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有機結晶工学

Research Project

Project/Area Number 04353012
Research Category

Grant-in-Aid for Co-operative Research (B)

Allocation TypeSingle-year Grants
Research Field 結晶学
Research InstitutionOsaka University

Principal Investigator

笠井 暢民  大阪大学, 工学部, 名誉教授 (50028958)

Co-Investigator(Kenkyū-buntansha) 戸田 芙三夫  愛媛大学, 工学部, 教授 (50036232)
青山 安宏  長岡技術科学大学, 工学部, 教授 (00038093)
岩崎 不二子  電気通信大学, 電気通信学部, 教授 (10017329)
大橋 裕二  東京工業大学, 理学部, 教授 (40016118)
甲斐 泰  大阪大学, 工学部, 助教授 (40029236)
Project Period (FY) 1992
Project Status Completed (Fiscal Year 1992)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1992: ¥2,200,000 (Direct Cost: ¥2,200,000)
Keywords有機結晶工学 / 動的構造解析 / 結晶構造予測 / 動的特性解析 / 分子認識解析 / 固相反応 / 結晶環境下 / 反応設計
Research Abstract

本研究は、科学研究費補助金平成6年度発足重点領域研究の申請を目的として、以下の(A)〜(E)の研究グループを組織し、それぞれの研究項目を進展させるための最適方法を検討すると同時に、グループ間の研究成果達成のための方法について検討した。(A)構造解析グループ:有機結晶物質の特性発現条件下での構造解析に行うことにより、動的特性を直接構造変化として捕えることを目的とした研究方法の開発について検討した。(B)理論解析グループ:結晶場に束縛された分子の特性発現機構を理論的に解析し、新しい系の設計に役立つ構造化学的予測を行うための研究方法の開発について検討した。(C)動的特性解析グループ:有機結晶物質の光
・電気・磁気等に対する動的特性の評価及び新らしい機能結晶材料の開発を目的として、そのための新しい方法論の開発について検討した。(D)分子認識解析グループ:分子間の水素結合相互作用に着目し、化学反応または包接現象に基づいた異種結晶間の相互変換及び有機結晶の構造を制御する因子の解明を目的として、新しい研究方法の検討を行った。(E)反応設計グループ:溶媒の存在しない結晶中で進行する高収率・高選択的反応の開発を目的として、新しい研究方法の開発について検討した。以上の各研究グループの成果を基に、平成4年11月大阪においてシンポジウムを開催し、またその前後数回にわたる研究打合せの結果、新しく愛媛大学工学部
・戸田芙三夫教授を領域代表者とする重点領域研究「結晶環境下での反応設計」を申請した。新しく申請した重点領域研究の基本的な考え方は、これまで溶液中で行われてきた有機化学反応を結晶中で能率良くしかも選択的に行わせようとするもので、化学反応といと研究分野ではこれまでに見られなかった全く新しい視点からの研究である。

Report

(1 results)
  • 1992 Annual Research Report
  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] K.Kondo: "Crystal Structure of Thermally Stable Non-linear Benzarbituric Acid Derivatives" Chem.Phys.Lett.188. 282-286 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Sugimoto: "Biradical Character of a Closed-Shell Heteroaromatic Quinone" J.Am.Chem.Soc.114. 1893-1895 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Yasui: "Three-dimensinal Structure of Ferricytochrome c' from Rhodospiril rubrum at 2.8A Resolution" J.Biochem.111. 317-324 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] N.Kanehisa: "Unique Molecular Structures of Tungten Phenoxides" Bull.Chem.Soc.Jpn. 65. 1197-1201 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Sugimoto: "Magnetic Properties in Charge-Transfer Complexes of High-Symmetry Organic Acceptors" Mat.Res.Soc.Symp.Proc.247. 417-428 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] I.Oonishi,S.Ohshima,S.Fujisawa,J.Aoki,Y.Ohashi & T.M.Krigowski: "Conformation of condensed polycyclic aromatic hydrocarbons Part III.The molecular and crystal structure of tribenzo-[1,2,10-cde]-pentaphene:a simple analysis of the in-plane distortions due to overcrowding" J.Mol.Stuc.265. 283-292 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Arai,T.Nemoto,Y.Ohashi & E.Nakamura: "Chlorosilane-Mediated 1,2-Addition of Organocuprates to a,b-Unsaturated Aldehydes;A Case of Vinylogous Cram's Rule" SYNLETT. 309-310 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] G.Yamamoto,T.Nemoto & Y.Ohashi: "Atropisomerism in Doubly peri-Substituted 9-(2-Methybenzyl)-triptycene Derivatives,8-Chloro-and 8-Bromo-1,4-dimethyl-9-(2-methybenzy)triptycenes" Bull.Chem.Soc.Jpn.65. 1957-1966 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Sakai,Y.Ohashi,Y.Arai & Y.Ohgo: "Multi-stage Crystalline State Racemization of a Bulky Chiral Group" Mol.Cryst.Liq.Cryst.219. 149-152 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Takenaka,Y.Kojima,Y.Ohashi & Y.Ohgo: "Temperature Dependence of Reaction Rate in Crystalline State Racemizition" Mol.Cryst.Liq.Cryst.219. 153-156 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 大橋 裕二: "分子性結晶の中の反応" 科学. 62. 730-738 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Ohgaki: "Structure refinement of lithium(I)noibuium(V)trioxide,LiNbO,with anharmonic thermal vibration model" Min.J.16. 150-160 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] N.Matsumura: "Synthesis and Characterization of 10-Se-3 Type Selenatetraazapentalene Derivatives with a Hypervalent Selenium" Phosphrus,Sulfur and Silicon. 67. 135-140 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Yasui: "Structure of 2.3-Di-tert-buty1-5,6,7,8-endo-tetrahydroxy-methyl-bicyclo[2.2.2]oct-2-ene" Acta Crystallogr.C48. 1065-1068 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] F.Iwasaki: "An Isomeric Series of Thiophene-fused Tetracyano quinodimethanes II.The Crystal and Molecular Structures." Bull.Chem.Soc.Jpn.65. 2173-2179 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Okuyama: "Crystal Structures of H-aggregate of Azobenzene-contalning Amphiphiles,C_6AzoC_8N+Br- and C_8AZoC_<10>N+Br-" Mol.Cryst.Liq.Cryst.Sci.Techonol.213. 105-115 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Okuyama: "Heat-Induced Structural Changes of Multibilayer Films of Benzylidene-and Salichilideneaniline-Containing Ammonium Amphiphiles" Chem.Letters. 1993. 295-298 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Okuyama: "Odd-even Effect on Bilayer Structures of CnAzoCmN+Br-" Mol.Cryst.Liq.Cryst.,.

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Honda: "Theoretical Study of Structure and Thermodynamic Properties of Liquid Hydrogen Fluoride" Bull.Chem.Soc.Jpn. 65. 3122-3134 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Goto: "Further Developement in the Algorithm for Generating Cyclic Conformers" Tetrahedron Lett.33. 1343-1346 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Goto: "An Efficient Algorism for Searching Low-Energy Conformers of Cyclic and Acylic Molecules" J.Chem.Soc.,Perkin Trans.2.

