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Functionalization and Control of Structure of Crystals of Interacting Molecules.

Research Project

Project/Area Number 04403016
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionGifu University

Principal Investigator

KAWAMURA Takashi  Gifu University ; Faculty of Engineering ; Professor,, 工学部, 教授 (40026125)

Co-Investigator(Kenkyū-buntansha) KUTSUMIZU Shoichi  Gifu University ; Faculty of Engineering ; Instructor.., 工学部, 助手 (80214964)
EBIHARA Masahiro  Gifu University ; Faculty of Engineering ; Instructor., 工学部, 助手 (80201961)
MIYATA Mikiji  Gifu University ; Faculty of Engineering ; Associate Professor., 工学部, 助教授 (90029322)
TSUJI Yasushi  Gifu University ; Faculty of Engineering ; Associate Professor., 工学部, 助教授 (30144330)
KATO Shinji  Gifu University ; Faculty of Engineering ; Professor., 工学部, 教授 (40021589)
守屋 慶一  岐阜大学, 工学部, 助教授 (40174461)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥32,500,000 (Direct Cost: ¥32,500,000)
Fiscal Year 1994: ¥4,200,000 (Direct Cost: ¥4,200,000)
Fiscal Year 1993: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1992: ¥23,400,000 (Direct Cost: ¥23,400,000)
KeywordsCluster Complex / Ionic Radical Salt / Rhodium Complex / Inclusion Complex / Organosilane / Organostannane / Organocarcogen Compound / Platinum Complex / コール酸 / 均一系触媒 / シリル化反応 / 有機カルコゲン化合物 / 液晶 / 金属原子間結合 / 結晶構造 / パラジウム触媒 / スタニル化
Research Abstract

The purpose of this project was to develop understanding of intermolecular interactions and multipoint interactions which control the crystal structure of organometallic and organic crystals and also to prepare related new compounds. The results are summarized as follows : 1. A new type of electronically conjugated system with a new streric configuration was developed by utilizing metal-metal bond and organic pi systems. An example is dirhodium cluster complexes with 4 bridging aromatic ligands. The crystal structure of their cationic radical salts showed the formation of 3-dimensional interaction networks. 2. In inclusion complexes of cholic acid and their derivatives, host molecules are shown to dynamically recognize the quest molecules with conformational change of the functional groups of the host. 3. New derivatives of thio-, seleno- and teluro-carboxylic acids have been synthesized and some of their crystal structures were analyzed. 4. Syntheses of silanes and stannanes catalyzed by Group 10 homogeneous catalysts have been developed and structure of some of model complexes for the catalytic intermediates have been analyzed. 5. Liquid crystalline phase of organophosphazenes has been analyzed. 6. New supramolecules formed from Group 10 and 11 complexes have been prepared and their x-ray structures have been analyzed. The structure changes from polymeric to discrete depending on the metal atoms and the size of the ligands.
As development from these results, we plan to develop a transition metal cluster complexes with bridging ligands with pi systems, in which the conjugation between metal-metal bond and ligand pi systems are more enhanced. Crystals of such type of complexes are expected to show interesting solid state properties.

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (72 results)

All Other

All Publications (72 results)

