| Project/Area Number |
04453023
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機化学一般
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| Research Institution | KYOTO UNIVERSITY |
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Principal Investigator |
MASTUMOTO Kiyoshi Kyoto Univ.Grad.Sch.of Human & Environmental Studies, Professor, 大学院・人間・環境学研究科, 教授 (20026818)
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| Co-Investigator(Kenkyū-buntansha) |
HASHIMOTO Shiro Kyoto Univ., Fac.of Int.Hum.Studies, Assis.Professor, 総合人間学部, 助手 (30026794)
OTANI Shinichi Kyoto Univ., Fac.of Int.Hum.& Studies, Professor, 総合人間学部, 教授 (10026768)
TODA Mitsuo Kyoto Univ., Grad.Sch.of Hum.& Env.Stud., Assis.Professor, 大学院・人間・環境学研究科, 助手 (70217511)
MATSUI Masafumi Kyoto Univ., Grad.Sch, of Hum.& Env.St, Assoc.Professor, 大学院・人間・環境学研究科, 助教授 (40101240)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥6,200,000 (Direct Cost: ¥6,200,000)
Fiscal Year 1993: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1992: ¥5,200,000 (Direct Cost: ¥5,200,000)
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| Keywords | Host-Guest Chemistry / Supramolecules / Ion Transport / Polyamine / Inclusion Compounds / Aromatic Nucleophilic Substitution / Ion Extraction / Crown Ethers / ホスト-ゲスト化学 / イオン捕捉 / 分子認識 / 銀錯体 / 超高圧 |
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| Research Abstract |
1.Based upon the previous results that single-and double-armed azacrown ethers showed specific binding and transport properties for Ag^+ion. a variety of bis-and tris-crown ethers possessing appropriate spacers have been prepared using high pressure S_NAr reactions. Some of them proved to be rival in transport properties for Ag+ ion compared with doublearmed diaza-crown ethers.
2.Due to their wide applications of polyamines for medicinal, pharmacological and as well as analytical chemistry, a wide range of the hetherto unknown cyclo polyamines that are directly connected to aromatic heterocycles have prepared based upon high pressure tactics. Preliminary extraction experiments have shown 1,4,8,11-tetrakis(2-pyridyl) 1,4,8,11-tetraazacyclo-tetradecane exhibit high extraction properties toward Hg^<2+>ion. More inteligent supramolecules are now under design.
3.The several crown ethers possessing sulfur and nitrogen atoms of in the rings were prepared, followed by directintroduction to nitrogen atom of various heteroaromatic subsituents by means of high pressure S_NAr reaction. The results of both ion transport and ion extraction experiments indicated that ion binding properties for alkali metal ions were decreased, whereas those for mercury ion were increased in comparison with the related crown ethers without sulfur atom.
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