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The Measurement of the Helicity Distribution of Orbital Electrons in Chiral Molecules.

Research Project

Project/Area Number 04402009
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 物理学一般
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

ARIKAWA Tatsuo  Tokyo University of Agriculture and Technology, Department of Engineering, Professor, 工学部, 教授 (90011543)

Project Period (FY) 1992 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥34,100,000 (Direct Cost: ¥34,100,000)
Fiscal Year 1995: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1994: ¥7,400,000 (Direct Cost: ¥7,400,000)
Fiscal Year 1993: ¥10,200,000 (Direct Cost: ¥10,200,000)
Fiscal Year 1992: ¥12,500,000 (Direct Cost: ¥12,500,000)
KeywordsBreaking of chiral symmetry / Chiral molecules / Parity Violating neutral current (PNC) interaction / Helicity of orbital electrons / Laser photolysis / Positron radiolysis / Perfectron / Van der Waals cluster of Amino acid / アミノ酸のクラスタリング機構 / 陽電子ラジオリシス / 可変波長VUV光源 / 画像粒子分光法 / カイラル生体分子 / パリティの破れ / 非平衡の非線形科学 / パーフェクトロン / カイラリティの破れ / L型アミノ酸 / 弱電磁相互作用 / レーザーフォトリシス
Research Abstract

It is well known that all biological proteins are exclusively constsructed from L-amino acid, i.e, there excists only L-living species on the earth. However, it is one of the most difficult problems for the study of the cemical evolution to solve "why does the first violation of the chiral symmetry occur resulting the original asymmetric synthesis to the L-amino acids? ." There are several hypotheses to answer this problem, however, no generally accepted theory on the origin of the life. Here we have performed the investigation under the assumption that the breaking of the chiral symmetry can be produced by the parity violating weak neutral currents (PNC).
As a result of the PNC interaction, the helicity of the orbital electrons in chiral molecules are difinitely decided either positive or negative according ot the chirality of the molecule. This is the objective of the present research to investigate this fact by using the novel bioreactor "Perfecctron" by means of the laser-photolysis … More , the positron radiolysis, the simulation of chemical revolution, and the orientation of chirality. On the process of these investigations we obtained many of new valuable informations on this research : Dynamical proprties of van der Waals clusters of amino acids were firstly succeeded to measure by virtue of many new techniques developed for this purpose. Especially, the fact that certain peptides were observed in the cluster beam under the few definite combinations of amino acids may provide a key to the alternative simulation of chemical evolution that might be proceeded on the ancient earth showing a process from weakly bound van der Waals clusters to corresponding peptides via the intermediate hydrogen bonding. The development of an intense VUV light source with tunable wavelength as well as a technique to cool the temperature of cluster beam of amino acids made possible both laser-photolysis and positron radiolysis experiments by which measurements of the helicitiy of orbital electrons were able to perform with a greater accuracy by three orders than before. The technique to produce a monochromatic atomic hydrogen beam made also easy to perform the orientation experiments for the better understanding of the origin of the chiral asymmetry.
All experiments mentioned above are now in progress, however, many new techniques developed in this project are considered to be very useful and instructive to many other branches of studies. Less

Report

(5 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (45 results)

All Other

All Publications (45 results)