  • [Publications] 海老原 昌弘: "Complexes of Silver(I)with Bis(dialkyldothiocarbmato)platinum(II)as Ligand:Synthesis and Structure of 〔Pt_3(S_2CNPr^i_2)_6Ag_2〕(BF_4)_2and〔Pt_3(S_2CNBu^n_2)_6Ag_2〕(ClO_4)_2" J.Chem.Soc.,Chem.Comm.1591-1592 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 辻 康之: "Palladium-Catalyzed Dimerization-Double Stannylation of 1,3-Dienes Using Hexamethyldistannane" J.Chem.Soc.,Chem.Comm.1000-1001 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 川村 尚: "A Three-Dimensional Interaction Network of δ(M-M)and π(ligand)Electrons.The Crystal Structure of〔Rh_2(mhp)_4〕(SbCl_6)・2CH_2ClCH_2Cl(mhp=2-oxy-6methylpyridine)" Chem.Lett.1509-1512 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 大洞 康嗣: "Dimerization Double Silylation of 1,3-Dienes Using Organodisilanes Catalyzed by a Palladium Complex" Organometallics. 12. 2853-2856 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 大洞 康嗣: "Palladium Catalyzed Insertion of Norbornenes and Ethylene into Silicon-Tin s-Bonds:Silylstannation of Alkenes with Silylstannanes" Organometallics. 12. 4697-4699 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 大洞 康嗣: "Palladium-Catalyzed Decarbonylative Coupling of Acid Chlorides,Organodisilanes,and 1,3 Dienes" J.Am.Chem.Soc.115. 10414-10415 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 辻 康之: "Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex" J.Org.Chem.,. 58. 16-17 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 辻 康之: "Palladium-Catalyzed Silylation of Allylic Acetates with Hexamethyldisilane or (Trimethylsilyl)tributylstannane" J.Org.Chem.58. 3607-3608 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 宮田 幹二: "Guest-Dependent Conformations of Side Chains in Cholic Acid Inclusion Compounds" Supramol.Chem.2. 283-288 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐田 和己: "A Novel Molecular Channel with a Hydrogen Bond ‘Hook';Inclusion Phenomena of Cholanamide and the Crystal Structure of a 1:1 Complex of Cholanamide and 1,4-Dioxane" J.Chem.Soc.,Chem.Comm.,. 753-755 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 加藤 晋二: "Selenonthiolesters:Isolation and Characterization" J.Am.Chem.Soc.115. 3000-3001 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 村井 利昭: "Diselenoic Acid Esters.Stability and Reactivity" J.Am.Chem.Soc.115. 5823-5824 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 守屋 慶一: "The Liquid Crystalline State in Organophosphazenes with Biphenyl Mesogenic Croups" J.Inorg.Organomet.Polymers.2. 443-454 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 伊藤 雅彦: "Preparation and Structure of 〔PhPt(OCO_2)(PEt_3)_2〕and〔PhPt(OH_2)(PEt_3)_2〕BF_4" Inorg.Chim.Acta. 218. 199-202 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Bonding Interaction between Group 10 and Group 11 Metal Atoms.Synthesis,Structure and Properties of 〔M_3(S_2CNR_2)_6M'_2〕^<2+>(M=Pt,Pd;M'=Cu,Ag,R=Et,Pr^i,Pr^n,Bu^n,cy)" J.Chem.Soc.,Dalton Trans.3621-3635 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Influence of a Neutral Terminal Ligand on the Structure and Redox Potential of Hexamolybdenum(12^+)Cluster Ion with Mixed Capping Ligand" Bull.Chem.Soc.Jpn.67. 3119-3121 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Distorted Planar Palladium Complex with Maleonitriledithiolato and Triphenylphosphine Ligands" Acta Crystallog.C50. 1880-1882 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐田 和己: "Inclusion Phenomena of Glycine-conjugated Bile Acids and the Crystal Structure of 1:1 Complex of Glycodeoxycholic Acid and Tetrahydrofuran" J.Chem.Soc.,Chem.Comm.905-907 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐田 和己: "Specific Inclusion of Water by N-Methyldeoxycholamide Revealed by the Crystal Structure of the Hemihydrate" Chem.Lett.2113-2116 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 蔭山 秀樹: "Tautomeric Equilibrium between Selenol and Selenoxo Forms of Selenocarboxylic Acids" J.Am.Chem.Soc.116. 2195-2196 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 守屋 慶一: "Dielectric Properties of Poly(trifluoromthoxy)and Poly(p-chlorophenoxy)-Phosphazene" Makromol.Chem.Phys.195. 713-721 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Mixed Metal Complexes of Groups 10 and 11 Elements.The Structure and Properties of 〔M(mnt)_2{Ag(PR_3)_2}_2〕(M=Ni,Pd,Pt,mnt^<2->=maleonitriledithiolate)" Inorg.Chim.Acta. 231. 35-43 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 川原 康行: "A Facile preparation of Cesium Tellurocarboxylates.The First X-Ray Structural Analysis of a Tellurocarboxylic Acid Alkali Metal Salt" Chem.Lett.1995. (87-88)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 大洞 康嗣: "Palladium Complex Catalysed Carbocyclization-distannylation,-disilylation,and-silastannylation of Bis-dienes Using Distannanes,Disilanes,and Silystannanes" J.Chem.Soc.,Perkin Trans.1. (印刷中). