭素の還元による一酸化炭素への変換の効率化(坂田)、ニッケル電極上での二酸化炭素の還元中間体として吸着一酸化炭素の生成(堀)など電解還元の研究が更に発展した。このように前年度に引き続き、二酸化炭素の化学的固定・変換に関し種々のアプローチを行い、基礎的な重要知見をさらに集積しつつある。

Report

(3 results)
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] 井上 祥雄: "Direct Synthesis of Polycarbonates from CO_2,Diols,and Dihalides" Macronol.Rapid Conmun. 15. 133-137 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 坂田 忠良: "Electrochemical Reduction of CO_2 on a Cu Electrode under High Pressure-Factors that Determine the Product Selectivity-" J.Electrochem.Soc.141. 2100-2106 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐藤 史衛: "Carbon Dioxide Fixation by Cp_2(η^3-allyl)Ti Complexes Generated from various Dienes." Inorg.Chem.Acta. 222. 145-153 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 堀 善夫: "Electrocatalytic Process of CO Selectioity in Electrochemical Reduction of CO_2 at Metal Electrodes in Agueous Media." Electrochim.Acta. 39. 1833-1839 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 米山 宏: "Electrochemical Conversion of Carbon Dioxide to Methanol with Assistance of Formate Dehydrogenase and Methanol Dehydrogenase as Biocatalysts." J.Am.Chem.Soc.116. 5437-5443 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 村井真二: "Rhodium-Catalyzed Ring-Opening Silylformylation of Epoxides Leading to β-Siloxy Aldehydes" The Journal of Organic Chemistry. 58(16). 4187-4188 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 村井真二: "Ruthenium-Catalyzed Reaction of 1,6-Diynes with Hydrosilanes and Carbon Monoxide:A Third Way of Incorporating CO" The Journal of The American Chemical Society. 115(24). 11614-11615 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 井上祥平: "Catalysts for a Rapid Transcyanation from Acetone Cyanohydrin to Aldehydes and Ketones" Chemistry Letters. 375-378 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 井上祥平: "Ring Opening of Epoxides with Acetone Cyanohydrin Catalyzed by Lanthanoid(III)Alkoxides" Chemistry Letters. 975-978 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 井上祥雄: "二酸化炭素,アルコール,ハロゲン化アルキルから非対称炭酸エステルの直接合成" 日本化学会誌. 985-987 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 井上祥雄: "カチオン性パラジウム(II)錯体触媒による中性条件下でのRittcr反応" 日本化学会誌. 1100-1101 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 村井 真二: "Regioselective Incorporation of CO into Enamines by Reaction with a Rhodium-Catalyzed Hydrosilane and CO." The Journal of Organic Chemistry. 57. 2-4 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 村井 真二: "Rh-Catalyzed Reaction of N,N-Acetals with a Hydrosilane and Carbon Monoxide" Organometallics. 11. 3494-3495 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 村井 真二: "Converison of Alkenes to Enol Silyl Ethers of Acylsilanes by Iridium-Catalyzed Reaction with a Hydrosilane and Carbon Monoxide" Journal of American Chrmical Society. 14. 9710-9711 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 井上 祥平: "二酸化炭素の化学的固定の現状と生化学への期待" 生化学. 64. 624 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masashi Komatsu,Takuzo Aida,and Shohei Inoue: "Novel visible-Light-Driven Catalytic CO_2 Fixation.Synthesis of Malonic Acid Deribatives from CO2,α,β-Unsaturated Ester or Nitril,and Diethylzind Catalyzed by Aluminum Porphyrins" Journal of American Chemical Society. 113. 8492-8498 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masashi Komatsu,Takuzo Aida,and Shohei Inoue: "Novel visible-Light-Driven Catalytic CO_2 Fixation.Synthesis of Malonic Acid Deribatives from CO2,α,β-Unsaturated Ester or Nitril,and Diethylzind Catalyzed by Aluminum Porphyrins" Journal of American Chemical Society. 113. 8492-8498 (1992)井上 祥雄:

    • Related Report
      1992 Annual Research Report
  • [Publications] 池田 章一郎,伊藤 要: "人工光合成モデルとしの二酸化炭素の光電気化学還元" 太陽エネルギー (Journal of JSES). 19(1). 26-31 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 坂田 忠良: "半導体表面での電子移動" 日本物理学会誌. 47. 196-203 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Tsuneto,A.Kudo,N.Saito and T.Salata: "Hydrogenation of solid state carbonates" Chemistry Letters. 831-834 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Manivannan,K.Hashimoto,T.Sakata and A.Fujishima: "Time resolved electroluminescence measurements at an n-SiC/electrolyte interface by transient study" J.Phys.Chem.96. 7399-7403 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Kudo and T.Sakata: "Photocatalytic decomposition of N_2O at room temperature" Chemistry Letters. 2381-2384 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Kudo and T.Sakata: "Photocatalytic decomposition of N_2O at room temperature" Chemistry Letters. 2381-2384 (1992)堀 善夫:

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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