  • [Publications] T. Kinugawa: "Position-sensitive Time-of-Flight Mass Spectrometer using a Fast Optical Imaging Techniques." Rev. Sci. Instrum.63. 3599-3607 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Kinugawa: "Three-dimensional Velocity Analysis Combining Ion Imaging with Doppler Spectroscopy: Application to Photodissociation of HBr at 243nm." J. Chem. Phys.96. 4801-4804 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Sato: "Two-photon Dissociation of SO_2 in the Ultraviolet Region." Chem. Phys.165. 173-182 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Mo: "Mechanism of the Photodissociation of Chloroethylenes Determined from the Doppler Profilees, Spatial Anisotropies and Power Dependence of the Photofragments." J. Chem. Phys.97. 4815-4826 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Kinugawa: "Diffractive Surface Scattering Experiment of H Atoms using Laser and Ion Imaging Techniques." Jpn. J. Appl. Phys.32. 550-552 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Arikawa: "Ion Scattering Spectroscopy Experiment in Collisions of He^+ Ions with Ta and W Targets," Jpn. J. Appl. Phys.34. L1561-L1563 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Sakurai: "Formation of Hot Atomic Hydrogen Beam for Surface Diffraction Experiments." Jpn. J. Appl. Phys.34. 4195-4196 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H. Yazawa: "Dynamical Properties of Amino-acid Beam Seeded in Pulsed Supersonic Expansion." J. Mass Spectrom. Soc. Jpn.43. 139-148 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Kotaki: "REMPI-Doppler Spectroscopy of H Atoms with Tunable VUV Radiation around Lyman α Line." J. Mass Spectrom. Soc. Jpn.43. 351-363 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W. Aoba: "Fourier Analysis for Quasi-resonant Oscillatory Yields in Low Energy ISS Experiments." J. Mass Spectrom. Soc. Jpn.43. 339-349 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Sato: "Velocity Distribution in a Short-pulsed Nozzle Beam Measured by using Time-of-Flight Metastable Spectroscopy." J. Mass Spectrom. Soc. Jpn.44(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H. Yazawa: "Dynamical Properties of van der Waals Clusters of Amino-acid Tryptophan Molecule." J. Mass Spectrom. Soc. Jpn.44(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Arikawa: "Formation of van der Waals Tryptophan Clusters in Seeded Beam Expansion." Jpn. J. Appl. Phys.35(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Kotaki: "Enhancement of Lyman Emission for Detection of Diffracted Atomic Hydrogen Beam." J. Mass Spectrom. Soc. Jpn.44(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Kinugawa: "Position-sensitive Time-of-Flight Mass Spectrometer using a Fast Optical Imaging Techniques." Rev.Sci.Instum.63. 3599-3607 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Kinugawa: "Three-dimensional Velocity Analysis Combining Ion Imaging with Doppler Spctroscopy : Application to Photodissociation of HBr at 243 nm." J.Chem.Phys.96. 4801-4804 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Sato: "Two-photon Dissociation of SO_2 in the Ultraviolet Region." Chem.Phys.165. 4815-4826 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Mo: "Mechanism of the Photodissociation of Chloroethylenes Determined from the Doppler Profiles, Spatial Anisotropies and Power Dependence of the Photofragments." J.Chem.Phys.97. 4815-4826 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Kinugawa: "Diffractive Surface Scattering Experiment of H Atoms using Laser and Ion Imaging Techniques." Jpn.J.Appl.Phys.32. L550-L552 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Arikawa: "Ion Scattering Spectroscopy Experiment in Collisions of He^+ Ions with Ta and W Targets." Jpn.J.Appl.Phys.34. L1561-L1563 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Sakurai: "Formation of Hot Atomic Hydrogen Beam Seeded in Pulsed Supersonic Expansion." Jpn.J.Appl.Phys.34. 4195-4196 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Yazawa: "Dynamical Properties of Amino-acid Beam Seeded in Pulsed Supersonic Expansion." J.Mass Spectrom.Soc.Jpn.43. 139-148 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W.Aoba: "Fourier Analysis for Quasi-resonant Oscillatory Yields in Low Energy ISS Experiments." J.Mass Spectrom.Soc.Jpn.43. 339-349 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Kotaki: "REMPI-Doppler Spectroscopy of H Atoms with Tunable VUV Radistion around Lyman alpha Line." J.Mass Spectrom.Soc.Jpn.43. 351-363 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Sato: "Velocity Distribution in a Short-pulsed Nozzle Beam Measured by using Time-of-Flight Metastable Spectroscopy." J.Mass Spectrom.Soc.Jpn.44, (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Arikawa: "Formation of van der Waals Tryptophan Clusters in Seeded Beam Expansion." Jpn.J.Appl.Phys.35, (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Kotaki: "Enhancement of Lyman alpha Emission for Detection of Diffracted Atomic Hydrogen Beam." J.Mass Spectrom.Soc.Jpn.44, (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Arikawa: "Ion Scattering Spectroscopy Experiment in Collisions of He^+Ions with Ta and W Targets." Jpn.J.Appl.Phys.34. L1561-L1563 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Sakurai: "Formation of Hot Atomic Hydrogen Beam for Surface Diffraction Experiments." Jpn.J.Appl.Phys.34. 4195-4196 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Yazawa: "Dynamical Properties of Amino-acid Beam Seeded in Pulsed Supersonic Expansion" J.Mass Spectrom.Soc.Jpn.43. 139-148 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W.Aoba: "Fourier Analysis for Quasi-resonant Oscillatory Yields in Low Energy ISS Experiments." J.Mass Spectrom.Soc.Jpn.43. 339-349 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Kotaki: "REMPI-Doppler Spectroscopy of H-Atoms with Tunable VUV Radiation around Lyman α Line." J.Mass Spectrom.Soc.Jpn.43. 351-363 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Arikawa: "Formation of van der Waals Tryptophan Clusters in Seeded Beam Expansion." Jpn.J.Appl.Phys.35(in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Yazawa: "Dynamical Properties of Van der Waals Clusters of Amino-acid Tryptophan Molecule." J.Mass Spectrom.Soc.Jpn.44(in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Sato: "Velocity Distribution in a Short-pulsed Nozzle Besm Measured by Using Time-of-Flight Metastable Spectroscopy." J.Mass Spectrom.Soc.Jpn.44(in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Arikawa: "ISS Experiment in Collision of He^+ Ions with Ta Target." Japanese Journal of Applied Physics. 34. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Yazawa: "Velocity Distribution of Aminoacid Molecules Seeded into Argon Carrier." Japanese Journal of Applied Physics. 34. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Kinugawa: "Diffractive Scattering Experiment of H Atoms Using Laser and Ion Imaging Techniques." Japanese Journal of Applied Physics. 32. L550-L552 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Kinugawa: "Diffractive Scattering Experiment of H Atoms Using Laser and Ion Imaging Techniques." Japanese Journal of Applied Physics. 32. L550-L552 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Kinugawa: "Ppsition-sensitive Time-of-Flight Mass Spectrometer using a Fast Optical Imaging Techniqes." Reviw of Scientific Instruments. 63. 3599-3607 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Kinugawa: "Three-dimensional Velocity Analysis Combining Ion Imaging with Doppler Spectros copy." Journal of Chemical Physics. 96. 4801-4804 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Mo: "Mechanism of the photodissociation of Chloro-ethylenes Determined from the Dopper Profiles,Spatial Anisotropy Power Dependence of the photo-fragments." Journal of Chemical Physics. 97. 4815-4826 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Sato: "Two-Photon Dissociation of SO_2 in the Ultraviolet Region." Chemical Physics. 165. 173-182 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Kinugawa: "Diffractive Surface Scattering Experiment of H Atoms using Laser and Ion Imaging Techniques." Japanese Jurnal of Applied Physics. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 絹川 亨: "レーザーを用いた水素原子線発生法及び検出法の開発" 真空. 35. 767-772 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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