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 村井 利昭: "Reaction of Diselenoic Acid Esters with Amines and X-Ray Structure Analyses of Aromatic Selenoamides" Heteroatom Chem.(印刷中). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Hexamolybdenum Cluster with One Telluride and Seven Chloride Capping Ligands" Acta Crystallog.(印刷中). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原 昌弘: "Discrete Hexamolybdenum Clusters with Six Chlorides and Two Selenides as Capping Ligands" Gazz.Chim.Ital.,. (印刷中). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Complexes of Silver (I) with Bis (dialkyldothiocarbmato) platinum (II) as Ligand : Synthesis and Structure of [Pt_3(S_2CNPr^i_2) _6Ag_2] (BF_4) _2 and [Pt_3 (S_2CNBu^n_2) _6Ag_2] (ClO_4) _2" J.Chem.Soc., Chem.Comm.1592 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Tsuji: "Palladium-Catalyzed Dimerization-Double Stannylation of 1,3-Dienes Using Hexamethyldistannane" J.Chem.Soc., Chem.Comm.1000 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Kawamura: "A Three-Dimensional Interaction Network of delta (M-N) and pi (ligand) Electrons. The Crystal Structure of [Rh_2 (mhp) _4] (SbCl_6) ・2CH_2ClCH_2Cl (mhp=2-oxy-6-methylpyridine)" Chem.Lett.1509 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Obora: "Dimerization-Double Silylation of 1,3-Dienes Using Organodisilanes Catalyzed by a Palladium Complex" Organometallics. 12. 2853 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Obora: "Palladium Catalyzed Insertion of Norbornenes and Ethylene into Silicon-Tin s-Bonds : Silylstannation of Alkenes with Silylstannanes" Organometallics. 12. 4697 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Obora: "Palladium-Catalyzed Decarbonylative Coupling of Acid Chlorides, Organodisilanes, and 1,3-Dienes" J.Am.Chem.Soc.115. 10414 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Tsuji: "Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex" J.Org.Chem.58. 16 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Tsuji: "Palladium-Catalyzed Silylation of Allylic Acetates with Hexamethyldisilane of (Trimethylsilyl) tributylstannane" J.Org.Chem.58. 3607 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Miyata: "Guest-Dependent Conformations of Side Chains in Cholic Acid Inclusion Compounds" Supramol.Chem.2. 283 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sada: "A Novel Molecular Channel with a Hydrogen Bond 'Hook' ; Inclusion Phenomena of Cholanamide and the Crystal Structure of a 1 : 1 Complex of Cholanamide and 1.4-Dioxane" J.Chem.Soc., Chem.Comm.753 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] S.Kato: "Selenonthiolesters : Isolation and Characterization" J.Am.Chem.Soc.115. 3000 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Murai: "Diselenoic Acid Esters.Stability and Reactivity" J.Am.Chem.Soc.115. 5823 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Moriya: "The Liquid Crystalline State in Organophosphazenes with Biphenyl Mesogenic Croups" J.Inorg.Organomet.Polymers. 2. 443 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ito: "Preparation and Structure of [PhPt (OCO_2) (PEt_3)_2] and [PhPt (OH_2) (PEt_3) _2] BF_4" Inorg.Chim.Acta.218. 199 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Bonding Interaction between Group 10 and Group 11 Metal Atoms. Synthesis, Structure and Properties of [M_3 (S_2CNR_2) _6M'_2] ^<2+> (M=Pt, Pd ; M'=Cu, Ag ; R=Et, Pr^i, Pr^n, Bu^n, cy)" J.Chem.Soc., Dalton Trans.3621 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Influence of a Neutral Terminal Ligand on the Structure and Redox Potential of Hexamolybdenum (12^+) Cluster Ion with Mixed Capping Ligand" Bull.Chem.Soc.Jpn.67. 3119 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Distorted Planar Palladium Complex with Maleonitriledithiolato and Triphenylphosphine Ligands" Acta Crystallog.C50. 1880 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sada: "Inclusion Phenomena of Glycine conjugated Bile Acids and Crystal Structure of 1 : 1 Complex of Glycodeoxycholic Acid and Tetrahydrofuran" J.Chem.Soc., Chem.Comm.905 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sada: "Specific Inclusion of Water by N-Methyldeoxycholamide Revealed by the Crystal Structure of the Hemihydrate" Chem.Lett.2113 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Kageyama: "Tautomeric Equilibrium between Selenol and Selenoxo Forms of Selenocarboxylic Acids" J.Am.Chem.Soc.116. 2195 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Moriya: "Dielectric Properties of Poly (trifluoromthoxy) and Poly (pchlorophenoxy) -Phosphazene" Makromol.Chem.Phys.195. 