    • Related Report
      1992 Annual Research Report
  • [Publications] E.Osawa: "Critical Evaluation of an Empirically Modified Karplus Equation" Magn.Reson.Chem. 30. 1104-1110 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] I.Fujii: "XELE- a polypeptide model-building program for a graphic work station" J.Molecular Graphics. 10. 185-189 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Yoneda: "Structures of Dienthyl 2-[(hydroxy-kO-2-quinolyl-kN)methy malonate(2-)-KC](pyridine)" Acta Crystallogr.C49. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Sugawara: "Organic Paralectrics REsulting from Tautomerization coupled with Proton-transfer" Solid State Commun.83. 665-668 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Mochida: "Tautomerization of 2-Carboxy-1,3-dibenzo[a,c]tropolone in the Solid State. Possibility of a Symmetrical Structure of the Enol Form" Chem.Lett.1623-1626 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Okuno: "Crystal State and Liquid Crystal State Polymerization of Unsymmetrical Diacetylenes with an Orientation-controlling Substituent" Mol.Cryst.Liq.Cryst.217. 59-64 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Izuoka: "Kinetic Feature of Nematic Phase Polymerization of Diacetylenes" Mol.Crysl.Liq.Cryst.226. 201-398 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] G.Matsubayashi: "Crystal Structures of [NBu^n_4]_2[M(C_3S_5)(C_3Se_5)](M=Ni or Pd) and Properties of the Nickel(II) Complex" J.Chem.Soc.,Dalton Trans.1827-1830 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] G.Matsubayashi: "Structures and Properties of [Cu_4(C_3X_5)_3]^<2->(X=S and Se)Cluster Anion Complexes" Phosphorus,Sulfur and Silicon and the Related Elements. 67. 339-344 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] G.Matsubayashi: "Intercalative Polymerization of 3-Methyl- and 3,4-Dimethylphrole in the VOPO_4 Interlayer Space" Chem.Lett.31-34 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kobayashi: "Molecular Recognition of the Guest Incorporation into Crystal Cavities of Hydrogen-Bonded Network" J.Am.Chem.Soc.

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Miyata: "Guest-Dependent Conformations of Solid Chains in Cholic Acid Inclusion Compounds" Supramolecular Chem.

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Miyata: "Intercalation Phenomena and Polymorphism of Cholic Acid Crystals" Mol.Cryst.Liq.Cryst.219. 503-507 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] W.Goonewardena: "One-Dimensinal Inclusion Polymerization of Diene and Viny Monomers by Using Methy Cholates as a Host" Polymer J.

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Tanaka: "Selective Photodimerizations of Conmarin in Crystalline Inclusion Compounds" J.Chem.Soc.,Perkin Trans.1. 943-944 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] F.Toda: "Photocylization of Phenylylyoxslamides as Inclusion Complexes with an Optically Active Host Derived from Tartaric Acid" J.Chem.Soc.,Perkin Trans.1. 1461-1462 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Tanaka: "Control of the Stereochemistry in the Photocyclization of Acrylanilides to 3,4-Dihydroquinoline-2(1H)-ones" J.Chem.Soc.,Chem.Commun.1053-1054 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] F.Toda: "Inclusion Complexation of Cholestanol,Cholesterol,Sitosterol,stigmasterol,and Ergosterol with various Guest Compounds" Bull.Chem.Soc.Jpn.66. 312-323 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kinbara: "Formation of a Topochemically Photoreactive Mixed Crystal by Grinding and Its Mechanistic Interpretation" Bull.Chem.Soc.Jpn.

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kudo: "Anti-Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles.Scope,Limitation,and Mechanism" J.Org.Chem.58. 579-587 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Kudo: "Highly Regioselective Pinacol Rearrangement of Sulfenylmethy Glycols" Chem Lett.1449-1452 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Shimada: "Diastereoselective Ring-Opening Aldol-Type Reaction of 2,2-Dialkokycyclopropanecarboxylic Esters with Carbonyl Compounds.1.Synthesis of Cis 3,4-Substituted γ-Lactons" J.Org.Chem.57. 7126-7133 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Shimada: "Diastereoselective Synthesis of b-Amino Esters by the Lewis Acid-Mediated Reaction of N-Tosyl Aldoimines with Ketene Bis(trimethylsilyl) Acetates" Chem.Lett.1445-1448 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Hashimoto: "Gallium Dichloride-Mediated Reductive Friedel-Crafts Reaction" Tetrahedron Lett.33. 6351-6354 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Saigo: "Synthesis and Properties of Polyamides Having Cyclobutane dicarboxylic Acid Derivatives as a Component" Prog.Polym.Sci.17. 35-86 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 大橋 裕二: "第4版実験化学講座10折(編、分担)" 日本化学会(飯島孝夫、大橋裕二)編、丸善, 559 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 大橋 裕二: "分子性結晶の反応(編、分担)" 大橋裕二編、リアライズ社, 342 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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