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Study of development of selective determination and separation method for trace element

Research Project

Project/Area Number 04303004
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionHokkaido University

Principal Investigator

TAGA Mitsuhiko  Hokkaido University, Dep.of Chem., Professor, 理学部, 名誉教授 (90000778)

Co-Investigator(Kenkyū-buntansha) YOSHIMURA Kazuhisa  Kyushu University, College of General Education, Professor, 教養部, 教授 (80112291)
KUMAMARU Takahiro  Hiroshima University, Faculty of Sci., Professor, 理学部, 教授 (50033816)
MOTOMIZU Shoji  Okayama University, Faculty of Sci., Professor, 理学部, 教授 (50032826)
OGUMA Koichi  Chiba University, Faculty of Engineering, Professor, 工学部, 教授 (60009529)
NAKAMURA Hroshi  Hokkaido University, Graduate School of Environ.Earth Sci., Professor, 大学院・地球環境科学研究科, 教授 (00117194)
赤岩 英夫  群馬大学, 工学部, 教授 (60008414)
寺田 喜久雄  金沢大学, 理学部, 教授 (50019460)
松本 和子  早稲田大学, 理工学部, 教授 (60111457)
河嶌 拓治  筑波大学, 化学系, 教授 (50041760)
鈴木 信男  東北大学, 理学部, 教授 (10006025)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥11,700,000 (Direct Cost: ¥11,700,000)
Fiscal Year 1993: ¥5,700,000 (Direct Cost: ¥5,700,000)
Fiscal Year 1992: ¥6,000,000 (Direct Cost: ¥6,000,000)
KeywordsComplexing ability / Adduct formation / Synthetic reference material / Humic acid / Metal furnace / Fluorescent reagent / Flow injection analysis / Ion-interaction chromatography / 錯形成能力 / コバルト / 接触作用 / チタニア / ヌクレオチド / 開環型クラウンエーテル / 蛍光試薬 / Fe(II)-フェロジン錯体 / Co(II)-ニトロソ-R錯体 / キレート抽出法 / HSABパラメーター / 協同効果抽出系 / マトリックス修飾剤 / 炭素炉原子吸光法
Research Abstract

The new determination methods having high sensitivity and selectivity were studied in this project for the speciation and charactarization of trace elements in environmental and biological samples and new materials.
1. The development of speciation methods for trace elements in ebvironmental and biological samples. The complexing ability of humic acid was evaluated exactly by anodic stripping voltammetry using the effect of sodium dodecyl sulfate(SDS). The pre-concentration methods of trace elements in polystylene film or PCTFE resin were developed and applied to analyzes of seawater and river water. A synthetic multi-element reference materials with a pseudo-biological composition was prepared and the usefulness as a atandard material was demonatrated.
2. The high selective separation and determination methods based on new viewpoint. The excellent separation of metal and rare earth metal ions was achieved by introducing adduct formation and masking effect to mobile phase system of HPLC … More and ion-interaction chromatography. The possibility of titania microparticles as a promising matrix for HPLC was investigated.
3. The development of analytical reagent having new function. A new fluorescent reagent which has two anthracene moieties at both terminals on linear polyether was synthesized. The fluorescent spectrum of the reagent changed from that of monomer to dimer at the complexation with metal ions. From extraction behavior of beta-diketone, the chelate ring rigidity was found to be a parameter governing the ion size recognition. Novel cationic triphenylmethane dyes were synthesized and their characteristics were investigated to evaluate them as an ion association reagent.
4. On-line system for the rapid and sensitive determination and separation. Flow injection methods by catalysis of oxidative coupling reaction, ion-exchange phase absorptiometry and ICP method using metal furnace vaporization via in situ solid phase reaction were developed for the determination of trace elements in environmental samples. Less

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (66 results)

All Other

All Publications (66 results)