713 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Mixed Metal Complexed of Groups 10 and 11 Elements. The Structure and Properties of [M (mnt) _2 {Ag (PR_3) _2} _2] (M=Ni, Pd, Pt ; mnt^2=maleonitriledithiolate)" Inorg.Chim.Ascta. 231. 35 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kawahara: "A Facile preparation of Cesium Tellurocarboxylates. The First X-Ray Structural Analysis of a Tellurocarboxylic Acid Alkali Metal Salt" Chem.Lett.87 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Obora: "Palladium Complex Catalysed Carbocyclization-distannylation, disilylation, and -silastannylation of Bis-dienes Using Distannanes, Disilanes, and Silystannanes" J.Chem.Soc., Perkin Trans.1. 1(in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Murai: "Reaction of Diselenoic Acid Esters with Amines and X-Ray Structure Analyzes of Aromatic Selenoamides" Heteroatom Chem.(in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Hexamolybdenum Cluster with One Telluride and Seven Chloride Capping Ligands" Acta Crystallog.(in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Ebihara: "Discrete Hexamolybdenum Clusters with Six Chlorides and Two Selenides as Capping Ligands" Gazz.Chim.Ital.(in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 海老原昌弘: "Bonding Interaction between Group 10 and Group 11 Metal Atoms.Synthesis,Structure and Properties of |M_3(S_2CNR_2)_6M′_2|^<2+>(M=Pt,Pd;M′=Cu,Ag;R=Et,Pr^i,Pr^n,Bu^n,cyclohexyl)" J.Chem.Soc.,Dalton Trans.3621-3635 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐田和己: "Specific Inclusion of Water by N-Methyldeoxycholamide Revealed by the Crystal Structure of the Hemihydrate" Chem.Lett.2113-2116 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 守屋慶一: "Dielectric Properties of Poly(trifluoromthoxy)and Poly(p-chlorophenoxy)Phosphazene" Makromol.Chem.Phys.195. 713-721 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 川原康行: "A Facile preparation of Cesium Tellurocarboxylates.The First X-Ray Structural Analysis of a Tellurocarboxylic Acid Alkali Metal Salt" Chem.Lett.87-88 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 海老原昌弘: "Mixed Metal Complexes of Groups 10 and 11 Elements.The Structure and Properties of |M(mnt)_2{Ag(PR_3)_2}_2|(M=Ni,Pd,Pt;mnt^2=maleonitriledithiolate)" Inorg.Chim.Acta.231. 35-43 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 大洞康嗣: "Palladium Complex Catalysed Carbocyclization distannylation,disilylation,and silastannylation of Bis-dienes Using Distannanes,Disilanes,and Silystannanes" J.Chem.Soc.,Perkin Trans.1,. (印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 川村 尚: "A Three-Dimensional Interaction Network of δ(M-M)and π(ligand)Electrons." Chem.Lett.1509-1512 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 加藤 晋二: "Diselenoic Acid Esters:Stability and Reactivity." J.Am.Chem.Soc.115. 5823-5824 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 辻 康之: "Palladium Catalized Insertion of Norbornenes and Ethylene into Si-Sn σBonds." Organometallics. 12. 4697-4699 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 宮田 幹二: "A Novel Molecular Channel with a Hydrogen Bond 'Hook'." J.Chem.Soc.,Chem.Commun.753-755 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 守屋 慶一: "Dielectric Properties of Poly(trifluoroethoxy)-and Poly(p-chlorophenoxy)-phospazene" Makromol.Chem.(印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 海老原 昌弘: "Preparation and Structre of[PhPt(OCO_2)(PEt_3)_2]and[PhPt(OH_2)(PEt_3)_2]BF_4." Inorg.Chim.Acta. (印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 海老原 昌弘: "Complexes of Silver(I)with Bis(dialkyldithiocarbamato)-platinum(II)as Ligand:Synthesis and Structures of [Pt_3(S_2CNPr_1 _2) _6Ag_2](BF_4)_2and[Pt_3(S_2CNBu_n _2) _6Ag_2](CIO_4)_2" J.Am Chem Soc. 1591-1592 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 加藤 普二: "Selenonthiolesters:Isolation and Characterization" J.Am Chem Soc.,. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 辻 康之: "Palladium-catalyzed Dimerization-Double Stannation of 1,3-Dienes using Hexamethyldistannane" J.Chem.Soc.,Chem.Commun.,. 1000-1001 (1992)

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      1992 Annual Research Report
  • [Publications] 宮田 幹二: "Guest-dependent Conformations of Side Chains in Cholic Acid Inclusion Compounds" Supramol.Chem.,. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 守屋 慶一: "The Liquid Crystalline State in Organophosphazenes with Biphenyl Mesogenic Groups" J.Inorg.Oranometal.Polymers,. 2. 443-454 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 守屋 慶一: "無機高分子1(梶原鳴雪、村上謙吉、監修)(分担執筆)" 産業図書, 12 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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