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High Density Memory System Using Organic Thin Film

Research Project

Project/Area Number 04453076
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionThe University of Tokyo

Principal Investigator

FUJISHIMA Akira  Faculty of Engineering, University of Tokyo, Professor, 工学部, 教授 (30078307)

Co-Investigator(Kenkyū-buntansha) BABA Ryo  Faculty of Engineering, University of Tokyo, Assistant, 工学部, 助手 (70198951)
HASHIMOTO Kazuhito  Faculty of Engineering, University of Tokyo, Associate Professor, 工学部, 助教授 (00172859)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 1993: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1992: ¥5,300,000 (Direct Cost: ¥5,300,000)
Keywordsorganic thin film / LB film / STM / azobenzene / memory device / photochemical reaction / electrochemical reaction / photo-information / LB法 / 記録素子
Research Abstract

We have investigated following subjects.
1. Development of new functional (intelligent) materials by combining photochemistry and electrochemistry : An example of our achievement is our recent discovery of LB (Langmuir-Blodgett) film that responds differently to light and to electrode potential. We have proposed the possibility of development a superhigh density recording device with this material. Another example is our success in developing a new display device by based on electrochromic reactions. We have also found a new type of diamond thin film can be obtained by pretreating the substrate using photoelectrochemical techniques.
2. Environment and photoelectrochemistry : The charge separation at the interface in a heterogeneous system was utilized. Utilization of light energy to induce chemical reactions was our main concern. The (photo) electrochemical approaches are actively pursued for the production of hydrogen, a clean energy source, and the efficient reduction of carbon dioxide, a substance maligned as the source of global warming. In addition, attempts are being made recently for the use of new deodorizing and contamination-proofing photocatalytic materials prepared by coating thin films of semiconductor materials on various types of substrates.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (42 results)

All Other

All Publications (42 results)

  • [Publications] T.Amemiya: "Faradaic Charge Transfer with Double-Layer Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem.97. 9736-9740 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayer Film" Ber.Bunsenges.Phys.Chem.97. 860-864 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11. 781-785 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A. 11. 763-767 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" Denki Kagaku. 61. 1030-1031 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayer Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys.32. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.348. 459-464 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Dynamics of Faradaic Processed in Polypyrrole/Poly-styrenesulfonate Composite Films in the Presence and Absence a of Redox Species in Aqueous Solutions" J.Phys.Chem.97. 4192-4195 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodilation Techniques:Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.97. 4187-4191 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surf.Sci.Lett.284. L411-L415 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal.Chem.345. 445-456 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Faradaic Charge Transfer with Double-Layr Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem.97(38). 9736-9740 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayr Film" Ber.Bunsenges.Phys.Chem.97(7). 860-864

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A,11(4). 781-785 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A,11(4). 763-767 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" Denki Kagaku. 61(8). 1030-1031 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayr Film of Azo Compound" Sensors and Actuators. B,13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys.32(1), 3A. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials. Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.348. 459-464 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Dynamics of Faradaic Processed in Polypyrrole/Polystirenesulfonate Composite Films in the Presence and Absence of a Redox species in Aqueous Solutions" J.Phys.Chem.97(16). 4192-4195 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodilation Techniques : Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.97(16). 4187-4191 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surf.Sci.Lett. 284. L411-L415 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials. Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal.Chem.345. 445-456 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Faradic Charge Transter with Double-Layer Charging and /or Adsorption-Related Charging at Polymer-Modified Electrodes As Observed by Colar Impedance Spectroscopy" J.Phys.Chem.,. 97. 9736-9740 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Morigaki: "In-Site Electrochemical Actinometry Using an Monolayer Film" Ber.Bensengs.Phys.Chem.,. 97. 860-864 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfacs" J.Vac.Sci.Technol,A,. 11. 763-767 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" 電気化学. 61. 1030-1031 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11. 781-785 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayer Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] O.Sato: "Self-Ordered Film of Hemicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys.,. 32. 1201-1203 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-Storing Materilas.Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.,. 348. 459-464 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Amemiya: "Dynamics of Faradic Procssed in Polypyrrole/Polystyrenesulfonate Composite Films in the Presence and Absence of Redox Species in Aqueou Solutions" J.Phys.Chem.,. 97. 4192-4195 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surface Sci.Lett.,. 284. L411-L415 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodulation Techniques:Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.,. 97. 4187-4191 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-Storing Matcrials Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroanal.Chem.,. 345. 445-456 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] J.N.Yao,B.H.LOO,: "Photochomic Response of Vacuum-Evaporated Nb_2O_5 Thin Films in Ethanol Vapor" Ber.Bunsenges.Phys.Chem.,. 96. 669-701 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Patel: "Photoelectrochemical Investigations on Boron-Doped Chemically vapour-Deposited Diamond Electrodes" J.Photochem.Photobiol.A:Chem.,. 65. 419-429 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] L.A.Nagahara,: "The Influence of Hydrofluoric acid Concentration on Electrodes Copper Deposition onto Silicon" J.Electroanal. Chem.333. 363-369 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Manivannan,: "Soanning probe Microscopic Investigation of Epitaxially Grown C_<60> Film on MoS_2" Jpn.J.Appl.phys.31. 3680-3685 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Fujishima: "Biochemical Application of Photoelectrochemistry photokilling of Malignant Cells with TiO_2 Powder" Electrochimlca Acta,. 18. 153-157 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Yanagi: "Molecular Orientation of Vacuum-deposited Thin Films of Zincnaphthalocyanine" J.Appl.Phys.71. 5146-5153 (1993)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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