  • [Publications] M.Fukushima: "Effect of sodium dodecyl sulfate on measurement of labile copper(II)species in the presence of humuc acid by anodic stripping voltammetry" Anal.Chim.Acta. 270. 153-159 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fukushima: "Interaction between humic acids and copper(II)oxinate" Anal.Chim.Acta. (in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Kakizawa: "Syntheses and complexing behavior of new fluorescent reagents for alkaline earth metal ions" Chem.Lett.1671-1674 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Nakamura: "Time resolved electron spin resonance spectra of linked radical pairs on laser excitation of zinc tetraphenylporphyrin-viologen systems" J.Phys.Chem.97. 534-536 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Iwata: "Preparation of thin support film for PIXE and its application to trace analysis of biological materials" Intern.J.PIXE. 2. 381 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Nakamura: "Synergistic extraction of tervalent lanthanoids with 2-thenoyltrifluoro-acetone and ethylenediamine as a neutral bidentate ligand," Anal.Chim.Acta. 270. 95 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Yasud: "Solvent Extraction of Divalent Metals as Dihydrobis(1-pyrazolyl)borate Chelates" Bull.Chem.Soc. 65. 781 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ogura: "Voltammetric Study on the Transfer of Alkali and Alkaline Earth Metal Ions at the Aqueous/Organic Interface Facilitated by Phosphine Oxides" Bull.Chem.Soc.Jpn.,. 66. 1971 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Motomizu: "Spectrophotometric determination of cationic and anionic surfactants with anionic dyes in the presence of nonionic surfactants,Part I:general aspect" Microchim.Acta. 106. 57 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Hagiwara: "Equilibrium and kinetic studies on the formation of triphenylmethanols from triphenylmethane dyes" Bull.Chem.Soc.Jpn.,. 67(in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] E.Iwamoto: "Graphite furnace atomic absorption spectrometry with graphite cloth ribbon and its application to determination of arsenic in mussel" Anal.Sci.,. 8. 389 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Fujiwara: "Automated method for the selective determination of gold by on-line solvent extraction and reversed micellar mediated luminol chemiluminescence detection" Microchem.J.,. (in press.).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] U.Hase: "Determination of trace amounts of iron in highly purified water by ion-exchanger phase absorptiometry combined with flow analysis" Talanta. 39. 1019 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] U.Hase: "Determination of silicic acid in highly purified water by improved gel-phase absorptiometry" Anal.Sci.,. 9. 111 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Nakano: "Flow injection determination of chromium(III)by pyrogallol chemiluminescence" Talanta. 40. 75-80 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Teshima: "Effect of ligands on the iron(III)/iron(II)system and its novel application to simultaneous flow injection determination of vanadium(IV)and vanadium(V)" Anal.Sci.,. 10. 207-212 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Tsunoda: "Characteristics of Potasium Ion Doped Slab Optical Waveguide as Absorption Cell and its Application to Spectrophotometric Determination of Methylene Blue" Anal.Chim.Acta. 276. 133-139 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Kawamoto: "Labitity of Soluble Copper(II)Complex in River Waters in the Uban Area" Bull.Chem.Soc.Jpn.,. 66. 2104-2105 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Kuroda: "Ion interaction chromatography of nitrilotriacetatocomplexes of the rare earth elements with post-column reaction detection" Talanta. 40. 237 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Kuroda: "Selective determination of yttrium in geological materials by ion-interaction chromatography" Mikrochim.Acta. 110. 47 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Ikeguchi: "Flow Injection-Acid Hydrolysis Technique for Determination of Organic Phosphates" Anal.Sci.,. 9. 397 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Murayama: "Preparation and Evaluation of Octadecyl Titania as Column Packing Material for High Performance Liquid Chromatography" Microchem.J.,. in press.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Katsura: "Enhancement effect of palladium and Albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.,. 8. 97 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Matsumoto: "Palladium as a matrix modifier in graphite-furnace atomic absorption spectrometry of group IIIB-VIB elements" Anal.Sci.,. 9. 447 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Billah: "Preconcentration and determination of a trace amount of manganese as its thenoyltrifluor acetone complex with dibenzo-18-crown-6 by means of synergistic extraction" Anal.Sci.,. 9. 251 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.Zhang: "Spectrophotometric determination of cobalt(II)in water after preconcentration by sorption of its nitroso R complex with poly(chlorotrifluoroethylene)resin" Anal.Sci.,. 10(in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fukushima: "Effect of sodium dodecyl sulfate on measurement of labile copper(II) species in the presence of humic acid by apdoc striping voltammetry" Anal.Chim.Acta. 270. 153-159 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fukushima: "Interaction between humic acids and Copper(II) oxinate" Anal.Chim.Acta. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Kakizawa: "Syntheses and complexing behavior of new fluorescent reagents for alkaline earth metal ions" Chem.Lett.1671 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Nakamura: "Time resolved electron spin resonance spectra of linked radical pairs on laser excitation of zinc tetraphenylporphyrin-viologen systems" J.Phys.Chem.97. 554 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Iwata: "Preparation of thin support film for PIXE and its application to trace analysis of biological materials" Intern.J.PIXE. 2. 361 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Nakamura: "Synergic extraction of tervalent lanthanoids with 2-thenoyltrifluoroacetone and ethylenediamine as a neutral bidentate ligand" Anal.Chim.Acta. 270. 95 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Nakano: "Flow injection determination of chromium(III) by pyrogallol chemiluminescence" Talanta. 40. 75 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Teshima: "Effect of ligands on the iron(III)/iron(II) system and its novel application to simultaneous flow injection determination of vanadium(IV) and vanadium(V)" Anal.Sci.10. 207 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Tsunoda: "Charactaristics of Potasium Ion Doped Slab Optical Waveguide as Absorption Cell and its Application to Spectrophotometric Determination of Methylene Blue" Anal.Chim.Acta. 276. 133 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Kawamoto: "Labitity of Soluble Copper(II) Complex in River Waters in the Uban Area" Bull.Chem.Soc.Jpn.66. 2104 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Kuroda: "Ion interaction chromatography of nitrilotriacetatocomplexes of the rare earth elements with post-column reaction detection" Talanta. 40. 237 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Kuroda: "Selective determination of yttrium in geological materials by ion-interaction chromatography" Mikrochim.Acta. 110. 47 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Ikeguchi: "Flow Injection - Acid Hydrolysis Technique for Determination of Organic Phosphates" Anal.Sci.9. 397 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Murayama: "Preparation and Evaluation of Octadecyl Titania as Column Packing Material for High Performance Liquid Chromatography" Microchem.J.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.katsura: "Enhancement effect of palladium and Albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.6. 97 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Matsumoto: "Palladium as a matrix modifier in graphite-furnace atomic absorption spectrometry of group IIIB-VIB elements" Anal.Sci.9. 447 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Billah: "Preconcentration and determination of a trace amount of manganese as it acetone comlex with dibenzo-18-crown-6 by means of synergistic extraction" Anal.Sci.9. 251 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.Zhang: "Spectrophotometric determination of cobalt(II) in water after preconcentration by sorption of its nitroso R complex with poly(chlorotrifluoroethylene) resin" Anal.Sci.10, (in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Yasud: "Solvent Extraction of Divalent Metals as Dihydrobis(1-pyrazolyl) borate Chelates" Bull.Chem.Soc.Jpa. 65. 761 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ogura: "Voltammetric Study on the Transfer of Alkali and Alkaline Earth Metal Ions at the Aqueous/Organic Interface Facilitated by Phosphine Oxides" Bull.Chem.Soc.Jpn.66. 1971 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Motomizu: "spectrophotometric determination of cationic and anionic surfactants with anionic dyes in the presence of nonionic surfactants, Part I : general aspect" Microchim.Acta. 106. 57 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Hagiwara: "Equilibrium and kinetic studies on the formation of triphenylmethanols from triphenylmethane dyes" Bull.Chem.Soc.Jpn.67, (in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] E.Iwamoto: "Graphite furnace atomic absorption spectrometry with graphite cloth ribbon and its application to determination of arsenic in mussel" Anal.Sci.8. 389 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Fujiwara: "Automated method for the selective determination of gold by on-line solvent extraction and reversed micellar madiated luminol chemiluminescence detection" Microchem.J.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] U.Hase: "Determination of trace amounts of iron in highly purified water by ion-exchanger phase absorptiometry combined with flow analysis" Talanta. 39. 1019 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] U.Hase: "Determination of silicic acid in highly purified water by improved gel-phase absorptiometry" Anal.Sci.9. 111 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Fukushima: "Effect of sodium dodecyl sulfate on measurement of labile copper(II)species in the presence of humic acid by anodic stripping voltammetry" Anal.Chim.Acta. 270. 153-159 (1992)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Kakizawa: "Syntheses and complexing behavior of new fluorescent reagents for alkaline earth metal ions" Chem.Lett. 1671-1674 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] R.Kuroda: "Ion interaction chromatography of nitrilotriacetatocomplexes of the rare earth elements with post-column reaction detection" Talanta. 40. 237 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Murayama: "Preparation and Evaluation of Octadecyl Titania as Column Packing Material for High Performance Liquid Chromatography" Microchem.J. in press (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Katsura: "Enhancement effect of palladium and Albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci. 8. 97 (1992)

