• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of (X,eX) Spectroscopy

Research Project

Project/Area Number 04403003
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 構造化学
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

UDAGAWA Yasuo  Research Institute for Scientific Measurements, Tohoku Univ., 科学計測研究所, 教授 (00004458)

Co-Investigator(Kenkyū-buntansha) 林 久史  東北大学, 科学計測研究所, 助手
高橋 正彦  東北大学, 科学計測研究所, 助手 (80241579)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥17,400,000 (Direct Cost: ¥17,400,000)
Fiscal Year 1994: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1993: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 1992: ¥9,300,000 (Direct Cost: ¥9,300,000)
KeywordsXeX / recoil electron / X-ray Raman scattering / Compton scattering / XeX / X線非弾性散乱 / 運動量 / X線散乱
Research Abstract

In Compton scattering experiments, monochromatic X-ray photons are inelastically scattered, and scattered X-ray photons are detected as a function of direction and energy. In (X,eX) spectroscopy, in addition to X-ray photons, coincident recoil electrons are measure also as a function of energy and direction. Then, by the use of momentum coservation and energy conservation, the initial electronic state can completely described. Although pointed out in earlier times, (X,eX) signal has never been observed because of experimental difficulties. In order for this goal to be achieved, excitation X-rays should be strong, scattered X-rays should be efficiently collected, and recoil electron should be discriminated from electrons from different origin, ex.photoelectron. In this study, efficient X-ray spectrometera and an electron analyzer are developed in order to observe (X,eX) phenomenon.
A monochromator having a spherically bent Si (440) crystal and a spectrometer having a singly bent graphite (004) crystal were constructed. By the use of these, very weak X-ray Raman scattering was observed (Reference 1). Then, a single spherical electrostatic analyzer was constructed, which consists of an inner sphere of 64 mm in diameter and an oute sphere of 86 mm in diameter. The resolution was 2 eV as expected, and (e, 2e) phenomena which is an electron analogure of (X,eX) were observed (submitted for publication). By combining these elements (X,eX) measurements were carried out and coincident signals were observed. They might, however, originate from photoelectron, and we are still trying to make it sure whether they are (X,eX) signals or not.

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] H.Hayashi,K.Tohji,Y.Udagawa,A.Ueno.: "Small-Angle X-Ray Scattering Study on the Growth of Metal Silicate Polymers" Bull.Chem.Soc.Jpn. 66. 1024-1027 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Udagawa,H.Hayashi,K.Tohji,T.Mizushima.: "X-ray Resonant Raman Spectra of Several Copper Compounds." J.Phys.Soc.Jpn. 63. 1713-1720 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Hayashi, K.Tohji, K.Udagawa, A.Ueno: "Small-Angle X-Ray Scattering Study on the Growth of Metal Silicate Polymers" Bull.Chem.Soc.Jpn. 66. 1024-1027 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Udagawa, H.Hayashi, K.Tohji, T.Mizushima: "X-ray Resonant Raman Spectra of Several Copper Compounds." J.Phys.Soc.Jpn. 63. 1713-1720 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Hayashi,K.Tohji,Y.Udagawa,and A.Ueno.: "Small-Angle X-Ray Scattering Study on the Growth of Metal Silicate Polymers" Bull.Chem.Soc.Jpn.66. 1024-1027 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Udagawa,H.Hayashi,K.Tohji,and T.Mizushima,: "X-ray Resonant Raman Spectra of Several Copper Compounds." J.Phys.Soc.Jpn.63. 1713-1720 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 水嶋生智 他: "アルコキシド法により調製したシリカ坦持ロジュウム触媒のキャラクタリゼーションとエチレンの気相ヒドロホルミル化反応におけるロジウム粒子径の影響。" 日本化学会誌. 31-38 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 宇田川康夫: "最新の手法と応用の接点。第7回X線微細構造国際会議。" 化学. 48. 60-61 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 宇田川康夫: "X線吸収微細構造" 学会出版センター, 222 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 水嶋生智、宇田川康夫: "「金属アルコキシドを用いる触媒調製」(上野晃史他編)" アイピーシー, 17 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Hayashi and Y.Udagawa: "Mixing State of 1-Propanol Agueous Solutions Studies by Small Angle X-ray Scattering" Bull.Chem.Soc.Jpn.65. 155-159 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Hayashi and Y.Udagawa: "SAXS Curve Shape Analysis of 2-Butoxyethanol Ageous Solations" Bull.Chem.Soc.Jpn.66. 600-602 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 宇田川 康夫,田路 和幸,水嶋 生智,林 久史: "種々の同化合物のX線共鳴ラマンスペクトル" 豊田研究報告. 45. 9-18 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 宇田川 康夫: "X線吸収微細構造" 学会出版センター, 222 (1993)

    • Related Report
      1992 Annual Research Report

URL: 

Published: 1992-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi