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分子設計の基礎と展開

Research Project

Project/Area Number 04299106
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionOsaka University

Principal Investigator

村田 一郎  大阪大学, 名誉教授 (90028077)

Co-Investigator(Kenkyū-buntansha) 安藤 亘  筑波大学, 化学系, 教授 (30008429)
竹内 賢一  京都大学, 工学部, 教授 (50026358)
新海 征治  九州大学, 工学部, 教授 (20038045)
大木 道則  岡山理科大学, 理学部, 教授 (40011407)
今村 詮  広島大学, 理学部, 教授 (70076991)
Project Period (FY) 1989 – 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1992: ¥2,800,000 (Direct Cost: ¥2,800,000)
Keywords分子設計理論 / 分子の動的性質 / 分子認識場 / 不安定分子種 / 電子授受 / ヘテロ原子
Research Abstract

本研究は平成元年度より三年度迄の三年間に亘って行った重点領域研究「分子設計の基礎と展開」の成果取纏めのため行われたものである。
研究成果取纏めは次の三点につき行った。
1.最終公開シンポジウムの開催:重点領域研究実施の三年間は各年度毎に2回づつの公開シンポジウムを開催し、全研究班員の成果発表とそれに関する討論を行ってきたが、今年度は最終の成果発表会として、各研究班より班長および班員1名を選び、総計12名による発表を下記のように行った、月日:平成4年11月30日(月)、12月1日(火)場所:東京都千代田区神田駿河台1-5、日本化学会館6階ホール。このシンポジウムには班員49名、評価班より長倉三郎教授、福井謙一教授の2名、また一般参加として大学関係20名、企業関係13名、計84名が出席し、2日間極めて活発な発表と討論が行われた。なお、評価班福井謙一教授より、3年間に亘る研究全般に亘って講評を頂いた。
2.研究成果報告書の作成:これ迄各年度毎の全班員の研究成果は、和文2頁、英文1頁で毎年作成したが、今年度は3年間の成果を英文6〜8頁に纏め、“Fundamentals and Evolution of Molecular Design"としてB5版456頁の報告書を作成し、班員並びに関係方面に配布した。
3.論文リストの作成:重点領域研究補助金で達成された班員の研究論文の全リストを作り、前記成果報告書末尾に印刷添付した。班員相互の共同研究論文は重複してリストアップされている為、実数は若干少くなるが、A01(131編)、A02(216編)、AO3(165編),AO4(136編)、AO5(126編)、AO6(108編)の計882編が、内外の一流学術雑誌に発表された。

Report

(1 results)
  • 1992 Annual Research Report

Research Products

(39 results)

All Other

All Publications (39 results)

  • [Publications] Y.Sugihara: "1-phenylthieno[3,4-d]borepine:A New 10π Electron System Isoelectronic with Azulene" J.Am.Chem.Soc.114. 1479-1481 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Sugihara: "[14π]Electrocyclization Followed by Preferential-[1,9]hydrogen Migration in the Thermolysis of 1-Formy1-4-[2,4,6-cycloheptatrienyl)(phenyl-sulfinyl)methyl]azulene." Bull.Chem.Soc.Jpn.65. 3198-3199 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Nakazawa: "Acid-catalyzed Rearrangement of 2-Substituted and 2,4-Disubstituted 8H-3-oxaheptalen-8-ones to 1-AcyL-6-hydroxyazulenes." Tetrahedron Lett.33-43. 6487-6490 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Sugihara: "A.Novel Rearrangement in the Sterically Congested(2,4,6-Cycloheptatrienyl)(phenyl-sulfinyl)methyl Group." Chem.Lett.2393-2396 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Aoki,and A.Imamura: "A simple treatment to design NBMO degenerate systems in alternant and non-alternant hydrocarbons," Theoretica Chimica Acta,. 84. 155-180 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Hayashi,and A.Imamura: "A study of the polarization reversal in poly(vinyl fluoride)using molecul ar orbtial calculations" J.Polym.Sci.Part B Polym.Phys.,. 30. 769-773 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Aoki,and A.Imamura: "Local density of states of aperiodic polymers using the localized orbital from ab initio elongation method" J.Chem.Phys.,. 97. 8432-8440 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Maekawa,and A.Imamura: "Statioanry conditions of the electronic structure against the extension of molecular systems and their application to the elongation method" J.Chem.Phys.,.

