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HREM-STM Analyzes of Metal-C60 Interface Structures

Research Project

Project/Area Number 04452284
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 生態学
Research InstitutionUniversity of Tokyo

Principal Investigator

ICHINOSE Hideki  University of Tokyo, Faculty of Engineering, Researcher, 工学部, 助手 (30159842)

Co-Investigator(Kenkyū-buntansha) TOKUMITU Kazuto  University of Tokyo, Engineering, Researcher, 工学部, 助手 (20180143)
MORI Minoru  University of Tokyo, Institure of Industrial Science, Associate Professor, 生産技術研究所, 助教授 (30134646)
ISHIDA Yoichi  University of Tokyo, Faculty of Engineering, Professor, 工学部, 教授 (60013108)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1993: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsC60 / HREM / STM / Interface / Ultra fine particle / カーボン60 / 界面構造 / ナノ結晶 / 超微細粒 / 格子像 / グラファイト / 転位 / 塑性変形
Research Abstract

Since C60 crystal is cohesive of van der Waals force the material is so poor in malleability and ductility. In order to make up the defects and to make the best use of the C60, production of a composite material was attempted.
Surface and interface structure of the produced composit materials were analized by scanning tunneling microscopy (STM) and high resolution electron microscopy (HREM).
Grain boundary structure of a C60 thin film grown on both Au substrate and Highly Oriented Pyrolytic graphite (HOPG) substrate were successfuly observed. It was found that C60 crystal was easily nucleated and grew three dimensionally on graphite substrate. On the Au surface, stable polycrystalline thin film was formed. The film consisted of fine crystal grains. Each grains were closely packed in the film. The interface fine structure of carbon fiber/C60 and Au/C60composites were analyzed by HRTEM as well. Attributing to the large difference in lattice constant between carbon fiber and C60, any epitaxial structure was not found at the interface. However, some possibility of a coherent parallel structure still remains. At the Au/C60 composite, no evidence of third phase precipitaion was detected in or near the interface. It is concluded that C60 and Au are directly connected and its in the surface is stable.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 末永 和知: "C_<60>ナノ結晶体の機械的性質" 日本金属学会誌. 57. 1103-1104 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 加藤 健夫: "C_<60>結晶体の塑性変形能と加工硬化能" 日本金属学会誌. 57. 1101-1102 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 石田 洋一: "C_<60>単結晶の超音波顕微鏡像" バウンダリー. 19. 17 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 石田 洋一: "Structure and Behavior of Grain Boundaries of Nanocrystalline C_<60>." Proc.MRS Conference. (in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Suenaga: "Mechanical Properties of Nanocrystalline C60" J.JPN.Inst.Met.57. No.9. 1103-1104 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Katoh: "Plasticity of C60 Crystals" J.JPN.Inst.Met.57. No.9. 1101-1102 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Ishida: "Acoustic Microscopy of C60 crystals" Boundary, 19. No.9. 17 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Y.Ishida: "Structure and Behavior of Grain Boundaries of Nanocrystalline C60" Proc.MRS Conference. (in Press). (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] H.Ichinose,Y.Ishida,A.Yamaguchi and R.Yamamoto: "High Resolution Electron Microscopy of vertically magnetized multilayered Film" Proc.5th A.P.E.M. 1. 420-421 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Y.Ishida,T.Kizuka,J.Matuzaki and H.Icxhinose: "High Resolution Electron Microscopy of Boundaries in Nano-crystalline Materials" Proc.5th A.P.E.M. 1. 304-305 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] X.Bingshe,H.IchinoseM.Mori and Y.Ishida: "High Resolution Electron Microscopy of Bi-Sr-Ca-O/Silver bonded Interfaces" Proc.5th A.P.E.M. 1. 290-291 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] S.Ono,H.Ichinose and N.Masuko: "The High Resolution Observation of porous anodic Films formed on Aluminum in phospoholic acid Solution" Corrosion Science. 33. 841-850 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 市野瀬 英喜: "粒界・界面の原子配列を観察する" セラミックス. 27. 1158-1165 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 石田 洋一・木塚 徳志・松崎 順・市野瀬 英喜: "極微細粒結晶材料(ナノ材料)の界面構造の高分解能電子顕微鏡解析" 電子顕微鏡. 27. 68-75 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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