    • Related Report
      1993 Annual Research Report
  • [Publications] U.Hase: "Determination of trace amounts of iron in highly purified water by ion-exchanger phase absorptiometry combined with flow analysis" Talanta. 39. 1019 (1992)

    • Related Report
      1993 Annual Research Report
  • [Publications] Shoichi katuta: "Novel enhancement effect of a proton donor on chelate extraction:Extraction of iron(III)with acetylacetone and 3,5-diclorophenol" J.Radioanal.Nucl.Chem. 157. 255-264 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Terada: "Preconcentration of gold(III),Palladium(III)and ruthenium(III)with dithicarbamate-chitin" Anal.Sci.7. 71-74 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Yamaguchi: "Preconcentration of trace metals as their complexes on poly(chlorotrifluoroethylene)resin" Anal.Sci.8. 851-855 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.kawamoto: "Extractive separation of trace amounts of Cu^<II>,Fe^<III>,and Ga^<III> from Al^<III> on the basis of HSAB rule" Bull.chem.Soc.Jpn. 65. 2537-2539 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Katsura: "Enhancement Effect of Palladium and Albumin on the sensitivities of Group IIIB-VIB Elements in Graphite Furnace Atomic Absorption Sprctrometry" Anal.Sci.8. 97-98 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.matsumoto: "Sensitivity Enhancement by Organo Palladium Compounds for Graphite Furnace Atomic Absorption Spectrometry of Alkyltin Compounds in Oraganic Solvent and Its Application to Paint Leaching test" Anal.Sci.7. 451-454 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 河嶌 拓治: "ポイント分析化学演習-基礎と計算-" 広川書店, (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Imura: "Solvent Extraction 1990" Elsevier sci.Pub., (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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