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Toyota,M.Oki: "Structure of Intramolecular Boron-Amine Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Structure and ..." Bull.Chem.Soc.Jpn.65. 1832-1840 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Toyota,M.Oki: "Secondary Isotope Effect on Kinetic Basicity of Amine Ligands in Boron-Amine Complexes and Ammonium Salts" Bull.Chem.Soc.Jpn.65. 2215-2220 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Toyota,M.Oki: "Structure of and Tetrahedral Character of the Boron Atom in 9-[2-(1-Ethylthiopentyl)phenyl]-9-borabicyclo[3.3.1]nonane" Bull.Chem.Soc.Jpn.65. 2857-2859 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Oki,Y.Taguchi,S.Toyota: "Syntheses of and Restricted C- 3-C 2 Bond Rotation in Triptycenes That Carry^^<sp> C^^<sp>__4-Olefinic Substituent at 9-Position" Bull.Chem.Soc.Jpn.65. 2616-2623 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Toyota,H.Yamane,M.Oki: "Absolute Stereochemistry of Dimethyl 9-(1,1-Dimethyl-2-phenylethyl)-9,10-dihydro-9,10-etheno-anthracene-11,12-dicarboxylate Rotamers" Bull.Chem.Soc.Jpn.66. 212-217 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Nagasaki: "Novel Conformational Isomerism of Water-soluble Calix[4]arenes" Tetrahedron. 48. 797-804 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Nagasaki: "Solvent Extraction of Transition Metal Cations by Calixarene-based Cyclic Ligands" Bull.Chem.Soc.Jpn.65. 471-475 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Ikeda: "Calixarne-TCNE Complexes.On the Selective Complexation with Calix[4]arene Conformers" Tetrahedron. 48. 1059-1070 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Shinkai: "Syntheses and Ion Selectivity of Conformational Isomers Derived from Calix[4]arene" J.Org.Chem.57. 1516-1523 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Iki: "Synthesis and Spectral Characterization of Tricarbonylchromium Complexes of Calix[4]arene Conformers" J.Chem.Soc.,Perkin Trans.1. 669-671 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Araki: "Acid Dissocition and Activation Parameters for Ring Inversion of Diaminocalix[4]arene" Chem.Lett.539-542 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Fujimoto: "Synthesis and Crystallographic Studies of a Calix[4]arene with a 1,3-Alternate Conformation" J.Chem.Soc.,Perkin Trans.2. 643-648 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Nagasaki: "¨Crowned Arborols¨" J.Chem.Soc.,Chem.Commun.608-610 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Araki: "On the Origin of the Distal vs.Proximal Regioselectivity in Di-O-alkylation of Calix[4]arene" Chem.Lett.1095-1098 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Shinkai: "Selective Ion Permeation across Membranes Prepared from Steroidal Crown Ethers" Israel J.Chem.32. 121-126 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Iwamoto: "Fluorogenic Calix[4]arene" J.Chem.Soc.,Perkin Trans.1. 1885-1887 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Ikeda: "Conformational Analysis of Calix[4]arenes with Chiral Substituents by Using Circular Dichroism" J.Phys.Org.Chem.5. 699-710 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Kijima: "Intercalation of a Trimethylammoniomethylated Calix[4]arene by Cu(II)-Montmorillonite" Bull.Chem.Soc.Jpn.65. 2510-2513 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Kameyama: "A New Electron Mediator:Reduction by Na_2S_2O_4 in Organic Media of a Novel Viologen Functionalized with Crown Ethers" J.Chem.Soc.,Chem.Commun.1058-1060 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Iwamoto: "Synthesis and Ion Selectivity of All Possible Conformational Isomers of Tetraki(ethoxy-carbonylmethoxy)calix[4]arene" J.Ora.Chem.57. 7066-7073 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Miyabo,T.Kitagawa,K.Takeuchi: "Significance of Steric Effect in the Heterolysis of Carbon-Carbon Bond in Ionically Dissocitive Hydrocarbons." Chem.Lett.,. 679-682 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Miyabo,K.Takeuchi,K.Komatsu,and T.Kitagawa: "Small Difference in Cation Stability in Controlling the Formation of Hydrocarbon Salt or Covalent Hydrocarbon." Chme.Lett.,. 683-686 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Kitagawa,K.Takeuch,K.Komatsu,and T.Kinoshita: "Synthesis and Properties of Hydrocarbon Salts and Ionically Dissociative Hydrocabons." J.Synth.Org.Chem.,Jpn.,. 50. 746-757 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Miyabo,T.Kitagawa and K.Takeuchi: "Steric and Solvation Effects in the Heterolysis of Carbon-Carbon Sigma Bond in Hydrocarbons Giving Stable Carbocations and Carbanions." J.Org.Chem.,.

    • Related Report
      1992 Annual Research Report
  • [Publications] W.Ando,T.Kadowaki,Y.Kabe,M.Ishil: "A Germanium Sesquisulfide,(tBuGe)_4S_6 without Adamantane structure" Angew.Chem.Int.Ed.Engl.31. 59-61 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Yoshda,Y.Takahara,T.Erata,W.Ando: "Structure and Bonding Nature of 2,4,5-Trisila-1,3-disilabicyclo(1.1.1.1)pentane" J.Am.Chem.Soc.114. 1098-1100 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] W.Ando,F.Hojo,S.Sekigawa,N.Nakayama,T.Shimizu: "First Isolation of Six membered Cyclic Acetylene:Synthesis and Reaction of Tetrasilahexynes" Organometallics. 11. 1009-1011 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 榊原 章人,安藤 亘: "ヘテロ原子(N,P,S)を含む環状ケイ素化合物の合成とその展開" 有機合成化学. 29. 899 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Shinkai: "Crown Ethers and Analogous Compounds" Elsevier Press, 45 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 新海 征治: "生物有機化学" 日本放送出版協会, 14 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 新海 征治: "分離・輸送機能材料" 共立出版, 48 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-03-31   Modified: 2016-04-21  

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