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Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups

Research Project

Project/Area Number 04303002
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 有機化学一般
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

SUZUKI Hitomi  Kyoto Univ. Dept. Chem. Professor, 理学部, 教授 (50025342)

Co-Investigator(Kenkyū-buntansha) KIRA Mitsuo  Tohoku Univ. Dept. Chem. Associate Professor, 理学部, 助教授 (40004452)
OKU Akira  Kyoto Inst. Tech. Dept. Chem. Professor, 工芸学部, 教授 (50027885)
TAKEUCHI Kenichi  Kyoto Univ. Dept. Chem. Professor, 工学部, 教授 (50026358)
OKUYAMA Tadashi  Osaka Univ. Dept. Chem., Associate Professor, 基礎工学部, 助教授 (40029484)
TOMIOKA Hideo  Mie Univ. Dept. Chem., Professor, 工学部, 教授 (20024599)
西田 進也  北海道大学, 理学部, 教授 (40029400)
香月 つとむ  九州大学, 理学部, 教授 (40037271)
稲津 孝彦  九州大学, 理学部, 教授 (60037207)
広田 穣  横浜国立大学, 工学部, 教授 (00017881)
安藤 亘  筑波大学, 化学系, 教授 (30008429)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥24,400,000 (Direct Cost: ¥24,400,000)
Fiscal Year 1993: ¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 1992: ¥14,500,000 (Direct Cost: ¥14,500,000)
KeywordsSubstituent effect / Heteroatom Compounds / Stereochemistry / Asymmetric Synthesis / Kinetics / Photochemical reaction / Electron transfer / Reaction intermediate
Research Abstract

Specificity in organic reactions, one of the most important research subjects of current organic chemistry, has been investigated systematically under the name of the title joint project by twenty-eight chemists of a wide variety of speciality backgrounds. The selected experts were devided into three project teams of comparative size ; the first team was mainly concerned with the problems on the enhancement of specificity and reactivity by organic functional groups ; the second one was devoted to the analysis of the relationship between reactivity and electronic requirements, and the last one dealt with the high specificity arising from some functionalized reactive intermediate. The project has brought a great success, more than 460 original papers being published in prestigeous international journals during the given period of the joint studies. Major part of the fruitful results has been presented by the members of each team at two open meetings held in Kyoto on Dec. 4-5, 1993 and Dec. 17-18, 1994.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N,N-Dimethylamino Group.X-Ray Structure Analysis,Asymmetric Induction at Bismuth Centre and Dynamic Behaviour in Solution" J.Chem.Soc.,Perkin Trans.1. 1169-1175 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Hideo Tomioka: "Formation of Heptafulvene in Reaction of [(Methoxycarbonyl)]phenylcarbene in the Gas Phases" J.Am.Chem.Soc.58. 4196-4197 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Okuyama: "Dual Reactivity of Methoxymethyl Benzenesulfinate in Nucleophilic Substitution" Bull.Chem.Soc.Jpn.65. 2672-2683 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Ken'ichi Takeuchi: "Quantitative Treatment of Rate Enhancement due to F-Strain in the Solvolysis of(Z)-2-Ethylidene-1-adamantyl Mesylate and Halides" Tetrahedron Lett.34. 3335-3338 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Akira Oku: "Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles.A Three-component Coupling Reaction" Acta Chem.Scand.47. 391-397 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Mitsuo Kira: "p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates" Chem.Lett.1859-1862 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N, N-Dimethylamino Group. X-Ray Structure Analysis, Asymmetric Induction at Bismuth Center and Dynamic Behavior in Solution" J.Chem. Soc. Perkin Trans.1. 1169-1175 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Hideo Tomioka: "Formation of Heptafulvene in Reaction of (Methoxycarbonyl) phenyl carbene in the Gas Phases" J.Am. Chem. Soc.58. 4196-4197 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Okuyama: "Dual Reactivity of Methoxymethyl Benzenesulfinate in Nucliophilic Substituion" Bull. Chem. Soc. Jpn. 65. 2672-2783 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kenichi Takeuchi: "Quantitative Treatment of Rate Enhancement due to F-Strain in the Solbolysis of (z) -2-Ethylidene-1-adamantyl Mesylate and Halides" Tetrahedron. 34. 3335-3338 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Akira Oku: "Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles. A Three-component Coupling Reaction" Acta Chem. Scand. 47. 391-397 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Mitso Kira: "p-and m-phenylenebis (tri-fluoro (phenyl) silicates) and related Monosilicates" Chem. Lett.1859-1862 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N,N-Dimethylamino Group.X-Ray Structure Analysis,Asymmetric Induction at Bismuth Centre and Dynamic Behaviour in Solution" J.Chem.Soc.,Perkin Trans.1. 1169-1175 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Hideo Tomioka: "Formation of Heptafulvene in Reaction of[(Methoxycarbonyl)]phenylcarbene in the Gas Phases" J.Am.Chem.Soc.58. 4196-4197 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Tadashi Okuyama: "Dual Reactivity of Methoxymethyl Benzenesulfinate in Nucleophilic Substitution" Bull.Chem.Soc.Jpn.65. 2672-2683 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Ken'ichi Takeuchi: "Quantitative Treatment of Rate Enhancement due to F-Strain in the Solvolysis of(Z)-2-Ethylidene-1-adamantyl Mesylate and Halides" Tetrahedron Lett.34. 3335-3338 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Akira Oku: "Reaction of Carbenes with Cyclic Ethers in the Presence of Nucleophiles.A Three-component Coupling Reaction" Acta Chem.Scand.47. 391-397 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Mitsuo Kira: "p- and m-Phenylenebis[trifluoro(phenyl)silicates]and Related Monosilicates" Chem.Lett.1859-1862 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Suzuku and T.Murafuji: "A New General Method for the Synthesis of Chiral Triarylbismuthines based on the Intramolecular Coordination by a Sulfonyl Group" J. Chem. Soc., Commun.1143-1144 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Otaku,Y.Kabe and W. Ando: "Synthesis of a Thiastannirane by the Reaction of a Stannylene with a Thiocarbonyl Compound" organometalics. 12. 4-5 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Komatsuzaki,I.Arai,K.Sakakubara and M.Hirata: "A New steric substituent constant s. Characteristic feature and Comparison with some other steric contants" Tetrahedron. 48. 1539-1556 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Takemura,K.Yoshimura,I.U.Khan,T.Shinmyozu and T.Inazu: "The First Synthesis and Properties of hexahomotrazacalix[3]arene" Tetrahedron lett.33. 5775-5778 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Ito,Y.Kimura and T. katsuki: "Enantioselective Addition of Diethylzinc to Aldehydes in the presence of Chiral Titanium Reagent Modified with N-Sulfonylated Amino Alcohol" Synlett. 573-574 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Nishida,N.Asanuma,M.Murakami,T.TsujiI and T.Imai: "Reaction of Spiro[2.4]hept-4-ene Derivatives with Tetracyanoethylene.Extensive Rearrangenents Involving Aza-Cope process" J. Org. Chem.57. 4658-4663 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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