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Structure and formation process of clathrate hydrate crystals in polar ice cores.

Research Project

Project/Area Number 04452320
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 結晶学
Research Institution(Institute of Low Temperature Science) Hokkaido University

Principal Investigator

HONDOH Takeo  Institute of Low Temperature Science Hokkaido University, Professo, 低温科学研究所, 教授 (60109494)

Co-Investigator(Kenkyū-buntansha) FUJITA Syuji  Faculty of Engineering, Hokkaido University, Research Associate, 工学部, 助手 (30250476)
後藤 明  北海道大学, 工学部, 助手 (20205587)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1993: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1992: ¥3,200,000 (Direct Cost: ¥3,200,000)
KeywordsClathrate hydrate / Ice core / Crystal growth / X-ray diffraction / Raman scattering / guest molecule / 結晶構造
Research Abstract

Purpose of the present study is to clarify the structure and formatino process of clathrate hydrate crystals included in the Vostok ice cores. The results obtained are summarized as follows.
(1) A picture of the whole transition process from air-bubbles to clathrate hydrates was obtained.
(2) It was found that the average volume of the clathrate hydrates is well correlated wth the surface temperature of the ice sheet.
(3) It was implied that air molecules are redistributed during the growth process of clathrate hydrates depending on their molecular sizes.
(4) A layr structure of very small clathrate hydrate crystals was found in a cloudy band locating at a depth of the coldest period.
(5) A new x-ray diffraction method was developed to make an efficient measurement of a clathrate hydrate distribution.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] S.Fujita S.Mae: "Relation between ice sheet internal radio-echo reflections and ice fabric at Mizuho Sttation,Dronning Maud Land,East Antarctica" Annals of Glaciolog. Vol.17. 269-275 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fujita,S.Mae and T.Matsuoka: "Dielectric anisotropy in ice Ih at 9.7GHz" Annals of Glaciolog. Vol.17. 276-280 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fujita S.Mae: "The causes and the natures of ice sheet radio-echo internal reflections estimated from the dielectric properties of ice" Annals of Glaciolog. Vol.20 (in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Uchida T.Hondoh: "Air-hydrate crystals in deep ice core samples from Vostok station,Antarctica" J.Glaciol. Vol.20 (in press). (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] J.Tabata,K.Kawamura,A.Goto,T.Hondoh,and S.Mae: "A molecular dynamics study on structural stability of clathrate hydrate crystals" Computer Aided Innovation of New Materials II. 329-332 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 本堂 武夫: "クラスレート水和物が拓く雪氷学の新分野" 雪氷. 55巻2号. 121-126 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fujita and S.Mae: "Relation between ice sheet internal radio-echo reflections and ice fabric at Mizuho Sttation, Dronning Maue Land, East Antarctica" Annals of Glaciolog. Vol. 17. 269-275 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fjita, S.Mae and T.Matsuoka: "Dielectric anisotrapy in ice Ih at 9.7GHz" Annals of Glaciolog. Vol. 17. 276-280 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fujita and S.Mae: "The causes and the natures of ice sheet radio-echo internal reflectios estimated from the dielectric properties of ice" Annals of Glaciolog. Vol. 20, in press. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Uchida and T.Hondoh: "Air-hydrate crystals in deep ice core samples from Vostok station, Antarctica" J.glaciol. Vol. 20, in press. (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] J.tabata, K.Kawamura, A.Goto, T.Hondoh and S.Mae: "A molecular dynamics study on structural stability of clathrate hydrate crystals" Computer Aided Inovation of New Materials. II. 329-332 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Hondoh: "Glaciological survay of clathrate hydrate" J.Jpn.Soc. Snow and Ice (in Japanese). Vol.55. 121-126 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Fujita,S.Mae: "Relation between ice sheet internal radio-echo reflections and ice fabric at Mizuho Station,Dronning Maud Land,East Antarctica" Annals of Glaciolog. Vol.17. 269-275 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fujita,S.Mae and T.Matsuoka: "Dielectric anisotropy in ice Ih at 9.7GHz" Annals of Glaciolog. Vol.17. 276-280 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fujita,S.Mae: "The causes and the natures of ice sheet radio-echo internal reflections estimated from the dielectric properties of ice" Annals of Glaciology. Vol.20(in press). (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Uchida,T.Hondoh: "Air-hydrate crystals in deep ice core samples from Vostok station,Antarctica." J.Glaciol. Vol.20(in press). (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] J.Tabata,K.Kawamura,A.Goto,T.Hondoh and S.Mae: "A molecular dynamics study on structural stability of clathrate hydrate crystals" Computer Aided Innovation of New Materials II. 329-332 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 本堂 武夫: "クラスレート水和物が拓く雪氷学の新分野" 雪氷. 55巻2号. 121-126 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 本堂 武夫: "氷結晶中の格子間分子" 応用物理. 第61巻第8号. 835-838 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 本堂 武夫・内田 努・前 晋爾・P.Duval・V.Ya.Lipenkov: "ボストーク・コアに含まれるクラスレート水和物の結晶学的解析" 南極資料. Vol.36No.2. 268-278 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 本堂 武夫・内田 努: "極地氷床における空気包接水和物の生成過程" 低温科学・物理篇. 第51号. 197-212 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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